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硫醛

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The synthetic methods of peptide thioester and peptide aldehyde are also discussed.

还介绍了与多肽片段连接有关的肽硫酯和肽醛的合成方法。

In order to examine the catalytic activity of the new catalysts, we have carried out the direct asymmetric Aldol reaction of tetrahydro-4H-thiopyran-4-one with aldehydes.

催化剂的基本结构单元如下:为了检验新型有机催化剂的催化活性,我们研究了硫代四氢吡喃酮和各种醛的直接不对称Aldol反应。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有:乙二醛、伯胺和多聚甲醛的缩合反应;卤代烷与咪唑及其取代咪唑的烷基化反应;原甲酸酯与1,2-二胺的成环反应;肼或酰胺与酸酐的环化反应;用Na/K对环硫脲化合物的还原反应。

In the part two, we reported the classical Knoevenagel condensation between aromatic aldehydes and acyclic active methylene compounds or cyclic active methylene compounds containing heteroatom such as (2-thio)barbituric acid, Meldrum's acid using ionic liquids as reaction medium.

在第二部分中我们研究了离子液体中开链活性亚甲基化合物、杂环类活性亚甲基化合物如(2-硫代)巴比妥酸、Meldrum's酸与芳香醛之间的Knoevenagel缩合反应。

Second, we investigated the aldol reactions of the specialα-oxo ketene dithioacetals with aromatic aldehydes under the mild conditions in good yields.

在温和的条件(室温、30℃)下,高产率地实现了α-羰基二硫缩烯酮与芳香醛的缩合反应。3。

In chapter four molecular modeling method is employed to comparatively study five S-allyl γ-hydroxy ketene dithioacetals reactions of Thio-Claisen rearrangement with and without zeolite catalysts.

第四章用分子模拟途径研究了在有、无分子筛催化条件下五种丙烯基羟基乙烯酮二硫代乙缩醛Thio-Claisen重排反应。

While erthrocyte, hemoglobin and Hela cell were under oxidative damage induced by the hydrogen peroxide (H2O2) or tert-butyl hydroperoxide on different concentrations of dihydromyricetin, hemolysis rate of erythrocyte and methemoglobin converted from hemoglobin was estimated by ultraviolet-visible absorption spectroscopy. Whereas mmalondialdehyde from erythrocyte was measured by thiobarbituric acid colorimetry, the cellular viability of Hela cell was examined using MTT 3-(4, 5-dimethylthiazol-2-yl-2, 5-diphenyl tetrazolium bromide assay.

在不同的二氢杨梅素浓度下,用过氧化氢或过氧化特丁烷对红细胞、血红蛋白和Hela细胞进行氧化伤害,以紫外-可见光分光光度法检测红细胞溶血率和由正常血红蛋白生成的高铁血红蛋白,硫代巴比妥酸法测定红细胞中的丙二醛,MTT法检测Hela细胞的活力。

It manufactures heterocyclic, such as pyrazine, thiazole, furan, pyridine and sulf-compounds with their ramifications; and pharmaceutical intermediates such as veratraldehyde, isovanillin, sufurol, diacetyl, acetoin, and 2, 5-dimethyl pyrazine.

食用产品有吡嗪、噻唑、呋喃、吡啶等杂环系列及含硫系列的合成香料化合物。医药中间体产品有:藜芦醛、异香兰素、硫噻唑、丁二酮、乙偶姻、2,5-二甲基吡嗪等。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始,经过乙烯酮二硫代缩醛中间体,合成了两个5-氨基-1H-吡唑,以这个两个化合物为中间体,与芳香族和脂肪族α-溴代酮反应,而后经酸催化亚胺化互变异构后得到含咪唑并[1,2-b]吡唑甲硫醚类化合物6a-6g。

In this paper, we have initiated the relationship between molecular connectivity index and retention value in TLC for ten amino acids, eleven sulfides, six mercaptans and twenty 2,4-dinitrophenylhydrazones of aldehydes or ketones respectively.

把分子连接性指数法应用到10种氨基酸、11种硫醚、6种硫醇和20种醛、酮的2,4-二硝基苯腙薄层色谱保留值的相关性研究中。

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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在,'歼灭战perfuming自己与胡努特,那麼,他来到和SAT 。

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三叶草是爱尔兰和圣特里克节的标志同时它的寓意是带来幸运。3片心形叶子围绕着一根断茎,深绿色。