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In this paper, based on the previous work experience, microscopic structures of electrolyte solutions and the tecknoledge of fourier transform spectroscopy and theory of quantum chemistry , we reseached on ionic solvation and ion association of the alkaline-earth metal electrolyte solution.

本文在总结前人工作的基础上,以研究电解质溶液微观结构为背景,借助傅里叶变换红外光谱技术和量子化学理论,对碱金属碱土金属电解质溶液中的离子溶剂化和离子缔合作用进行了研究,主要的研究内容如下:1。

The mechanism,thermodynamics and kinetics of ion-exchange reactions between alkali,alkaline-earth and transition metal ions and zirconium phosphate and its derivatives ar...

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法,包括二异氰酸酯在催化剂的存在下进行反应,其中所述催化剂由盐化合物组成,该盐化合物由选自1,2,3-或1,2,4-三唑、1,2,3-或1,2,4-三唑的取代系列者、1,2,4-三唑的碳环稠合系列者、1,2,3-或1,2,4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

The raw materials used by the method are green chemicals dimethyl carbonate and p-nitrophenol, and the catalyst is NaY molecular sieve, activated aluminum oxide or activated carbon which is impregnated by alkali metals or alkaline-earth metal compounds.

本发明涉及到一种合成对硝基苯甲醚的方法,该方法所用的原料为绿色化学品碳酸二甲酯和对硝基苯酚,催化剂是经碱金属或碱土金属化合物浸渍过的NaY分子筛、活性氧化铝或活性碳。

Alkalescence a flux, such as alkali metals and alkaline-earth metal, zinc oxide and most stain oxide or chromophores components are gender neutral, the principal is alumian oxide, sometimes hemaite and electrolyic, and so on are also included in this composition; acidic components of oxide for silica, phosphoric acid, zirconia, etc.

碱性成分为熔剂,如碱金属、碱土金属、氧化锌及多数的着色氧化物或发色基团;中性成分为两性氧化物,主体为氧化铝,有时将氧化铁和氧化锰等也列入此成分中;酸性成分中有代表性的氧化物为氧化硅、磷酸、氧化锆等

Transition probabilities, oscillator strengths, and lifetimes of configurations, multiplets, and individual lines for many-electron atoms and ions are studied employing the WBEPM theory. Transition probabilities and oscillator strengths for alkali metal atoms, alkaline-earth elements Be, Mg, Be , and Mg , carbon atoms and its ions , nitrogen atom and its ions , oxygen atoms and its ions , fluorine atom, Ne , and IB elements are calculated. Lifetimes of C, N, and O atoms are evaluated as well.

运用WBEPM理论对多电子原子和离子的组态、谱项和能级间的跃迁几率、振子强度以及辐射寿命进行系统地研究,计算了碱金属原子、碱土金属的Be、Mg原子及其一价离子、C原子及其离子、N原子及其离子、O原子及其离子、F原子、Ne离子和重金属IB族原子的跃迁几率和振子强度以及C、N、O原子的辐射寿命。

Alkali metal; Alkaline-earth metal; ionic salvation; ionic association ; quantum chemistry

碱金属;碱土金属;离子溶剂化;离子缔合;量子化学

Mixture of alkali metals with a number of halogenated alkane solvents such as carbon tetrachloride and chloroform can be used to form the C-C bonds between alky groups.

很多卤代烷烃,例如:四氯化碳、氯仿等与碱金属混合,进行有机增链反应,但由于容易发生剧烈爆炸,所以这类反应在传统的有机合成中很少被应用。

The invention relates to a method for the extraction of keratin from dead animal skins, characterised in the treatment of dead animal skins with a substance of general formula, or at least one corresponding alkali metal, earth alkali metal, ammonium, or phosphonium salt, the variables having the following definitions: R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, whereby at least one of R or R is not H, or R and R are not H and two vicinal groups of R to R together may be C3-C10 alkylene, R = H, C1-C12 alkyl, H-C=O or C1-C4-Alkyl-C=O, X, X, X and X = OH, SH or NHR, whereby where Rto R contains at least one sulphur atom, at least one of X to X = SH and where R to R contains no sulphur atom, at least two of X to X= SH.

本发明涉及一种从死亡动物原皮中除去角质的方法,其特征在于用通式I的物质或至少一种对应的碱金属盐、碱土金属盐、铵盐或∴盐处理死亡动物原皮,式I中各变量定义如下:R 1 和R 4 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基,其未被取代或被一个或多个SH或OH基团取代;R 2 和R 3 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基,其未被取代或被一个或多个SH或OH基团取代,其中至少一个基团R 2 或R 3 不为氢,或R 1 和R 4 不为氢,且两个相邻基团R 1 -R 4 可以一起为C 3 -C 10 亚烷基;R 5 选自氢、C 1 -C 12 烷基、H-C=O或C 1 -C 4 烷基-C=O;X 1 、X 2 、X 3 和X 4 选自OH、SH和NHR 5 ,其中若R 1 -R 4 含有至少一个硫原子,则至少一个基团X 1 -X 4 为SH,以及若R 1 -R 4 不含硫原子,则至少两个基团X 1 -X 4 为SH。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

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