碳

Among his other professional activities, Doney serves on the NASA Orbital Carbon Observatory science team and is chair of the Ocean Carbon and Climate Change Scientific Steering Group, which is a part of the U.S.

唐尼从事许多科学研究，他是美国航太总署轨道卫星碳观测站的科学小组成员，也是海洋碳与气候变迁科学指导小组的主席。

By simulating and spitting of the line atδ145, we were able to show five isotropic components at δ134.6,δ139.6,δ145.1,δ147.9 and δ149.1, and the numbers the inequivalent sp2 carbons neatly dovetailed with the integral areas of the every line.

我们利用拟合分峰的方法得出了这五个不等价的碳原子的峰的位置，分别位于δ134.6、δ139.6、δ145.1、δ147.9 以及δ149.1，这五个不等价的碳原子数目上的比例关系和核磁共振曲线的积分面积吻合。

Electrocatalysis can be considered as one of the most popular application of selemium nanoparticles and carbon nanotubes. In this paper, the potential applications of MWCNTs/Se modified electrode in biological electrocatalytic were investigated and discussed.

根据碳纳米管和纳米硒在生物电催化反应中表现出的巨大潜能，研制了碳纳米管复合纳米硒修饰电极并探讨其在生物分子电化学研究中的应用，对发展新型电化学传感器和拓展纳米材料的应用具有重要的理论意义和实际应用价值。

In the first part of this work, it has been demonstrated that the ordered mesostructure of OMC plays an important role in the electrocatalytic activity towards the thiols and the destruction of this structure results in the decrease of such properties.

在论文第一部分中，我们介绍了介孔碳在硫醇类物质的电催化活性中所起的重要作用，以及介孔碳结构的变化导致这些性质的下降。

And the electroreduction process of nitrobenzene on WC powder electrode in basic solution is investigated by cyclic voltammetry, linear potential sweep and chronoamperometry. In the process of electroreduction of nitrobenzene on WC powder electrode, liquid phase mass transferring may be the control step.

并且也用循环伏安、线性扫描和恒电位阶跃等测试方法研究了碳化钨粉末电极在碱性介质中析氢和还原硝基苯的电化学特性，发现碳化钨在电催化还原硝基苯过程中，可能主要受反应物的液相传质控制。

Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.

全文共分8章：第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述；第二章研究了磷脂-桐酸脂质体的稳定性，通透能力及桐酸的聚合对这些性质的影响；磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体，〓的作用首先是使脂质体集聚然后使脂质体融合，并加速内包荧光物的释放；第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA，DDOL，研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响，聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性；第四章合成了两类氨基酸为极性基团的双亲分子，它们均可以在超声下形成稳定的脂质体结构；氨基酸基团可以在脂质体上进行缩聚反应，若聚合后脂质体表面仍有足够的亲水能力，则可得到稳定的多肽型脂质体；聚合后脂质体的相变温度降低，通透能力增加；第五章合成了四种亲水基团为单糖基的双亲分子GL-l，GL-2，GL-3， GL-4，研究了它们在水中的分散情况、集合体形态与分子结构的关系；在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高，阻止脂质体在低温放置时的集聚与融合；第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1，CL-2，CL-3；它们可以象胆固醇一样与磷脂混合形成稳定脂质体，胆甾环基团位于脂质体双分子层膜的中间；与胆固醇的作用相反，它们可以增加磷脂双分子层膜的流动性，降低混合脂质体的相变温度；三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关，比膜厚度短的分子影响最大。

Total percent of carbon, nitrogen and phosphorus in Engraulis japonicus varied from 46.3% to 60.5%. And carbon content of Engraulis Japonicus was increasing and phosphorus was decreasing when growing from larvae to adult. However, there was not significant difference to nitrogen in different stages. Differences of nutrient contents in different life stages may be caused by changes in allocation of materials for growth within the body.

结果表明，碳、氮和磷三种元素占到鳀鱼体重的46.3-60.5％，其中碳元素含量与体长成正相关，磷元素与体长成负相关，氮元素与体长之间的联系并不非常明显，不同阶段的鳀鱼在元素组成上的差异直接反映了各阶段其需要不同物质。

Its mechanism is the use of anthraquinone in alkali conditions off proton surface forming 10 more stable carbon anion face, but because carbon anion and oxygen ion exist between testosterone and enolate type each other changes, cause reaction product complex, at least five, reaction selectivity, product yield, separation difficulties, and product purity is not high, therefore, using the type and quantity of alkali, phase transfer catalyst type, solvent, to optimize the selection process conditions so as to improve the yield target product.

其机理是利用蒽酮在碱存在的条件下脱去氢质子面形成10位较稳定的碳负离子面进行，但是因为碳负离子和氧负离子之间存在酮式和烯醇式的互变，导致反应复杂，产物至少有五种，反应选择性差，产物分离困难，产率低，且产品纯度不高，因此，利用对碱的种类和量的多少，相转移催化剂的种类，反应溶剂的选择，来优化反应工艺条件从而提高目标产物的产率。

Pt nano particles decorated with nafion ionomers were synthesized and used as electrocatalyst in proton exchange membrane fuel celldue to plentiful proton channels provided by the enwrapping polymers.Then decorated Pt particles were deposited on carbon nanotubes,which enwind each other into interconnect nets and form the framework of the catalyst layer for PEM fuel cell.

介绍了Nafion聚合物作为修饰离子，合成具有原位质子导电能力的纳米Pt颗粒；TEM分析显示Pt颗粒的平均粒径为4nm，颗粒之间界限明显，分散状态良好；将这种离子导体修饰的纳米Pt沉积到纳米碳管表面作为质子交换膜燃料电池催化电极，纳米碳管相互缠绕在催化层形成交联的电子通道。

For the stepwise mechanism, the ethylene molecule was firstly adsorbed at the Brnsted acid site via π-hydrogen bonding to form a stable complex, which then went through the protonation, leading to the formation of the ethoxide intermediate. Furthermore, the ethoxide reacted with the second ethylene molecule to form the butoxide product.

对于分步反应机理，乙烯分子首先通过π-氢键作用在酸性位形成稳定的吸附络合物，再进一步发生质子化并生成乙醇盐中间体，随后乙醇盐与第二个乙烯分子发生碳－碳键结合形成丁醇盐产物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。