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Because the olefinic hydroxyl groups are linked with olefinic carbon, so it can ionize H〓 ion and present the properties of weak acid, and so the olefinic hydroxyl groups change into the structure of alcoholate in the presence of alkali , but the structure of alcoholate may change into the structure of olefine alcohol again, after the Na〓 ions is removed, or when the pH value of its solution turn into pH. Because the structure of the olefine alcohol is not stable and is easy to isomerizate to become the structure of olefine ketone, so there appear the ca. 1730cm〓 C=O absorption peak in the IR spectra of the products.

明确指出了在C〓、C〓富勒醇中存在烯羟基与叔羟基等二类羟基,烯羟基由于与一个共轭体系相连,从而其羟基可以离解而呈现出弱酸的性质,因而在碱性条件下易形成烯醇钠盐的结构,当除去钠离子后或在酸性溶液中,烯醇钠盐结构转变为烯醇结构,但由于烯醇结构不如烯酮结构稳定,从而形成烯醇结构后,烯醇结构异构化为烯酮结构,因此在其产物的IR谱图上出现1730cm〓附近的C=0吸收信号。

Study on the Crystallization Process of Labeled GL-7-ACA Acylase CA130 Complex 7β-bromoacetyl amino cephalosporanic acid (BA-7-ACA), an analog of glutaryl-7-amino cephalosporanic acid (GL-7-ACA), can inhibit and specifically alkylate GL-7-ACA acylase (CA130) from Pseudomonas sp. 130, forming a carbon-carbon bond between BA-7-ACA and the C-2 on indole ring of Trp-β4 residue of CA130.Here we reported that BA-7-ACA labeled CA130 (BA-C130) could self-catalyze the hydrolysis of BA-7-ACA during crystallization process. The hydrolysis was confirmed to be a reaction analogous to the one of GL-7-ACA by comparative MALDI-TOF (matrix-assisted laser desorption/ionization-time of flight) spectrometry analysis.

二、GL-7-AcA酰化酶CA130标记复合物的结晶过程研究溴乙酰氨基头孢烷酸(7β-bromoacetyl amino cephalosporanic acid,BA-7-ACA)作为戊二酰-7-氨基头孢烷酸(GL-7-ACA)的类似物,不仅能够抑制GL-7-ACA酰化酶CA130的活力,而且能通过在BA-7-ACA和CA130的β亚基第四位色氨酸吲哚环二位原子之间形成-共价键而将CA130特异的烷基化。

Proved by experiments, the two antimonic composite oxides both had high electrochemical capacities.The reversible capacities of SbFeO 3 were 550 mAh/g and the reversible capacities of SbPbO 2.5 were 1 270 mAh/g. They were far more than carbon materials.

负极在有机电解质中易形成钝化膜,引起初始容量的不可逆损失,且材料的电极电位与金属锂相近,当电池过充电时,电极表面易析出金属锂,形成枝晶而引起短路[4] 。

The formation situation of the bond for metallocarboranes and metalloboranes is analyses with the bond valence formula for atomic cluster compound.

运用原子簇化合物键价公式,对金属硼烷和金属硼烷进行了成键情况分析,提出了硼金属三中心键和硼硼金属三中心键的概念,并指出了簇合物型、夹心型和多层夹心型金属硼烷的稳定存在主要是形成金属三中心键的缘故

Controlled synthesis of carbon nanotubes and assembling them into macroscopic structures are of great importance to the applications of carbon nanotubes, and a deep understanding of the growth mechanism of carbon nanotubes would be an indispensable prerequisite for well-defined synthesis in a controllable way.

纳米管的可控制生长,及其宏观尺度结构的制备,对于纳米管的应用具有重要的意义,为了实现准确的生长控制,对纳米管生长机理的深入了解是不可缺少的前提条件。

In order to have further information about the degree of concrete carbonization influenced by wind pressure and based on the present theories and researches,the experiment with T-type beam concrete carbonisation accelerated by wind pressure was performed.

为了进一步了解外界风压对混凝土化的影响程度,在已有理论分析和矩形混凝土梁化实验结果的基础上,进行了T型混凝土梁受风影响的化试验研究。

The results showed that the best carbon and nitrogen sources for xylanase production were lactose combined with beef extract.

结果表明,里氏木霉产两种酶的最佳源和氮源各异,其中木霉产木聚糖酶的最佳源为乳糖,氮源为牛肉膏;而产β-葡聚糖酶的最佳源为麸皮,氮源为硫酸铵。

The main problems in boron carbide ceramic machining are introduced,and the laser technique is used to machine boron carbide.

介绍了化硼陶瓷加工中存在的主要问题,将激光技术应用于加工化硼陶瓷上,研究出一种新型加工方法,设计出两种有效的激光切割方法并对化硼陶瓷进行切割。

Artificial SiC: black silicon carbon, green silicon carbon, cerium silicon carbide, boron carbide

sup2;人造化硅:黑硅、绿硅、铈化硅、化硼

Data from the experiment suggest that Artemisia frigida-short bunchgrass steppemay shift from carbon sink to carbon source due to the dual influences of climatechange and anthropogenic activities.

对内蒙古草原放牧条件下收支状况的研究表明,冷蒿-小禾草草原受自然条件和人为因素双重作用存在由库向源转化的可能性。

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推荐网络例句

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。