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Studing on samarium diiodide promoted asymmetric intramolecular reducing coupling reactions, we have made the resolution of the racemic biaryl dials by using enantiomeric N-tert-butanesulfinamine as the resolving reagent successfully and thus obtained a series of axially chiral biaryl dials with high enantiomeric excess.

中文摘要在二碘化钐促进的分子内不对称还原偶联反应中,我们不仅对联芳基二醛底物的合成路线进行了优化,还发现N-叔丁基亚磺酰胺辅基可以作为手性试剂,成功地对联芳基骨架二醛化合物进行拆分,得到高对映体过量的轴手性二醛类化合物。

When all the water has been consumed, an excess of iodine occurs, which usually is detected electrometrically, thus indicating the endpoint.

当所有的水被反应完,生成的过量的碘,可以被永停法检测到,以此指示终点。

Commander Lee Archambault and his crew also will deliver a spare machine that converts urine into drinking water to replace one that's broken at the space station, and a flusher and iodine solution to get rid of bacteria that's lurking in the water dispenser.

李·阿查姆曼堡尔特船长及其船员还将运送一台将尿液转换成饮用水的装置(用来替换国际空间站上损坏了的装置)、一台冲洗装置和碘液(用来除去潜伏在饮水机的细菌)。

In addition, it is also demonstrated that the haloid ions co-absorbed on the assembly play an important role in controlling the charge transfer between PATP and silver substrate.

4利用聚乙烯吡咯烷酮共聚对聚苯乙烯微球的表面改性进行碘催化剂的固定化,制备粒径均一、可循环使用的催化剂微粒。

Nafion 117CS membrane and electrodes of graphite or activated carbon fiber cloth are adopted to establish electro-electrodialysis apparatus for concentration of hydriodic acid in HI phase of IS cycle.

为应对碘硫循环制氢工艺中浓缩HI的要求,采用石墨、活性炭纤维布为电极,Nafion 117CS为质子交换膜构成电解渗析池,对Bunsen反应HI相的模拟溶液进行了HI的EED浓缩实验。

Patients with free thyroxine and suppressed serum thyrotropin could have Graves' disease, painless thyroiditis, painful subacute thyroiditis, toxic multinodular goiter, solitary hyperfunctioning nodule, or iodine-induced hyperthyroidism.

同时具有正常的甲状腺素水平和降低的促甲状腺素水平的病人可能患有Graves'病,无痛性甲状腺炎,痛性亚急性甲状腺炎,多结节性甲状腺肿伴甲亢,单发性高功能结节或者碘甲亢。

Preparation and Properties of A Chloroperoxidase-like Catalytic Antibody Iodination of free tyrosine and tyrosine in protein is m...

游离酪氨酸和蛋白质中酪氨酸的碘化是由甲状腺匀浆液和亚细胞部分中存在的酶催化的。

"With the collapse of the system, certain babies went out with the bathwater, and iodization was one of them," said Alexandre Zouev, chief Unicef representative in Kazakhstan.

佐夫是哈萨克斯坦儿童基金会的首席代表,他说:&随着整个体制的崩溃,之前的一切被全盘否定,食盐加碘只是其中之一。&

We studied reactions of sulphoxide with aliphatic and aromatic 1,3-dicarbonyl compounds promoted by Cu2·H2O, 2,2′-biimidazole and iodobenzene diacetate, with the presence of K2CO3 as a base and DMSO a solvent.

我们以K2CO3作为碱,DMSO作为反应的溶剂,在二醋酸碘苯、Cu2·H2O、2,2′-联咪唑体系中,对脂肪族和芳香族的1,3-二羰基化合物和亚砜的反应进行了研究。

The microscale reaction was performed by introducing the solution of benzaldehyde and phenylenediamines in ethanol, and the solution of iodobenzene diacetate in ethanol through the two inlets of the Y-shaped microfluidic chip reactor at ambient temperature.

反应物邻苯二胺和苯甲醛的乙醇溶液以及二醋酸碘苯的乙醇溶液,分别从微流控芯片反应器的&Y&型进样口注入,混合反应2分钟后,即可得到苯并咪唑类化合物。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。