碱

The preventive measures for the harmful defects of alkali metals are as follows: 1, reducing the alkali metals content in the raw materials; 2, increasing the MgO content of the sinter , decreasing the basicity of slag , decreasing the Si content of the pig iron, increasing relative slag volume; 3 , introducing prereduced ore pellets or partly reducted sinter; 4increasing the ability of coke resisting alkali metals; 5, using refractories that have the ability of resisting corrasion of alkali metals; 6 , cleaning the blast furnace periodically. The above recommendations are necessary for decreasing the circulation and accumulation of alkali metals effectively in blast furnace, reducing the harmful influence of alkali metals on blast furnace, increasing the smelting intensity, decreasing the coke rate, improving the gas permeability.

基于碱金属对高炉冶炼的上述危害，本文结合湘钢高炉的实际生产情况，通过理论分析、计算以及其他钢厂防治碱害的经验，提出防治高炉碱害的措施：1、减少入炉原、燃料的碱金属含量；2、提高烧结矿中的MgO含量、降低炉渣碱度、降低生铁含硅量、适当增加渣量；3、采用预还原的金属化球团或部分还原的烧结矿；4、提高焦炭的抗碱能力；5采用抗碱侵蚀的耐火材料；6、周期性性洗炉，以有效地减少碱金属在高炉内的循环富集，降低碱金属对高炉的危害，提高高炉的冶炼强度，降低焦比，改善高炉透气性。

Chapter 5 covered the quantum chemistry study of the model molecule (410 atoms) of HupA- Acetylcolinesterase complex at HF/4-31G level with point charge model (1929 point charges) to simulate the environment effect on complex active site.

第五章：用HF/4-31G量子化学方法对单分子状态石杉碱甲、活化状态的石杉碱甲以及石杉碱甲-乙酰胆碱酯酶复合物的模型体系（410原子，1929个点电荷）进行了从头计算研究，指认了对于形成稳定复合物贡献最大的石杉碱甲分子的基团和酶的氨基酸残基，揭示了活性位点中水分子的重要作用。

The method using periwinkle cells to cultivate and produce vinblastine and vincristine can stably realize the industrialized production of vinblastine and vincristine, and the production cost is rather low, the culture period is short, and the production is insusceptible to the natural environment and weather, so the year-round production can be realized.

本发明的方法用长春花细胞培养生产长春碱和长春新碱，可稳定的实现长春碱和长春新碱的工业化生产，并且其生产成本较低，培养周期短，不受自然环境以及气候的影响，可以实现周年生产。

Most importantly, with analyzing the calcined cinder by X-ray powder diffraction and scanning electron microscope, it was clear that at an appropriate calcination temperature, the activated SiO2 and Al2O3 in alkaline coal-cinder would react with the decomposed fused Na2CO3 to form a new neutral matter nepheline（NaAlSiO4）and other amorphous silicate compounds,causing an obvious reduction of the alkali content in coal-cinder.

采用X射线粉晶衍射及扫描电镜对煅烧后的灰渣进行表征，揭示了含碱灰渣煅烧脱碱过程的实质，即在适宜煅烧温度下，含碱灰渣中被活化的主要矿物质SiO2、Al2O3和熔融并分解的Na2CO3（分解为修饰网络氧化物Na2O）等发生化学反应转变为中性物质霞石（NaAlSiO4）及其他无定形复合硅酸盐，从而降低了灰渣中的碱含量。

The 1:1 mixtures of chaconine and solanine or solamargine and solasonine, produced markedly synergistic effects while the mixtures of unpaired glycoalkaloids from different plants did not have this effects.

卡茄碱与茄碱，澳洲茄边碱与澳洲茄碱的1：1的混合物产生了明显的协同作用，而来自于不同植物的不成对的糖苷生物碱则没有这种协同作用。

The results of the dissertation were concluded as follows:(1) It is essential to deposit a basic additive on the Mo-based catalysts for the synthesis of CH_3SH. The potassium-doped Mo-based catalysts exhibit the highest activity than that of the catalysts doped with the otherⅠA andⅡA group basic promoters. H_2-TPR and LRS characterizations suggest that the addition of a base leads to the transformation of octahedrally coordinated Mo to tetrahedrally coordinated Mo, thus leads to the split of low temperature reduction peaks. The interaction between the basic components and Mo lead to the formation of B-Mo interface phase, which are closely correlated with the formation of CH_3SH.(2) It has been found that Fe, Co, Ni and Te have evident promoting effects for the K-Mo/SiO_2 catalysts.

主要结果归纳如下：(1)在Mo基催化剂中，必须添加碱才具有可观的合成甲硫醇活性，在IA和IIA族元素中，K是最佳的碱促进剂，当K/Mo摩尔比为2，前驱体为K_2CO_3，采用共浸法制备的K-Mo催化剂活性最高。H_2-TPR和LRS表征显示，碱的加入导致表面八面体钼氧物种向四面体转化，催化剂的低温还原峰发生分裂，碱助剂与钼之间存在强相互作用形成了B-Mo"界面相"，该物种与合成甲硫醇密切相关。

Catalytic synthesis of ethyl chloroacetate with phospho-molybdic acid ;2. The capsaicin in the sample was alkalized with NaOH solution and mixed with phosphotungstic acid and phospho-molybdic acid , the blue heteropoly acid salt has characteristic absorption at 660 nm.

对以辣椒碱为单剂和复配剂制成生物农药中辣椒碱总量的测定条件研究结果表明，含有辣椒碱的生物农药试料，辣椒碱在碱性溶液中与磷钨酸-磷钼酸作用，生成蓝色的磷钨酸–磷钼酸杂多酸盐，在660nm有最大吸收，其吸光度与溶液中辣椒碱的含量成正比。

On the discussion about mechanism of mutation of methylating, we explored thermodynamics and dynamic properties on base pairs, investigating the proton transfer on base pairs.

从甲基化对嘌呤碱基电荷的影响，到甲基化引起碱基配对的改变造成碱基配对的诱变等都作了较为详细的探讨；在对甲基化诱变的探讨中，我们进行了热力学和动力学方面的研究，同时对碱基之间的质子迁移的难易程度也作了探讨；并在充分考虑水分子存在的情况下研究了甲基化对碱基之间的氢键作用和堆积作用的影响。

And we also research the impact of methylating on hydrogen bond and stacked bond in base pairs under considering water molecules.

研究结果表明，烷基化之所以能造成碱基错配是它可使碱基的质子迁移或烯醇互变现象容易发生，改变原有原子的电荷分布或配对模式，同时碱基自身的互变异构体会跟烷基作用，致使互变异构体能够稳定存在，影响正常碱基配对，引起碱基诱变，造成生理疾病的发生。

Western blot analysis with the antiserum ATP95 revealed a significant increase of protein amounts of the V-H〓-ATPase subunits B and c of S. slasa under 100 and 400 mmol/L NaCl treatment, which gave another evidence for a salt-induced coordinate up-regulation of V-H〓-ATPase subunits at transcription and translation levels. The coordinated salt-induced increase of subunit B, H and c of V-H〓-ATPase from S. salsa at transcription and translation levels indicated an increase of V-H〓-ATPase holoenzyme amounts, which might be the reason for the increase of V-H〓-ATPase activity of S. salsa under salt stress.

400 mmol／L NaCl处理盐地碱蓬植株分离其叶片液泡膜微囊进行Western-blot分析发现盐胁迫明显诱导了盐地碱蓬液泡膜H〓-ATPase B、c亚基蛋白的表达，证明盐胁迫下，盐地碱蓬液泡膜H〓-ATPase各亚基在转录、翻译水平存在协同表达。100、400mmol／L NaCl处理亦明显增加了盐地碱蓬叶片液泡膜微囊H〓-ATPase活性，表明盐胁迫下，盐地碱蓬液泡膜H〓-ATPase各亚基在转录、翻译水平的协同表达增加了H〓-ATPase全酶的数量，进而增大了H〓-ATPase的活性。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。