硫醚

It is found that their thermal conversion pathway of mercaptan, sulfides and disulfides can change after the addition of few methanol.

研究发现，少量甲醇添加到反应体系中可以使硫醇、硫醚、二硫化物热转化路径发生变化。

The course of thermal reaction for iso-butyl mercaptan, di-n-butyl sulfide and di-n-butyl disulfide is free radical mechanism.

对于异丁硫醇、丁硫醚、丁基二硫化物的热反应，其热转化的途径是自由基机理。

On the other hand, the corresponding bromohydroxylation of 1, 2-allenyl sulfides with Br〓 and water should be carried out in aqueous acete nitrile at 0℃.

在1，2-联烯基硫醚分子中由于同时存在着硫原子和具有两个相互垂直π-键的累积双烯结构，使其具有一些特殊的反应性能。

Halohydroxylation reaction of allenyl sulfides occurs predominately with the β,γcarbon-carbon double bonds with the halogen atom bonded to the middle carbon atom of the allene moiety.

在1，2-联烯基硫醚分子中由于同时存在着硫原子和具有两个相互垂直π-键的累积双烯结构，使其具有一些特殊的反应性能。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

Namely, only for biobriquette low presence of dialkyl sulphides and aliphatic thiols was registered.

对于生物型煤来说，仅检测到少量二烷基硫醚和脂肪硫醇的存在。

The poisoning effects of alkyl sulfur compounds on the reactivity of isoprene hydrogenation over supported Pd catalyst are more and more serious with the decrease of the molecular mass of alkyl thiols and dialkyl disulfides.

乙硫醇和二甲基二硫醚使Pd／树脂催化剂中毒的机理是，它们分别在催化剂上发生SH和S-S键断裂，并与Pd形成带烷基基团的S-Pd吸附络合物，致使催化剂上异戊二烯选择加氢活性降低。

The enzymolytic products identified were:diisopro-pylaminoethanethiol through the breakdown of P-S bond, and its oxidized product, N, N'-dithiodiethylene-bis ; and diisopropyla-minochloroethane through the breakdown of S-C bond.

VS与电鳐乙酰胆碱酯酶作用的主要产物是： P—S键断裂产物二异丙氨基乙硫醇，该化合物在水溶液中不稳定，可进一步氧化为N，N＇-双二异丙氨基乙基二硫醚；S—C键断裂产物二异丙氨基氯乙烷。

To synthesize the octreotide, Phe-Leu-Glu-Glu-Leu and C_(15)H_(31)-CO-Lys-Thr -Thr-Lys-Ser peptides, the strategies are as followings: Fmoc- group as protective group for α-NH_2; TBTU, DIEA and HOBt as coupling reagent; and ethanedithiol -phenol - thioanisole - H_2O - TFA ( 2.5:5:5:5:82.5 , V/V ) as cleaving solution.

采用Fmoc固相合成法，以苯并三哗四甲基脲四氟硼酸盐、二异丙基乙胺和1-羟基苯骈三氮唑为缩合剂；苯酚—乙二硫醇—苯甲硫醚—水—三氟乙酸(5：5：2.5：5：82.5，V/V)为切割试剂，合成了奥曲肽、Phe-Leu-Glu-Glu-Leu及C_(15)H_(31)-CO-Lys-Thr-Thr-Lys-Ser三种小分子多肽，并对奥曲肽的合成规模进行了放大。

On the contrary, sulfonated poly(arylene thioether phosphine oxide)s, with a IEC of 1.60 meq/g, even denote a swelling of 70.1% at 80oC and thus lose most of the mechanical strength.

而前述IEC为1.60 meq/g的磺化聚芳硫醚三苯基氧膦在80oC下的溶胀率为70.1%，已经出现溶胀突变，显著丧失力学强度，其耐溶胀性能比磺化聚二氮杂萘酮醚三苯基氧膦差得多。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。