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硫醚

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Besides, it can degrade the sulfur in phenyl sulfide and dodecanethiol.

除此之外,它还可以脱除苯硫醚和硫醇类含硫化合物中的硫。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中,开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应,为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法;在此反应体系中,离子液体不仅起到了反应溶剂的作用,而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

Synthesis of organic sulfuric compounds in aqueous media is carried out by: using thio-olefin compounds with carbonyl compounds, acetal/keltone, hydrazone, oxime, osazone and enamine to synthesize mercaptal/keltone compounds in aqueous media; using thio-olefin compounds with alpha-hydroxyaldehyde/keltone or alpha-halogenated aldehyde/keltone to synthesize thia-olefin derivatives in a queous media; using thio-olefin compounds with alpha, beta-unsaturated hydroxy compounds, C-C treble bond, C-N treble bond, C-C double bond, N-N double bond, C-N double bond, C-S double bond, epoxy and its derivatives, aziridine and its derivatives, cyclopropane and its derivatives and halogenated carboxy to synthesize sulfoether compounds in a queous media.

含水介质中有机硫化合物的合成方法,本发明属于有机合成方法,用硫缩烯酮类化合物与羰基化合物、缩醛/酮、腙、肟、脎、烯胺在含水介质中合成缩硫醛/酮化合物,与α-羟基醛/酮或α-卤代醛/酮在含水介质中合成噻烯类衍生物,与α,β-不饱和羰基化合物、碳碳叁键、碳氮叁键、碳碳双键、氮氮双键、碳氮双键、碳硫双键、环氧乙烷及其衍生物、氮杂环丙烷及其衍生物、环丙烷及其衍生物、卤代烃等在含水介质,中合成硫醚化合物。

The X-ray diffraction shows that the resin is crystalline. The heat analysis shows that the resin is well heat-resistant and has very good thermal stability and T=101℃. The T is better 10℃ than polyphenylene sulfide. The PASI resin will be applied abraod.

表征结果表明,聚合物为设计聚芳硫醚酰亚胺结构;X射线衍射表明聚合物为结晶性聚合物;热性能测试表明,聚合物的玻璃化温度为101.91℃,高于聚苯硫醚(87.00℃),聚合物具有良好的热性能。

It is necessary to carry out a thorough study on pest control technology with DMDS, with an expectation of obtaining a new fumigant of methyl bromide alternative.2. Investigation of the toxicity of fumigation on adult and mixed stages of the three most tolerant insect species -- Sitophilus oryzae, Rhyzopertha dominica and Tribolium castaneum -- under a range of EtF、DMS and DMDS doses in a Flow-through Fumigation System shows that the FTFS procedure offers a constant concentration of fumigant with low CO2 concentrations and ensures that the fumigant toxicity is effectively not compromised by CO2. In comparison with chamber fumigation method, the toxicity data of EtF、DMS and DMDS obtained from this experiment is more accurate by using FTFS.

主要研究结果如下:1、甲酸乙酯和二甲基二硫对仓储害虫具有良好的控制作用,应加快甲酸乙酯替代溴甲烷防治仓储害虫开发应用,同时,二甲基二硫是很有潜力的仓储害虫防治熏蒸剂,要深入进行二甲基二硫控制有害生物的技术研究,以期获得新的溴甲烷替代熏蒸剂。2、利用循环熏蒸系统测定了甲酸乙酯、二甲基二硫和甲硫醚对米象Sitophilus oryzaeL。

The paper introduces the injection molding equipment, mold and molding technique for the thermotolerant engineering thermoplastic polyphenylene ether sulphone .

介绍耐高温热塑性工程塑料聚苯醚砜树脂的注射成型设备、模具和注射工艺等。相关:聚苯醚(聚2,6-二甲基苯醚),聚苯撑氧聚苯硫醚

The removal of organic sulfur such as thiofuran , thioether and mercaptan is the main objective of dry desulfurization , and hydroconversion of organic sulfur and preventing the methanation side reaction are the technological difficulties of hydroconversion desulfurization. The combination of two-level conversion and two.1evel absorption is the preferential scheme for refined removal of high-concentration organic sulfur.

脱除噻吩、硫醚、硫醇类有机硫是干法脱硫的主要目标,加氢转化有机硫并防止发生甲烷化副反应是加氢转化脱硫的技术难点,组合式两级转化、两级吸收是精脱高浓度有机硫的优选方案。

Coordination polymers of dimethyl sulfide: Using P2S5 as deoxygenating agents, three coordination polymers containing dimethyl sulfide, [4(CH3SCH3)3]n (34) and n X = Cl(35, Br(36) have been successfully synthesized.

硫醚类化合物本文首次利用P2S5作为有机物的脱氧剂,在溶剂热条件下,成功地合成3种亚铜甲硫醚配位聚合物[4(CH3SCH3)3]n (34)和n X = Cl(35, Br(36)。

By the bio-assay directed fractionation of the volative constituents.dimethyl disulfide,allyl methyl trisulfide,allyl methyl sulfide and diallyl disulfide were found to increase the beating rate and beating amplitude in a standard medium,but the compund 2-pentanone without sulfide did not affect either of them.

从具有生物活性的挥发性提取物中分离得到的二甲基二硫、烯丙基甲基三硫、烯丙基甲基硫醚和二烯丙基二硫对培养心肌细胞心率和振幅均有不同程度的增强作用,而不含硫的2-戊酮则没有作用。

A series of sulfonated poly(arylene thioether phosphine oxide)s with various degrees of sulfonation was prepared by polycondensation of 4,4'-thiobisbenzenethiol with the mixture of sBFPPO and BFPPO at different ratios. The effect of IEC on the properties of the products was studied.

以BFPPO、sBFPPO和4,4'-二巯基二苯硫醚为单体,通过改变BFPPO/sBFPPO的配比,合成了一系列不同磺化度的磺化聚芳硫醚三苯基氧膦,考察了IEC对产物性能的影响。

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