硼烷

Asymmetric borane reduction of prochiral ketones is a good process to the synthesis of enantiomerically enriched secondary alcohols.

硼烷对前手性酮的不对称还原是合成手性仲醇的重要方法。

Using 10 as the catalyst, six prochiral ketone s were reduced enantioselectively with borane and the results were compared with those with 1,1- diphenylprolinol as catalys.

用10催化6种前手性酮的不对称硼烷还原反应，其结果与-二苯基脯氨醇催化的同一反应的结果进行了对比。

Herein we mainly discuss the design of four series of chialβ-amino alcohols and their application to the asymmetric borane reduction ofprochiral ketones.

本论文主要设计合成了四个系列的手性氨基醇类的催化剂，研究了它们在硼烷对前手性酮的不对称还原反应中的应用。

All the prepared compounds were characterized by 〓H NMR、〓P NMR and elemental analysis. The catalytic activity of each prepared chiral phosphorus compound in the borane reduction of prochiral ketones was studied.

对每一种手性磷化合物，考察了其作为配体催化剂在潜手性酮的不对称硼烷还原反应中的催化效果，讨论了影响不对称诱导的各种因素。

To strengthen the properties of Ni-W alloy, dimethylamine borane was added to an alloy Ni-W electrolyte solution and a ternary Ni-W-B alloy was electrodeposited.

为提高Ni-W合金的性能，在加入二甲基胺硼烷的Ni-W合金电解液中电沉积获得Ni-W-B三元合金镀层。

The first part is concerned with catalytic asymmetric borane reduction of aromatic ketones. Up to 83% ee could be obtained with 10 mol% Al3/BINOL2 complex as catalyst.

在不对称硼烷还原反应方面，利用BINOL作为掌性配位基与Al3组成催化系统还原芳香酮类，反应过程方便快速，最高可获得83%的镜像超越值，我们也推测了可能的反应机构并用以解释所得产物的立体化学组态。

Keywords: Enantioselective catalysis; phosphorus reagents; silylcyanation; borane reduction

中文关键词：对映选择催化；磷试剂；硅氰化；硼烷还原

3A series of C_2-symmetric chiralβ-amino alcoholsⅢ-6 andⅢ-10were synthesized in several steps from natural amino acids,and applied in the asymmetric borane reduction of prochiral ketones.The catalytic activity ofⅢ-6 was better thanⅢ-10.

3以天然氨基酸为起始原料，经过简单的几步反应合成了开链冠醚类C_2-对称的手性β-氨基醇Ⅲ-6以及Ⅲ-10，将其应用于硼烷对前手性酮的不对称还原反应中，含有脯氨醇结构单元Ⅲ-6的催化效果要好于由其他氨基酸衍生的Ⅲ-10，THF为溶剂，回流，催化量为10 mol%时，最高得到85%的ee值。

S-1-phenylethanol was obtained in up to 19%ee in toluene at 0℃.(4)A series of C_2-symmetric chiralβ-amino alcoholsⅣ-5were synthesized in several steps from natural amino acid L-proline,and applied in the asymmetric borane reduction of prochiral ketones.

4以天然L-脯氨酸为起始原料，经过几步转化合成了以萘环为母体的C_2-对称的手性β-氨基醇Ⅳ-5，将其应用于硼烷对前手性酮的不对称还原反应中，同样，我们也观测到温度影(来源：Ac1BC论文网www.abclunwen.com)响产物构型的现象。

Asymmetric catalytic activity of chiral spiroborate esters,- or-1,1′-bi-2-naphthoxyboric acid-proline anhydride [-1 or-1], toward borane reduction of prochiral imine s has been ob- served.

手性螺硼酸酯-或-1，1'-联-2-萘酚硼酸--脯氨酸酐[-1或-1]对前手性亚胺硼烷还原的不对称催化活性被观察到。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。