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硫醚

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Compared with the composites made of high density polyethylene , carbon black and graphite by solution blending, the composites made of polyphenylene sulfide , polyarylethersulfone with cardo group , short carbon fiber and carbon black by mechanical blending are provided with better repeatability of electrical resistivity.

聚苯硫醚和酚酞型聚芳醚砜与碳纤维和炭黑机械共混所得复合材料和高密度聚乙烯与炭黑和石墨溶液共混所得复合材料相比,前者具有电阻率较易控制、重复性较好的特点。

In this study, the electrical conductive composites (comprised of thermoplastic matrix resins-high density polyethylene, polyphenylene sulfide and polyarylethersuifone with cardo group, and conductive fillers-short carbon fiber, carhon black and graphite) are prepared and characterized in detail. The relation among composite structure and directalternating electric properties, some electric and magnetic parameters under X-band microwave and shielding effect, the mechanical behaviour are analysed. And furthermore, some relative experimental devices are developed.

本工作利用短切碳纤维、炭黑、石墨为导电填料填充热塑性树脂高密度聚乙烯、聚苯硫醚、酚酞型聚芳醚砜,制得具有良好导电性能和机械性能的导电性高分子复合材料,并以此为对象,研究了材料的稳恒电场和交变电场的基本特性与材料结构的关系,研究了在X波段微波场下的电磁参量及屏蔽效应,以及研究了复合材料及其基体树脂的力学行为,与此同时还建立了相应的表征测试手段。

This paper mainly studies effect and influence factor that typical corrosive medium (muriatic acid, vitriol, nitric acid, sodium hydroxide, sodium chloride etc.), consistence and condition temperature acts on the material coated on castiron centrifugal interface (PFEP, PPS, CPE, remodeled epoxy). It is studied that powder electrostatic spray, suspend fluid spray, suspend fluid electrophoresis underside coat etc. technics influences on coat quality coated with above four anticorrosive material. The property analysis is done that above four anticorrosive material and three coat technics adapt to centrifugal pump frame and running dynamic condition. In addition, the effect is introduced that castiron centrifugal coated anticorrosive material is used in coal water with alum.

本文侧重研究了典型腐蚀工作介质盐酸、硫酸、硝酸、氢氧化钠碱、氯化钠盐等品种、浓度、环境温度,对铸铁离心泵过流面的聚全氟乙丙烯、改性聚苯硫醚、改性氯化聚醚、改性环氧四种防腐涂层材料的试验使用效果和影响因素分析;研究了四种涂层材料粉末静电喷涂、悬浮液喷涂、悬浮液电泳底涂等涂装方法工艺对涂层质量的影响;四种涂层材料和三种涂装方法对离心泵结构和运行动态环境的适应性分析;介绍了铸铁离心泵防腐涂层在煤矿矾水中的应用效果。

To our surprise we achieved the ligand 9, 11 and 29 with coordinating atoms fixing at benzylic and benzene ring positions, whose structure is unique in the planar chiral cyclophane chemistry.

以钯催化的烯丙基取代反应对配体进行了考察,硫醚或硒醚取代基在苄位取代的配体表现出更高的反应活性和更高的对映选择性,配体9和11均给出最高为94%的ee值。

Based on the principle of ester hydrolyzation to ether in alkali condition, the process for preparation of dimethyl sulfide from sodium methyl sulfate residue was investigated.

根据酯在碱性条件下水解反应生成醚的原理,研究了以甲基硫酸钠废渣为原料制备二甲基硫醚的方法。

A practical charged membrane which prepared from the blends of sulphonated polyphenylene sulfide/poly can be considered as a 3D lattices. The experimental conductivity was related with a 3D simulation and the result showed the membrane has a transition from insulator to conductor at the ratio of charged components SPPS about 0.144. Obviously, this value falls in the range of a theoretical simulation for a 3D lattices.

由於实际的荷电膜也可看作为三维格栅体系,因此,可用三维格栅体系程序对不同荷电分率膜的电导数据进行拟合,结果表明,对於实际的磺化聚苯硫醚/聚醚碸共混膜,当荷电组分SPPS的分率达到0.144时,共混膜即会从不良导体变为良导体,显然该值落在理论值0.1~0.2,因此,理论模拟结果与实际荷电膜传质的实验数据相吻合。

The redox separation conditions were investigated in detail. It was indicated that TBAPI exhibited appropriate oxidation intensity and well selectivity, thiolethers can be oxidized into sulphoxide, but it cannot oxidize thiols.

详细考察了氧化还原分离条件,实验结果表明,TBAPI具有适宜的氧化强度和良好的选择性,它能将硫醚硫氧化成亚砜,且在同条件下,对噻吩硫不起作用。

So the difficult sequence of cracking to remove the sulfur for different sulfur compounds is that thiophene, benzothiophene>alkyl side-chains of thiophenic compounds>mercaptan, sulfur ether.

总之,不同含硫化合物裂化脱硫的难度顺序为:噻吩、苯并噻吩>烷基噻吩>硫醇、硫醚

In the contaminated lard sample, 6 organic compounds have been thus identified to be the raw materials or byproducts in the production of organic tin compounds. Based on the identified contaminants, it can be postulated that the chemical structure of the organic tin compound is dibutyltin-bis-(2-isooctyl thioacetate). The method is simple and precise, and has not been reported in the local literature.Keywords Organic tin compound, Lard, SPME-GC-MS

经过摸索研究,采用固相微萃取方法富集挥发性杂质,直接注入色谱中,经色谱分离,质谱测定,确定了杂质的结构,由杂质成分推断生产有机锡所用的原料,然后判断合成路线,最后确定有机锡的结构,从有毒猪油中鉴定出2-巯基醋酸异辛酯、双(2-醋酸异辛酯)二硫、双醋酸异辛酯硫醚等6种与有机锡有关的杂质,并与相应的有机锡工业品对照,发现工业品中也含有这些杂质,与其合成过程的原料及副产物相符,从而确定有机锡化合物为二硫代醋酸异辛酯二丁基锡。

For example, in the process of aeration or oxygen exposures, oxygen together with compounds in the sewage generates a different stench; Also, in the anaerobic process, in the role of microorganisms, sulfur from the sewage, reates hydrogen sulfide, mercaptans and sulfide compounds.

例如,在曝气或曝氧过程中,氧气可与污水中的化合物生成有异臭味的产物;又如,在厌氧过程中,污水中的硫在微生物的作用下,生成硫化氢、硫醇和硫醚等化合物。

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