碘醇

Ingredients: Rose oil, rose fruit Oil, clove flower oil, deionized water, isopropyl myristate, glycerol, propylene glycol, polyethylene glycol -400, central PDMS, poly dimethyl siloxane, PDMS alcohol, polyacrylamide, C13-14 iso-paraffin, octoic acid / capric Acid Triglyceride, lauryl alcohol -7, hydroxyethyl acrylate, acryloyldimethyltaurate copolymer, squalane, poly sorbate esters -60, PEG-20 sorbitan laurate, panthenol, allantoin, methyl p-hydroxybenzoate, diazolidiny1 urea, 3-iodo-2-propynyl-butyl-carbamate, essence.

产品成分：玫瑰精油、玫瑰果油、丁香花油、去离子水、肉豆蔻酸异丙酯、甘油、丙二醇、聚乙二醇-400、环聚二甲基硅氧烷、聚二甲基硅氧烷、聚二甲基硅氧烷醇、聚丙烯酰胺、C13-14 异链烷烃、辛酸/癸酸甘油三酯、月桂醇醚-7、羟乙基丙烯酸酯、丙烯酰二甲基牛磺酸钠聚物、角鲨烷、聚山梨酸酯类-60、PEG-20 失水山梨醇月桂酸酯、泛醇、尿囊素、对羟基苯甲酸甲酯、双咪唑烷基脲、碘代丙炔基丁基甲氨酸酯、香精。

Two magnetic triphase catalysts of comb-like polyether s supported by γ-Fe2O3 were synthesized, and their catalytic behaviors in the iodo-substitution, etherization and the addition reaction of dichlo-rocarbene to styrene were also investigated.

以表面经偶联剂修饰的γ-Fe2O3为载体，通过聚分别与乙二醇单甲醚和一缩二乙二醇单甲醚的醇钠盐反应，合成了两种磁性梳状聚醚三相相转移催化剂，研究了它们在碘代、二氯卡宾对双键加成和混合醚制备反应中的催化活性。

The catalytic activity of iodine in the esterification reaction was studied by synthesis cyclohexyl acetate from acetic anhydride,cyclohexano and acetic acid,cyclohexano.

以单质碘为催化剂，通过乙酸酐、环己醇及乙酸、环己醇为原料合成乙酸环己酯，对碘的催化活性进行了研究。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

Methods 55 patients were treated with pelvic cavity fourfold radiography and conventional check before iodic allergic experiment.

方法选择门诊患者55例，均行四重造影检查，检查前常规行碘过敏试验阴性52例，用复方泛影葡胺为造影剂；用非离子型碘造影剂碘海醇为造影剂，观察造影过程中患者过敏反应，分析碘过敏反应的机制。

The high content of Iohexol, a contrast media, in nanogel based on PNIPAAm dispersion had a profound effect on the volume phase transition of nanogel particles and thermosensitive phase behavior of nanogel dispersion, which mainly due to the presence of Iohexol with polyhydroxy group changed the micro-environment of nanogel particles.

这主要是因为多羟基的碘海醇的存在改变了纳米凝胶粒周围的微环境，使纳米凝胶粒在较低温度时处于收缩状态，并使纳米凝胶的VPTT比不含碘海醇的水分散体的升高10℃。

The conversion of alcohols to alkyl halides was investigated using acidic ionic liquid X as halogenating agent, acidic catalyst as well as medium. The reactions of primary alcohols gave very satisfactory conversions and selectivities except for the substrates with lower boiling point,such as n-octanol and benzyl alcohol. They obtained the corresponding halides with almost quantitative yields(95%-100%).The secondary alcohols also gave the corresponding halides with excellent conversions, however, the by-products of dehydration were detected.

伯醇除某些低沸点底物外，都以高转化率(最高达100％)和高选择性(最高达100％)转化为相应的氯代烃、溴代烃和碘代烃，例如正辛醇、苯甲醇，在X中进行卤代反应得到令人满意的结果，无论氯代、溴代还是碘代得到卤代产物的收率一般都很好华东师范大学化学系01级博士学位论文(95十100%)，极少有重排产物及脱水产物被检测出来。

The main products are: iodine, alginates, mannitol, sorbitol, alginic acid, seaseed fertilizer, marine feedstuff and propylene glycol alginate.

主要产品有碘、海藻酸盐、甘露醇、山梨醇、海藻酸、海藻肥、海藻饲料、藻酸丙二醇酯。

Main products include alginic acid and its salts, mannitol, sorbitol, iodine, PGA, seaweed fertilizer, seaweed fodder etc.

主要产品有海藻酸盐，甘露醇，山梨醇，碘，藻酸丙二醇酯，海藻肥，海藻饲料等

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了