碱的

A novel endocyclic enamine cyclopentenone annulation was discovered and rationalized as an unusual Nazarov-type electrocyclization, which would have broad applications in the synthesis of natural alkaloids and other heterocycles.

我们在合成路线一、路线二中用的6-6元环系到7-5元环系的还原重排反应，在温和的酸性还原条件下即能发生，这说明在三尖杉碱的生物合成中6-6元环到7-5元环的还原重排步骤是非常有可能发生的；因此，我们的合成路线二中可认为是生物合成过程。

The constituents of bulb of F. puqiensis were studied. Five steroid alkaloids were isolated. The plane structure and stereoscopic configuration of 4 compounds were elucidated. They are named as puqienine A (FP-33), puqienine B (FP-3), N-demethyl-puqietinone (〓 FP-34) and puqietinone (〓, FP-9). Puqienine A and N-demethyl-puqietinone are new compounds. Puqienine B is as same as FPQ-3 elucidated by Prof.

对F.puqiensis鳞茎化学成份进行了研究，分得5个甾体类生物碱成分，并采用 UV、IR、EI-MS、1D-NMR，HHCOSY、CHCOSY、HMBC和X-RAY等光谱技术和理化常数测定，鉴定出4个化合物的平面结构和立体构型，分别为蒲圻贝母碱甲（puqienineA，FP-33）、蒲圻贝母碱乙（puqienineB，FP-3）、N-去甲蒲贝酮碱（N-demethyl-puqietinone，FP-34）和蒲贝酮碱（puqietinone，FP-9），其中蒲圻贝母碱甲和N-去甲蒲贝酮碱为新化合物。

Determined by the specific geological background of Longhetun, the characteristics of the soil resources show abundant calcium and leaning to alkaline. Monomial indexes to evaluate the revisal coefficient of soil adapted to karst mountains areas were screened out combined with the function of karst dynamics system and analysis of characters of each factor about fertility in soil. Predigestion model to soil revisal coefficient monomial assessment was established by successful importation of the content of nutrition elements in plant body, latent efficient elements in soil and available thickness of soil in the cranny of epikarst according to the characters that three carriers of soil, soil water and karst water supply nutrition to plants and two layers of foundation consist of surface soil and soil in epikarst cranny, and several types of soil revisal coefficient and weather-soil productive potentiality were calculated, the results show that the soil revisal coefficient was even more practical after modification than before, which make up of innovation of this study.

龙何屯特殊的地质背景条件决定了耕地土壤资源的富钙偏碱的特点，结合岩溶动力系统的作用，系统分析土壤中各肥力因子的特点，筛选出适宜岩溶石山区特点的土壤订正系数评价单项指标，针对研究区存在土壤、土壤水、岩溶水三种载体提供植物营养和表层土、土下表层岩溶带裂隙土两层空间基质的特点，成功引入植物体内营养元素含量、土壤元素隐性有效态含量及土下表层岩溶带裂隙土有效厚度等新参数指标，探讨建立了土壤订正系数单项指标评价简化模型，计算出龙何屯各耕地类型土壤订正系数和气候-土地生产潜力，结果显示修正后的土壤订正系数比修正前更符合实际，成为本研究的创新点。

Host plant could also influence the competitiveness of rhizobia which shown the interaction between rhizobium and plant.

同时，宿主植物对根瘤菌的竞争结瘤也有着明显的影响。在偏酸的条件下，慢生根瘤菌的生长状况较好竞争结瘤能力强而在偏碱的条件下，快生根瘤菌的竞争能力强。

Till today, we have extracted and purified alkaloids from from Macleaya Cordata, Chelidonium Majus L., Tripterygium Wilfordii Hook f., Sedum Sarmentosum Bunge, and obtained pure sanguinarine, ethoxysanguinarine, oxysanguinarine, chelidonine, chelerythrine, ethoxychelerythrine, chelilutine, chelirubine, protopine,α-allocryptopine,β-allocryptopine, coptisine, berberine, corysamine, bocconine; triptolide, tripdiolide, triptonide, wilforddine; N-methylisopelletierine, dihydro-N-methylisopelletierine, sarmentosin etc.

我们对博落回、白屈菜、雷公藤、垂盘草等天然植物进行了大量的提取和分离研究；并分离出了血根碱、乙氧基血根碱、氧化血根碱、白屈菜碱、白屈菜红碱、乙氧基白屈菜红碱、白屈菜黄碱、白屈菜玉红碱、原阿片碱、α-别隐品碱、β-别隐品碱、黄连碱、小檗碱、沙明碱、博落回碱，雷公藤内酯醇、雷公藤内酯二醇、雷公藤内酯酮、雷公藤碱，N-甲基异石榴皮碱、二氢- N-甲基异石榴皮碱、垂盘草甙等单体。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中，开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应，为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法；在此反应体系中，离子液体不仅起到了反应溶剂的作用，而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

The interfacial tension between ABEPS solution and crude oil had been investigated. It was shown that ABEPS not only displayed outstanding salt resistance, but also good hard-water endurability, furthermore ultra low interfacial tension could be achieved without alkaline but proper amount NaCl in the water-crude oil system, which proved its excellent interfacial performance and better application prospects.

本论文还通过对ABEPS水溶液与原油之间的界面张力测定，发现ABEPS不仅具有出众的耐盐性能，而且具有良好的抗钙镁性能，合适的盐浓度下，表面活性剂水溶液与胜利原油之间可以在没有外加碱的情况下形成超低界面张力，说明这类表面活性剂具有良好的界面活性和潜在的应用前景。

In order to meet the market development, our factory introduced a 55% focus on content protopine, protopine content 60%, 65% content protopine, and 70% content protopine, 75% and 80% and other low-grade protopine, low-grade films alkali, low-level protopine, and 90% content of 92% and other non-GB Product in order to adapt to different manufacturers and the general needs of distributors, products are exported to Shandong, Jiangsu, Zhejiang, Anhui, Guangzhou and other places, by our customers trust and.

为适应市场发展我厂重点推出了55%含量片碱，60%含量片碱，65%含量片碱，和70%含量片碱，75%和80%等各种低度片碱，低度片碱，低含量片碱，以及90%含量92%等非国标产品，以适应不同厂家和广大经销商的需求，产品远销山东，江苏，浙江，安徽，广州等地，深受客户的信赖和欢迎。

The proper alkaline content was in favor of compressive strength. The chemically combined water of paste without activator decreases with the increase of fly ash content, the content of Ca2 decreases after 28d. The increase extent of chemically combined water of pastes with NaOH is higher than that of without activator, and the paste with Ca2 is the same. The XRD peak of Ca2 of paste without activator is high at early age, and the peak of mullite and quartz has less change along with age. When NaOH is added, the peak of quartz of fly ash has clear drop. The surfaces of fly ash activated has eroded trace at 7 d.

研究结果表明：适量碱的掺入对强度有利；未掺激发剂浆体的化学结合水量随着粉煤灰掺量的增加而减少，Ca2含量在28d后开始下降；掺NaOH浆体的结合水量随龄期增长的幅度比未掺激发剂的浆体的大，而掺Ca：试样变化较小；未掺激发剂的水泥－粉煤灰体系在早期Ca2的峰值较大，且粉煤灰中的莫来石和石英晶体的衍射峰随龄期变化不大；NaOH掺入后，28d时，粉煤灰中的石英晶体衍射峰明显下降；时于掺激发别的试样，在7d时粉煤灰颗粒表面已被腐蚀。

The result shows that to improve the anodic current efficiency, we should decrease the reactions in the anodic solution between dissolving chlorine and transferring sodium hydrate and reduce a series of the reactions between the anode and the cathode.

本论文首先阐述了氯碱工业生产技术发展历史，并介绍离子膜法电解产生、发展过程以及其发展方向，考察了影响电流效率的各种因素，并提出提高电流效率的措施，得出要提高阳极电流效率，就要尽量减少在阳极液中产生的溶解氯与迁移烧碱之间发生的副反应，减少阳极上氧的析出量；要提高碱的电流效率，就要尽量减少氢氧根离子向阳极室的反渗。

If you are committed to an education career, then the Master of Arts in Education from Ashford University is for you.

如果你是致力于教育事业，那么，艺术教育硕士学位阿什福德大学是给你的。

objective:to explore the expression of survivin protein and its mrna in rectal cancer and their clinic significance.

目的：研究凋亡抑制因子survivin蛋白及其mrna在直肠癌组织中的表达及其与临床病理关系。