碱性反应

Reaction .coordinate calculations show that for all of these phosphodiesters the alkaline hydrolysis follows a one-step bimolecular mechanism initialized by the attack of hydroxide ion at thephosphorous atom of the ester.

反应坐标计算表明所有这些磷酸酯的碱性水解均遵循一步历程双分子反应机理，磷酸酯的水解由氢氧根对酯上的磷原子的亲核进攻开始。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下，利用2，4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应，合成了中间体4-丙氧基－2-羟基二苯甲酮，将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

Bunte salt was first prepared by α-furfuryl chloride and sodium thiosulfate. Then under the reaction of Bunte salt with 2-methyl-3-furanthiol in the presence of sodium hydroxide, furfuryl 2-methyl-3-furyl disulfide was prepared.

首先以α-糠基氯和硫代硫酸钠反应制备Bunte盐，然后Bunte盐与2-甲基－3-呋喃硫醇在碱性条件下反应合成了产品糠基2-甲基－3-呋喃基二硫醚。

The alkaline methanolysis of 2 occurred in MeONa-MeOH solution, and gave the products with the inversion of configuration with PhO as a leaving group.

我们曾研究过个别硫代磷酞胺醋的酸性醇解反应'了，关于这类化合物的碱性醇解反应未见文献报道。

In this paper, we have investigated and discuss the appropriate conditions under which the developing reaction to responds to Phospho Vando Molybdic acid and basic dye malachite green in aqueous solution by conducting experiments, through which the best quantity about addition of reagents can be fixed.

研究了磷钒钼酸与碱性染料孔雀绿在水溶液中的显色反应，确定了最佳反应条件，并将这种方法应用于复混肥中磷含量的测定，试验结果表明，此方法的灵敏度高、重现性好、准确度高。

Bis-imidazoline was prepared from triethylene tetraamine and N,N-dimethylformamide dimethyl acetal at 85℃ for 2 h with toluene as solvent, with a yield of 90.4%. The reaction of bis-imidazoline with 1,2-dibromoethane and potassium carbonate in acetonitrile provided with a monobromide salt yield of 78.7%. Hydrolysis of monobromide salt under aqueous causic solution formed 1,4,7,10-tetraazzcyclododecane in a 74.2% yield.

用甲苯作溶剂，使三乙烯四胺和N，N-二甲基甲酰胺二甲基缩醛在85℃反应2 h，得到中间体双咪唑啉，产率90.4%，在乙腈溶剂中，碳酸钾存在下，双咪唑啉和1，2-二溴乙烷进行扩环反应，得到环状中间体一溴盐，产率78.7%，一溴盐经碱性水解2 h，得到1，4，7，10-四氮杂十二烷，产率74.2%。

Cycloserine was produced using L-serine methyl ester hydrochloride as raw material. L-serine methyl ester hydrochloride was chloridized with phosphorus pentachloride to afford 2-amino-3-chloride propanic acid methyl ester hydrochloride, which was cyclized with hydroxylamine in the presence of alkali to give cycloserine.

以L-丝氨酸甲酯盐酸盐为原料制备了环丝氨酸。L-丝氨酸甲酯盐酸盐和五氯化磷在氯仿溶剂中进行氯代反应生成2-氨基-3-氯丙氨酸甲酯盐酸盐，后者和羟胺在碱性溶液中发生环合反应得到环丝氨酸。

Basic ionic liquid OH has been introduced as catalyst and reaction medium for Knoevenagel and Perkin reactions.

以碱性离子液体OH作为催化剂，在无溶剂条件下，催化Knoevenagel反应和Perkin反应两类缩合反应。

The gelatin-siloxane nano-particles are prepared from gelatin and 3-(2,3-epoxy propoxy )propyltrimethoxysilicane by performing chemical combination and hydrolytic reaction in acidic condition to obtain sol; and adjusting the pH value to slightly alkaline for performing polymerization reaction of silicane.

将明胶和3-(2，3-环氧丙氧)丙基三甲氧基硅烷在酸性条件进行化合、水解反应；将该溶胶的pH值调节至弱碱性，使硅烷发生聚合反应，即可得明胶-硅氧烷纳米颗粒。

These compounds, properly designed, can be 1～2 orders of magnitude more surface active than surfactants with a single corresponding hydrophobic and a single corresponding hydrophilic group in the molecules. In this work, selected trimeric surfactant TNP is first synthesized.

本文研究了Gemini表面活性剂GNP和GTB用于脂肪酸酯的碱性水解催化作用，测定了水解速率常数和反应活化能，从动力学机理上说明了所合成的Gemini表面活性剂对脂肪酸酯水解反应有明显的胶束催化作用。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。