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碱性反应

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The chromogenic reaction of iron with phenylfluorone was studied in the presence of Tween-20 by the spectrophotometric method in detail.

在吐温-20(Tween-20)存在下,用分光光度法研究了苯芴酮与铁在碱性介质中的显色反应性能。

The basic functionalized ionic liquid, 1 -butyl-3-methylimidazolium hydroxide OH, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

The basic functionalized ionic liquid, 1-butyl-3-methylimidazolium hydroxide, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

Enzymes could enhance the deamidation rate of Gln residues. Nutrase was the most effective. The rate of deamidation by Nutrase after 6 hours at the given conditions were up to 40.85 percent, followed by alkaline enzyme and papain. Prozyme A, flavourzyme, pepsin had no obvious effect.

蛋白酶具有明显的水解酰胺基的作用,以中性蛋白酶为最,反应6小时,脱酰胺率高达40.85%,碱性蛋白酶和木瓜酶次之,复合酶A、风味酶和胃蛋白酶的作用较小。

The results show that the debromination rate of 2-bromophenol can be accelerated significantly by increasing temperature and adding alkaline materials.

结果表明:升高温度和添加碱性物质能显著提高反应的脱溴率。

Methods: In alkaline condition, reaction between amino acids and phenylisothiocyanate formed a derivant of phenylisothiocyanate-amino acid. For RP-HPLC, the Diamonsil C18 column 250 mm×4.6 mm,5 μm) and binary gradient elution were used. The mobile phase A was 0.1 mol/L sodium acetate solution-acetonitrile (93∶7) and the mobile phase B was acetonitrile-water(80∶20). The detecting wavelength was 254 nm.

在碱性条件下,氨基酸与异硫氰酸苯酯反应,生成异硫氰酸苯–氨基酸的衍生物,采用 Diamonsil C18色谱柱(250 mm×4.6 mm,5 μm),用二元梯度洗脱方式,流动相A为0.1 mol/L乙酸钠–乙腈(93∶7),流动相B为乙腈–水(80∶20),检测波长254 nm。

Trisodium salt of N,N,N'-ethylenediamine triacetic acid was prepared by hydrolyzing 2-oxo-1, 4-piperazine diacetic acid(3-KP) in the strong base solution. Then it was combined with lauroyl chloride, hexadecanoyl chloride and benzoyl chloride respectively. N-lauroyl-ED3A and N-hexadecanoyl-ED3A were prepared in succsess. The molecular structure of N-lauroyl-ED3A was characterized by ~1HNMR and ~(13)CNMR. The molecular structure of N-hexadecanoyl-ED3A was characterized by 1HNMR.

将3-KP 在强碱性条件下水解,生成ED3ANa3 的水溶液,然后分别与月桂酰氯、棕榈酰氯和苯甲酰氯反应,成功制得N—月桂酰基ED3A 和N—棕榈酰基ED3A,并用~1HNMR 和~(13)CNMR 对N—月桂酰基ED3A 的分子结构进行了表征,用1HNMR 对N—棕榈酰基ED3A 的分子结构进行了表征。

In this paper, kinetics and mechanism of oxidation of dihydric alcohols、 ethylene glycol monoethyl ether 、 amino acids by Ag in alkaline medium were studied by spectrophotometry.

本文用分光光度法研究了在碱性介质中,二羟基二合银配离子氧化二元醇、乙二醇独乙醚和天冬氨酸的反应动力学及机理。

Through dynamic examination of electrolyses, this paper research on treatment efficiency of bipolar packed bed cell under different voltage, electrolyses time, PH value andThe experimental results show that the decompounding speed of phenol decrease with the electrolyze time increasing. With the cells voltage augment the decompounding rate of phenol increase also. But when the voltage exceed 10V, the increasing speed of decompounding rate decrease.

BPBC处理苯酚废水的实验研究结果表明,苯酚的降解速率与酚浓度呈一级反应关系,即随着实际电解时间的增加苯酚降解速率逐渐减小;随着槽电压的增大,苯酚的去除率也随之增大,但是槽电压超过10V后,苯酚去除率增加趋势减缓;在碱性条件下,pH值的变化对苯酚的去除率有一定的影响,随着pH值的增大,去除率逐渐的降低;空床流速过大时,苯酚去除率有一定的下降;投加电解质后,苯酚的去除率增加,而就投加NaCl和NaNO_3的情况下,投加等摩尔浓度的NaCl和NaNO_3,投加NaCl的效果要优于投加NaNO_3的效果;提高废水中的溶解氧有利于苯酚的去除。

And the electroreduction process of nitrobenzene on WC powder electrode in basic solution is investigated by cyclic voltammetry, linear potential sweep and chronoamperometry. In the process of electroreduction of nitrobenzene on WC powder electrode, liquid phase mass transferring may be the control step.

并且也用循环伏安、线性扫描和恒电位阶跃等测试方法研究了碳化钨粉末电极在碱性介质中析氢和还原硝基苯的电化学特性,发现碳化钨在电催化还原硝基苯过程中,可能主要受反应物的液相传质控制。

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