硫醇

Octyl mercaptan may exist in the base oil or continue to decompose to volatile low molecular mercaptan or H 2S.

辛硫醇有可能存在于基础油中，或在摩擦热的作用下继续分解生成挥发性的低分子硫醇或硫化氢挥发掉

There are mainly two ways to sweeten light oils: removal of mercaptan from the lightoils, and oxidation of mercaptan to less harmful disulfide.

轻质油品脱臭主要从两个途径达到脱臭目的，一是除去油品中的硫醇，二是将油品中的硫醇转化为危害性较小的二硫化物。

The results of the dissertation were concluded as follows:(1) It is essential to deposit a basic additive on the Mo-based catalysts for the synthesis of CH_3SH. The potassium-doped Mo-based catalysts exhibit the highest activity than that of the catalysts doped with the otherⅠA andⅡA group basic promoters. H_2-TPR and LRS characterizations suggest that the addition of a base leads to the transformation of octahedrally coordinated Mo to tetrahedrally coordinated Mo, thus leads to the split of low temperature reduction peaks. The interaction between the basic components and Mo lead to the formation of B-Mo interface phase, which are closely correlated with the formation of CH_3SH.(2) It has been found that Fe, Co, Ni and Te have evident promoting effects for the K-Mo/SiO_2 catalysts.

主要结果归纳如下：(1)在Mo基催化剂中，必须添加碱才具有可观的合成甲硫醇活性，在IA和IIA族元素中，K是最佳的碱促进剂，当K/Mo摩尔比为2，前驱体为K_2CO_3，采用共浸法制备的K-Mo催化剂活性最高。H_2-TPR和LRS表征显示，碱的加入导致表面八面体钼氧物种向四面体转化，催化剂的低温还原峰发生分裂，碱助剂与钼之间存在强相互作用形成了B-Mo"界面相"，该物种与合成甲硫醇密切相关。

The study reveals the change of cell type is related to thiol in cell, especially cytoskeletal proteins.

本实验显示细胞形态的改变确与胞内硫醇，尤其是细胞架构蛋白硫醇有关。

In order to investigate the activity of bi-CoSPc to the higher thiol oxide, the 1-octanethiol oxidation rate was determined, the result showed that, the rate of 1-octanethiol oxidation increased with rising of reaction temperature, concentration of catalyst, and concentration of alkali.

结果表明：在相同反应条件下，与CoSPc相比，bi-CoSPc对正辛硫醇的氧化过程具有更高的催化活性；反应温度的升高，催化剂浓度的增加及碱液浓度的提高，均有利于硫醇的催化氧化反应。

Gas-phase reactions of Al〓 with ethanethiol molecule have been studied for the first time.

首次研究了Al〓和乙硫醇的气相化学反应，结果观察到了Al〓与1～6个乙硫醇分子形成的团簇离子。

Thiol groups were good to be used in functionalizing gold nanoparticles, and ester bond formation and breakage played the major role in this research. Thioctic acid and 11-mercapto-1-undecanol were used to functionalize the gold nanoparticles and form ester bond by using the carboxylic acid group on thioctic acid and the hydroxyl group on 11-mercapto-1-undecanol. Concentrated sulfuric acid was used to be the catalyst in this reaction, and sodium hydroxide was added for the proceeding of the reverse reaction.

硫醇官能基在金奈米粒子的修饰有很好的效果，利用带有硫醇官能基之tioctic acid 与11-mercapto-1-undecanol (11-MUDO)分子修饰在金奈米粒子上，并使TA上之羧基和11-MUDO上之羟基脱水生成酯化键，浓硫酸则是反应中的催化剂，而氢氧化钠则可促使系统进行逆反应。

Acetaldehyde(0\^1 mol) was treated with n propylthiol(0\^1 mol) at 35 ℃ for 20 min to yiled 72% acetaldehyde propyl mercaptal .

以 0 。1 mol乙缩醛和 0 。1 mol 正丙硫醇为原料，35℃下在四氯化碳中反应，经红外光谱，色谱，质谱，元素分析以及核磁共振谱检测，确证了产物为乙醛正丙硫醇缩醛。

The kinetics for the catalytic oxidation of mixed thiol s with different catalyst particle sizes was studied in the gas-liquid-solid triphase reaction system.

用室内实验的方法对气-液-固三相催化反应体系中不同粒径催化剂催化下混合硫醇的氧化反应动力学进行了研究，并依据球形催化剂假设，采用薄膜理论对反应体系中硫醇浓度分布进行了分析，计算出不同粒径催化剂的有效因子。

Furthermore, the jellium model was used to analyze the characteristic of SPR; the dipole model and the IR spectrum were used to form a new dipole model.,It can be used to explain the mechanism of the red shift.4. The preparation of DDT-modified gold nanoparticles and the dicuss of theiroptical propertiesWe preparated DDT-modified gold nanoparticles using Brust approach.

十二烷基硫醇修饰的金纳米颗粒的制备及对其光学性质的探讨本文采用了Brust法制备了硫醇修饰的金纳米颗粒，用电镜进行了表征，表明制出的金纳米颗粒粒径比较均一，而且在浓度相当的情况下，能够通过化学键与范德瓦尔斯力之间的相互作用形成有序结构。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。