碲

This dissertation deals with the synthetic method of benzotellurazoles containing various substituents in benzene nuclei: introducing tellurium atom to the acetanilide derivatives in ortho-position by direct or indirect ways, then reduced and cyclized to give substituted benzotellurazoles directly or indirectly.

本文系统研究了含各类取代基的苯并碲唑杂环的合成方法，即向原料中用四氯化碲以直接或间接定位的方法引入碲，再经过直接或间接还原关环法制备苯并碲唑。

B ides the tellurides mentioned above that are common in gold deposits, Te isalso seen in such rare minerals as hessite, Au2Te and, a variety of unnamed telluritesand tellurates that may be subdivided into Au-bearing and Au free minerals.

除上述碲化物外，碲在本矿床形成罕见的碲银矿、Au2Te和种类繁多的未名碲化物、碲酸盐等含氧盐，含氧盐进一步可分为含 Au、不含Au，包括 AuT。。。

The major telluride minerals are hessite and petzite, with some alaite and tellurobismuthite intergrowthed, occurring as a closely paragenetic group in inter-crystal porosesor fractures of sulfides and gangue minerals.

碲银矿和碲金银矿中Au含量变化较大，w为痕量至26.1%，与银呈负相关，与铋为正相关，可能是以类质同象形式替代Ag进入到碲银矿中；碲铅矿中未检测到金。

B ides the tellurides mentioned above that are common in gold deposits, Te isalso seen in such rare minerals as hessite, Au2Te and, a variety of unnamed telluritesand tellurates that may be subdivided into Au-bearing and Au free minerals. Theformer includes AtteO3, Au2TeO4, AuTeO4; and the latter schieffinilite, Zn2Te3O8,H2Pb2Fe4[TeO4]9.7-12H2O that were found by the author and are yet to be furtherstudied for acceptance by IMA-CNMMN as potential new minerals.

除上述碲化物外，碲在本矿床形成罕见的碲银矿、Au2Te和种类繁多的未名碲化物、碲酸盐等含氧盐，含氧盐进一步可分为含 Au、不含Au，包括 AuTeO3、Au2TeO4、AuTeO4 等以及水硫碲铅石、Zn2Te3O8、H2Pb2Fe4［TeO4］9.7－12H2O等，后二种为待申报的新矿物。

Native tellurium,melonite and altaite exist as inclusions in sylvanite.

自然碲、碲镍矿、碲铅矿在针碲银金矿中呈包裹体产出。

From mineral associations ofnative gold -calaverite, ga1ena -altaite in conunon, and native silver-hessite at the endof the sulfides quartz stage, it is concluded that Te, fugacity is in "unstheated statefor native Te" and will decline with the temperature of metallogeulc fluids decreased.

自然金-跨金矿、碲铅矿-方铅矿与晚阶段碲银矿-自然银共生组合分析表明，本区碲逸度处于&自然碲的不饱和&状态，并随成矿温度降低而减小。

Most of thesete1lurites and tellurates in these deposits are found to be products of coeval oxidationof calaverite, altaite and sufides, by Which "refractory gold" of Au tellurides will bereleased as naive gold. Most native gold released through oxidation of tellurides,however, will be trapped in the telluraes or tellurites; or be combined by Te intellurites or tellurates, which prevent gold of hyPergene from secondaxy enrichmentunder the supergene oxidation environrnenis.

研究表明，这些碲含氧盐大多数为碲金矿、碲铅矿与硫化物共同氧化的产物，&难溶金&矿物在氧化条件下发生分解，一般释放出自然金；由于金要么以自然金形式被&捕获&于这些含氧盐，要么重新与碲形成Au－Te含氧盐，所以抑制了金的次生富集。

The thermal stability, Raman spectra, and upconversion luminescence spectra of lead halide-modified Tm~3+/Yb~3+-codoped tellurite glasses have been investigated, and the upconversion luminescence mechanism of Tm~3+/Yb~3+-codoped oxyhalide tellurite glasses were analyzed.

研究了卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃的热稳定性能、Raman光谱和上转换发光光谱，分析了Tm3+/Yb3+共掺氧卤碲酸盐玻璃的上转换发光机理。结果发现：混合卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃具有好的热稳定性能、低的声子能量、强的上转换蓝光。这表明混合卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃是一种上转换蓝光激光器的潜在基质材料

The methods of extracting and refining tellurium presently were mainly soda roasting,autoclaving in general basic solution,sulfating roasting,oxidative leaching in acid solution, solvent extraction ,emulsion liquid membrane,microbial method,electrorefining,vacuum distillation and zone melting etc.

目前分离提纯碲的方法主要有苏打粉焙烧法、碱性高压浸出法、硫酸化焙烧法、氧化酸浸法、萃取法、液膜法、微生物法、电解精炼法、真空蒸馏法、区熔精炼法等，其中电解精炼法得到的碲的纯度达到99.99%，真空蒸馏碲的纯度达到99.999%，区熔精炼碲的纯度可达99.999995%，本文综述了以上分离提纯碲的方法。

Brief description is given to the test on the technology for comprehensively recovering gold and silver from tellurium-bearing slag: Tellurium-bearing slag is ground and leached with water to produce crud tellurium dioxide which is then purified through ion precipitation and complexing purification process; leaching reside is leached with chloride to produce copper and bismuth, bismuth oxychloride is recovered through neutralization and hydrolysis and sponge copper is recovered through cementation; gold and silver in the remaining residue can be recycled to the gold and silver smelting system for recovery.

文摘：简述了碲渣综合回收金银等的工艺试验：碲渣经磨矿水浸碲产出粗二氧化碲，用离子沉淀和络合净化法提纯；浸碲渣用氯盐浸出铜铋，中和水解回收氯氧铋，置换回收海绵铜；残留渣中的金银可返回金银冶炼系统回收。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。