碘化物

Part 3 : determination of chromate, iodide, sulfite, thiocyanate and thiosulfate.

第3部分：铬酸盐、碘化物、亚硫酸盐、硫氰酸盐和硫代硫酸酯的测定

According to the H NMRstudy, it was found that the protons on the cyclopentadienyl ring of 〓 were not splitted, but when one proton on the cyclopentadienylring was substituted by methyl, that is in〓 complexes, thefour protons on the ring were splitted into four groups,the 〓 between the onesignal and the others is large, the total splitting is over 2ppm. The splittings werealso affected by the halides linked with the titanium, they increase according to theorder of CI, Br, I. By the study of the 〓 Sn NMR, it is found that the chemicalshifts of 〓 are present in low field. It is assume that the large space strain causesthe angles of the tin linked with ligands deviate from the normal tetrahedral anglesresults low field shift for 〓Sn. And by MS study,there were no molecular ions for 〓 complexes in the spectra. However, for 〓 when X=CI,Br,NCO and Ar is tolyl or phenyl group,there were molecular ions,but theirabundances were very small,and no that for the iodide was found.

钛上的卤素对茂环氢的裂分也有影响，依〓，Br，I顺序，卤素对茂环氢的裂分依次加大；通过对〓的研究发现，以上这些化合物〓的化学位移都出现在低场，认为大的空间张力造成的锡的键角偏离正常的锡的四面体键角是造成〓化学位移出现在低场的原因；对这些化合物质谱的研究发现，〓系列化合物得不到分子离子峰，而〓系列的化合物，当X=〓，NCO和苯环上不带取代基或只带甲基时，则出现分子离子峰，但丰度很低，而相应的碘化物和其它化合物则没出现分子离子峰。

Started from D-tyrosine, we obtained the tetramic acid 96 using Jouin reaction. The assembly of the second fragment 109 was stared from 1,4-butandiol,using asymmetric alkylation reaction developed by Oppolzer as a key step. Coupling of the tetramic acid 96 with 109 provided the key intermediate 110 according to Yoshii\'s procedure. After remove protective group and Sharpless epoxidation, we obtained the key intermediate 113. Its macrocyclization to form the final product is in progress.

本论文的第二章主要对Macrocidin A开展了合成工作，我们从D构型的酪氨酸出发，经过官能团转换；利用Jouin反应生成Tetramic acid 96，另外一个片断从1，4-丁二醇开始经过多步反应生成碘化物104，利用Oppolzer发展的手性樟脑磺酰胺为辅基参与的不对称烷基化反应，引入手性甲基，生成关键中间体109，接着通过Yoshii发展的方法连接96和109生成110，经过Sharpless不对称环氧化反应建立环氧化合物，然后脱去保护基得到关环前体113，分子内的Mitsunobu反应进行关大环反应正在进行之中。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

The inhibitory effect of GABA could be blocked by GABAAreceptor antagonist bicuculline bicuculline methiodide and Cl- channel blocker picrotokin.

GABA的抑制效应大部分可被GABAA受体选择性拮抗剂荷苞牡丹碱甲基碘化物和Cl-通道阻断剂印防己毒素所阻断，而单独灌流BMI和PTX对RVLM神经元主要起兴奋作用。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

Thus. Treatment of CR1R2=C=CH2 (R1 = R2 = Me; R1 = H, R2 = n-Bu; R2 = Ph; R2 = cyclohexyl; R2 = cyclopentyl, R2 = C6H5O, R2 = 2-IC6H4O, R2 = 4-IC6H4O) with bisdiborn in the presence of Pd2 (5 mol %) and 3-iodo-2-methyl-2-cyclohexen-1-one (5 mol %) in toluene at 80 oC gave products bearing both vinylic and allylic boron moieties in good to excellent yields.

但我们发现可以使用Pd金属错合物与有机碘化物共同催化下的系统，来进行此种加成反应。溶剂的选择以甲苯为最佳，Pd错合物以没有强配位基存在为最好的选择。

Methods IO(superscript - subscript 3) was prepared by quantitative oxidation of bromine water, with the excessive bromine removed with formic acid. In the presence of excessive iodide, I(superscript -) would be oxidized by I(superscript - subscript 3) to form 3 times of I(superscript - subscript 3) in mol, displaying maximal absorption at 286nm in ultraviolet zone and a slightly low apex at 345nm.ε286=1.3×10^5 Lmol^(-1)cm^(-1),ε345=8.1×10^4 Lmol^(-1)cm^(-1), with both showing high sensitivity.

利用溴水定量氧化I生成IO(上标-下标 3)，再用甲酸除去过量的溴，IO(上标-下标 3)在过量碘化物存在下氧化I产生3倍摩尔量的I(上标-下标 3)，在紫外光区的286nm具有最大吸收，并在345nm处另有一略低的吸收峰，ε286=1.3×10^5 Lmol^(-1)cm^(-1)，ε345=8.1×10^4 Lmol^(-1)cm^(-1)，均具有很高的灵敏度。

Its sources and compounds are usually iodides; iodates and periodates also occur.

其来源和化合物通常都是碘化物，也有碘盐和高碘酸盐。

NaBH4 reduction of the iodides in DMSOfollowed by deprotection of Boc gave theα-methylamine in 61.5% yield.

得到的碘化物再用NaBH4还原，并且脱除Boc保护基可制备出α-甲基胺。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。