碳

ABSTRACT Global carbon cycle is a very important issue in the study of global climate change. Forest ecosystem carbon cycle is one of the important part of global carbon cycle, but at the present time there are considerable uncertainties in the research of global carbon cycle, which also exist in forest ecosystems carbon cycle research, especially in the estimation of carbon storage of region forest ecosystems and CO〓 fluxes exchanging with other systems.

全球碳循环是全球气候变化研究的核心问题之一，森林生态系统碳循环是全球碳循环的重要组成部分，目前在全球碳循环的研究中还存在很大的不确定性，这种不确定性同样存在于森林生态系统碳循环的研究中，尤其表现在对区域森林生态系统碳库大小及其与大气CO〓交换通量的估计上。

Meanwhile, the isomer with a larger change of dipole moment has larger value of the first hyperpolarizability during the charge-transfer process.

5， 6， 7顶点双取代碳硼烷桥连分子受推拉电子基的影响，5， 6， 7顶点碳硼烷的构型发生一定变化，碳硼烷中两个C原子间的距离变长；同时碳硼烷中两个C原子取代位置的不同，影响了分子的稳定性和极化率，取代基团与碳硼烷中成键数较低的C原子相连的异构体，稳定性较好且具有大的极化率； 5，6，7顶点双取代碳硼烷桥连分子形成一维结构有利于分子内电荷转移，在电荷转移过程中偶极矩变化较大的体系，其二阶NLO系数也较大。

Because of the nondirectional property of ionic bond and the fully delocalized property of pi electrons on carbon layers, translation will not change the electronic structure of carbon layers, resulting in that A-GIC and AE-GIC hare quite good lubrication as well. The electrons come from metals mainly transfer to the delocalized pi orbitals of carbon layers, and the increase of delocalized electrons will make metal graphite intercalation compound more electro-conductive than graphite itself. Because ionic bond between metals and carbon layers is weaker and its lattice energy is much less than that of typical NaCl crystal, so metals could be left from interlayers. The Mulliken populations of C-C in intercalation compounds are smaller than that of graphite, and the HOMO energy level of GIC is higher than that of graphite too. These Lead to that GIC will easier be oxidized.

由于离子键没有方向性，又由于碳层中的π电子是充分离域的，所以碳层不会由于平移而改变其电子结构，金属石墨层间化合物仍具有很好的润滑性；金属失去的电子主要转移到碳层的离域π轨道中，碳层离域电子增多使金属石墨层间化合物的导电性比石墨增强；金属与碳层间的离子键强度比较弱，其晶格能远小于典型的离子晶体，因而金属易从石墨层中脱出；金属石墨层间化合物中的C-C间Mulliken布居值小于石墨中C-C间的值，且金属石墨层间化合物的HOMO能级也高于石墨的HOMO能级，所以石墨层间化合物中的碳原子较石墨更易被氧化。

The iron nanoparticles in inner core have good magnetism and targeting heating effect. The temperature can go up to 52 ℃ in the case that 0.1 g carrier (carbon-coated iron nanoparticles) is injected in a local point of pig's liver,while the temperature can go up to 42℃ in the case that pig's liver uniformly containing carrier of 0.4 wt.% and 45℃ in the case that pig's liver uniformly containing carrier of 0.6 wt.%. Carbon-coated iron nanoparticles also has good antioxidation and stability by an X-rays diffraction structural analysis.

铁纳米粒子磁场强，靶向效果好，有较佳的磁靶向发热效应，在动物病灶局部放置0.1 g碳包铁纳米粒子将能使发热温度平均升到52℃；而将碳包铁纳米粒子均匀与猪肝混合也有明显的产热效果：含量0.4%碳包铁纳米粒子的一组猪肝能将温度升到42℃，而含量0.6%碳包铁纳米粒子的一组猪肝能将温度升到48℃。X射线衍射表明借助于碳的包裹，碳包铁纳米粒子有好的抗氧化性和稳定性。

In addition nC〓, nC〓, two isomers of C〓 sterene and three isomers of C〓 isoprenoid hydrocarbons were also identified from aliphatic fraction of pyrolyzed product at 200℃. After pyrolyzed at 300℃, the main aliphatic hydrocarbons were normal alkanes ranged from C〓 to C〓, with C〓 as the main peak and C〓 as the second main peak. Meanwhile, pristane, phytane and C〓 sterane were also detected. In the pyrolysates at 400℃ and 500℃, the content of saturated hydrocarbons decreased, the range of normal alkanes distribution became narrow and the main peak was nC〓. Low concentration of C〓-C〓 steranes was detected and the content of C〓-C〓 increased more.

在200℃热模拟产物饱和烃馏分中除检测出两种长链烯烃外，还检测到正十九碳单烯烃、正三十五碳双烯烃、两个碳二十八甾烯的同分异构体和三个C〓类异戊二烯烷烃化合物同分异构体。300℃模拟产物饱和烃主要为正烷烃，正烷烃的碳数分布范围为C〓-C〓，以C〓为主峰、C〓为次主峰；另外，样品中还检出姥鲛烷、植烷和C〓甾烷等化合物。400和500℃热模拟产物中的饱和烃含量下降，正烷烃系列碳数分布范围变窄，主峰碳后移至C〓，检测到低浓度的C〓-C〓甾烷系列化合物，另外，C〓-C〓藿烷系列化合物含量进一步增加。

To counter the problems present in the CO 2 removal with PC method in the little scale ammonia synthesis plant at present, the effect of CO 2 removal plant with carbonic propenyl ester method on the different factors of normal production has been analysed in detail.

针对目前小合成氨厂碳丙脱碳存在的问题，详细分析了影响碳丙脱碳装置正常生产的因素，总结了 90年代以来人们在解决生产实践中诸多问题的经验和方法，对碳丙脱碳工艺作了总结与评述。

The method comprises following steps: reacting hydroxylation carbon nano-tube successively with reagent containing halogen and hydrosulphide to prepare sulfhydryl carbon nano-tube; reflowing the sulfhydryl carbon nano-tube and platinum salts in polyatomic alcohol, processing in hydrogen atmpsphere to obtain sulfhydryl anchoring platinum / carbon nano-tube catalyst; reflowing the sulfhydryl carbon nano-tube successively with the hydrochloroauric acid and the platinum salts in polyatomic alcohol, processing in hydrogen atmpsphere to obtain sulfhydryl anchoring platinum-gold / carbon nano-tube catalyst.

本发明将市售羟基化碳纳米管先后与含卤试剂和氢硫化物反应得到巯基化碳纳米管。再将巯基化碳纳米管与铂盐在多元醇中回流，氢气氛中处理得到巯基锚固铂/碳纳米管催化剂。将巯基化碳纳米管依次与氯金酸和铂盐在多元醇中回流，氢气氛中处理得到巯基锚固铂-金/碳纳米管催化剂。

Halogenated aromatic compounds with great q〓(the most negative net atomic charges on an atom of the molecule), ENC (electron-nuclear attraction energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), qc (thenet atomic charges on the carbon atom of the weakest carbon-halogen bond) and E〓 tend to be reductively dehalogenated slow, while halogenated aromatic compounds with high values of △E (the difference of front-line orbital energy), EEC (electron-electron repulsion energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), Mw, q〓 and α tend to be reductively dehalogenated fast.

卤代芳烃化合物的整个分子的最负的原子净电荷，键序最小的碳卤键中碳原子的单中心项电子-核吸引能，该碳-卤键上碳原子的净电荷和E〓与该卤代芳烃化合物还原脱卤的速率常数负相关；而前线轨道间隙能，键序最小的碳卤键中碳原子的单中心项电子-电子推斥能，Mw，q〓和α与该卤代芳烃化合物还原脱卤的速率常数正相关。

The results showed that silver ion can complex with segregative carbon-carbon double bonds in DHA ester, with isolated C=C bonds in allyl ether and with conjugate C=C bonds in benzene individually.

研究结果表明，银离子可以与DHA乙酯的隔离碳—碳双键、烯丙醚的孤立碳—碳双键及苯的共轭碳—碳双键形成络合物。

The contents of total organic carbon and humic acid carbon in the soil from stone pit were markedly higher than that of the soils from rocky ditch, swallet or stone cavern.

结果表明：喀斯特石漠化区阔叶林土壤有机总碳含量和腐殖酸碳含量明显高于灌木林、灌草丛和稀疏草丛，而土壤水溶性有机碳含量的变化则相反；喀斯特森林退化后，土壤有机碳的累积量减少、流失量增加；喀斯特小生境土壤有机总碳和腐殖酸碳含量存在明显的水平空间变异：石坑＞石沟＞石缝＞石洞。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。