硫醇

3Nm, modified with alkylamine and alkylthiol were prepared by a simple phase-transfer method using a small Pt nanocluster stabilized by glycol and OH〓 as a building block.

四、采用"非保护型"Pt金属纳米簇作为构筑基元，通过简单的相转移方法制备了长链胺和长链硫醇修饰的Pt纳米簇。

It was observed that the Pt 4f binding energies in the same-sized Pt nanoclusters modified with alkylamine, alkylthiol, PVP, PVA or PPh〓 increase by 0.5-0.8eV relative to those of bulk Pt.

观察到具有相同金属尺寸的Pt金属内核而外层配体分别为长链胺、长链硫醇、PVP、PVA或PPh〓的纳米簇的Pt 4f电子结合能相对于块体Pt样品升高了0.5-0.8eV。

A kinetic study on the photopolymerization of MMA with benzophenone/triethylamine/mer-captan system as initiator has been carried out in the presence of oxygen.

采用二笨甲酮/三乙胺/硫醇体系作为引发剂，在含氧条件下进行了MMA光聚合反应的动力学研究。

From the aspects of statistical data,diffusibility,odor and toxicity of pollutants,it discussed the main odor pollutants such as hydrogen sulfide,sulfur dioxide, carbon bisulfide ,thior and ammonia etc.

综述了硫化氢、二氧化硫、二硫化碳和硫醇等硫化物的臭味特征、危害性、中毒症状、国家环保部门许可的排放标准及其防治办法。

The invention discloses an InP quantum point preparing method, comprising the steps of:(1) mixing InCl3 with trioctylphosphine oxide, and preserving heat at 90-110DEG C to prepare a solution whose In content is 0.1-0.3mol/L;(2) raising temperature to 130-180DEG C, and charging argon gas;(3) injecting PSi(CH333 into InCl3-TOPO compound in the molar ratio of 1 to 1-1 to 2;(4) when the solution color turns into transparent red or orange, raising temperature to 260-270DEG C and preserving heat;(5) lowering temperature to 90-110DEG C and injecting dodecyl amine, decyl amine or mercaptan;(6) dissolving reacting mixture in nonpolar solvent to form transparent colloidal solution, then adding in polar solution until the colloidal solution is muddy, and centrifugally separating and obtaining deposits and supernatant; and (7) centrifugally separating the supernatant, where the above steps (1)-(5) are performed.

本发明公开了一种InP量子点的制备方法，其步骤为：①将InCl 3 与三辛基氧膦混合，在90～110℃保温制得In含量为0.1～0.3mol/L的溶液；②升温到130～180℃，通入氩气；③将PSi(CH 3 3 3 注射入InCl 3 -TOPO复合物中，其摩尔比为1∶1～1∶2；④待溶液颜色变为透明的红色或橙红色，将升温260～270℃保温；⑤降温到90～110℃，注入十二胺、癸胺或硫醇；⑥将反应混合物溶于非极性溶剂，形成透明的胶体溶液，然后加入极性溶剂，直至胶体溶液出现混浊状，然后离心分离获得沉积物和上层清液；⑦取上层清液进行离心分离。上述步骤①～⑤在保护气氛下进行。

The results show that, in the lower voltage regime, the molecular currents decreased exponentially with the molecular length, and the corresponding decay constant is about 1.41/CH2. Furthermore, the decay constant is demonstrated to be almost independent of the external voltage.

研究结果表明，在低的外加偏压下，烷烃硫醇分子电流值随着分子链长度的增加而指数减小，其衰减常数约为1.41/CH2，且衰减常数基本上与外加偏压值的大小无关。

A decay constantβof 0.98 per methylene group is measured. Electron transport propeties for n-alkanedithiol monolayers on Au(111) is investigated using conducting atomic force microscopy.

使用导电原子力显微镜方法研究了在Au(111)表面上的硫醇分子自组装膜的电子输运特性。

After developing 48 hours, hepatocytes enters 2.0 mM t-butyl hydroperxide or 2.0 mM diamide to induced cell blebbing. The samples collected at 0, 15, 30, 60 minutes to analyze cell about membrane protein thiol deletion; the leakage of lactate dehydrodenase; the change of glutathione; the lipid peroxidation; the variation of actin and tubulin, and use Confocal fluorescent microscope to observe the change of actin and tubulin in rat hepatocytes.

肝细胞在48小时培养后，分别加入2.0mM t-buty1 hydroperoxide或2.0 mM diamide诱发细胞膜小泡生成，并分别於0、15、30、60分钟取样，分析细胞膜硫醇流失程度；乳酸去氢□渗漏；□胱甘□浓度变化；脂质过氧化；肌动蛋白与管蛋白变化；并利用雷射共轭焦萤光显微镜观察肝细胞中肌动蛋白及管蛋白的变化。

The result indicates the t-BHP or diamide both cause the mass loss about the membrane protein thiol in hepatocytes, the fast oxidization about glutathione in hepatocytes, the leakage of lactate dehydrodenase, but the level of t-BHP is larger than of diamide. In the aspect of lipid peroxidation, only the t-BHP produces apparent change. As to actin and tubulin, they both find fall-off and present time-dependency effects. The result in Confocal fluorescent microscope also show these two cytoskeletal proteins are related to cell blebbing, but they don''t play the same role during the porcess. Tubulin may be more important than actin. If the study predispose dithiothreitol before adding t-BHP or diamide, then the damage by the diamide is repressed, but just partly protection for the damage by t-BHP.

结果显示t-BHP或diamide均可造成细胞膜蛋白硫醇大量流失与胞内GSH快速氧化，亦显著导致乳酸去氢□渗漏，但t-BHP诱发的渗漏程度大於diamide；在脂质过氧化方面，则仅t-BHP处理组产生明显的脂质氧化情形；至於肌动蛋白与管蛋白单体均可见减少且呈现时间依赖效应；在雷射共轭焦萤光显微镜观察中，亦显现这两种架构蛋白与细胞膜起泡有关，但两者在小泡生成的过程中扮演的角色并不完成相同，可能管蛋白较肌动蛋白重要；如果细胞在t-BHP或diamide加入前预先以dithiothreitol处理，则diamide 所造成的伤害显著的受到抑制，但DTT对t-BHP所诱发的伤害则仅有部分保护效果。

Results show that the best value of w is 7~10% and 5~7%, i is 0.08~0.2 A/cm^2 and 0.03~0.05 A/cm^2 respectively, during the electrolysis fluorination of pyridine and tributylamine; the addition of N-butyl mercaptan into the organic mixture can stabilize electrolysis process with its mass fraction 15~20% at best; impulse current polarization work status of low load is helpful to the electrolysis process and reduces corrosion rate of anode; electrolysis temperature is suitable at 0~20℃; electrobath can use electrolyte inner circulation structure, exterior circulation structure or blending structure.

结果表明：吡啶和N-三丁胺电解氟化的最佳值w分别为7%~10%和5%~7%，i分别为0.08~0.2A/平方公分和0.03~0.05A/平方公分；有机混合物中添加N-丁基硫醇可稳定电解过程，其质量分数最佳为15%~20%；采用低负荷的脉冲电流极化工况有利电解过程，降低阳极的腐蚀速度；电解温度0~20℃为宜；电解槽可采用电解液内循环、外循环结构，或其混合结构。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。