碘化

In the chapter 2 of this dissertation, we studied the cross-coupling reaction of aryl halides and vinyl iodides with sodium azide under the catalysis of copper and amino acids.

在4-碘茴香醚与叠氮化钠的模型反应中，我们考察了不同溶剂、氨基酸、碱、铜盐对反应的影响，最后筛选出了最佳的反应条件：CuⅠ/脯氨酸/NaOH/DMSO。

Similarly NAC was also protective in a bleomycin fibrosis model. Moreover, amiodarone, a benzofuran compound with redoxcycling properties induces oxidative lung injury.

同时NAC也对由博来霉素所介导的纤维化模型有保护作用；此外，胺碘酮和苯基呋喃类化学物，具有氧化还原环，可介导肺的氧化损害。

This research used the optical frustrated total internal reflection by the coupling of prisms to excite surface plasma waves to measure the resonant angle of the chlorine and Halogen-methane (including the fluoromethane, chloromethane, bromomethane, and iodomethane).

中文摘要本论文是根据光受挫式内部全反射方法利用稜镜的耦合来激发表面电浆波，量测出氯气与卤族甲烷(氟甲烷、氯甲烷、溴化甲烷、碘甲烷)之共振角度。

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2，4，6-三甲基苄氯，合成了一种新的手性季铵盐(1a)，并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化，得到相转移催化剂1b、1c和1d。

Racemic backbones 2-amino-2'-hydroxy-6,6'-dimethyl-l,l'-biphenyl la and 2-amino-2'-hydroxy-4,4',6,6'-tetramethyl-l,1'-biphenyl 1b were synthesized from o-methylaniline and 2,4-dimethylaniline via nitration, diazotation/iodination, Ullmann coupling, selective reduction, diazotation/hydrolysis and hydrogenation.

从邻甲苯胺及2，4-二甲基苯胺出发，经过硝化，重氮化-碘代，偶联，单还原，重氮化-水解及还原反应合成了消旋体骨架2-氨基-2'-羟基-6，6'-二甲基-1，1'-联苯1a和2-氨基-2'-羟基-4，4'，6，6'-四甲基-1，1'-联苯1b。

Result shows that the sulfur compounds in the diesel can react with iodomethane easily at room temperature, the most of sulfur compound derived into methylsulfonium salts; the homologue of benzothiophene get the higher conversion ratio and react selectivity than the homologue of dibenzothiophene. It is found that primarily sterically hindered alkylated DBT, for example, 4-or 4-, 6-DBT, is recalcitrant to be methylated.

结果表明：柴油中硫化物在室温条件下容易与碘甲烷发生甲基化反应，大部分硫化物转化为锍盐，总转化率超过80%，苯并噻吩类比二苯并噻吩类更易发生甲基衍生化反应，转化率也相应较高。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

Determination of its content by idometry is performed and the effect of acidifying with acetic acid and hydrochloric acid on the result of the test is investigated.

采用碘法滴定测其含量，并探讨了醋酸酸化和盐酸酸化对测定结果的影响。

In the one hand, for catalytic double carbonylation of phenyl iodide or catalytic hydroesterification of styrene, the effect of pressure on products ratio reflected the difference in the volume of activation of different reaction routes.

对于碘苯双羰基化反应或苯乙烯氢酯基化反应，由于不同产物反应的活化体积不同，压力对于不同反应速率常数的影响亦不相同，因此压力增大会有利于其中某个反应。

Melting point 3410 ℃, boiling point 560 ℃, relative density of 1935, F the external electronic structure of 5d46s2, in the chemical reaction time is very easy to lose 1-6 electronic, but also can get 1-2 electronic, so oxidation number of 0,± 1,± 2, 3, 4 , 5 and 6, with 6 price of the most stable compounds, such as WO3 does not dissolve in water, the air will form in the tungsten trioxide thin protective layer of tungsten, tungsten with fluorine at room temperature, chemical combination, red hot when there is no moisture and Bromine iodide together, red hot when you can and water reaction WO3, at room temperature reaction of tungsten with aqua regia, but the hot concentrated hydrochloric acid and sulfuric acid can only be played with its weak response, but molten nitrate, nitrite, too Hydrogen peroxide, sulfur steam, steam and other phosphorus can play intense reaction, high temperature can not be carbon, boron and silicon reaction of binary compounds, widely used in industrial tungsten steel and tungsten carbide, pure tungsten filament is used to the system, and X-ray tube Tube heating components, semiconductor components can be prepared tungsten silicide, tungsten industrial production is white or black tungsten ore tungsten ore refining.

熔点3410℃，沸点560℃，相对密度1935，F外围电子结构为5d46s2，在化学反应时很容易丢掉1—6个电子，也能得到1—2个电子，所以氧化数为0、±1、±2、＋3、＋4、＋5和＋6，以＋6价化合物最稳定，如WO3不溶于水，空气中的钨会形成薄层三氧化钨保护层，钨能与氟在室温下化合，红热并无潮气时能与溴、碘化合，红热时还能和水反应生成WO3，室温下钨可与王水反应，但热的浓盐酸和硫酸只能与其起微弱反应，但对熔融的硝酸盐、亚硝酸盐、过氧化氢、硫蒸汽、磷蒸汽等能起激烈反应，高温下不能与碳、硼和硅反应生成二元化合物，工业上广泛使用钨钢和碳化钨，纯钨用来制灯丝、电子管和X射线管的发热元件，硅化钨可制半导体元件，钨工业生产是将白钨矿石或黑钨矿石精炼。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。