硫醇

In chapter three, the activating agents of ytterbium have been examined. Barbier-type reaction promoted by ytterbium metal was examined. The experimental results shown that the yield of Barbier reaction of imines with allylic bromide promoted by ytterbium is higher than that of aldehydes and ketones with allylic bromide under the same reaction conditions. In this chapter, the reductive cleavage of Se-Se and S-S bond induced by ytterbium metal was also studied.

首先研究了金属镱的活化剂以及活化方法，接着考察了金属镱促进的Barbier反应及其在合成高烯丙基胺和高烯丙基醇中的应用，以及影响该反应的主要因素；究了金属镱促进的二硫醚和二硒醚的S—S键和Se—Se键的还原断裂，继而与氯代烃，胺基甲酰氯反应生成相应的硫醚，硒醚，胺基甲酸硫代酯和硒代酯。

In the present study, Hartree-Fock and Density Functional Theory with different basis sets were employed to calculate the structural and thermodynamic parameters of 66 thiophenyl, phenyl sulfoxide and phenylsulfonyl cycloalkane carboxylates. With the statistic software SPSS11.5 for windows and GQSARF2.0, the QSAR models relating physicochemical properties of these compounds to their structural and thermodynamic parameters were successfully obtained, using multiple stepwise regression method. The physicochemical properties observed in this work include octanol/water partition coefficient, chromatographic capacity index, toxicity (EC50 and LC50), and solubility etc.

本文采用从头算方法中的Hartree-Fock 方法、密度泛函理论方法(Density functional theory，简称DFT)中的不同基组，计算了苯硫基、苯亚砜基和苯砜基含硫芳香羧酸酯三类共66 个化合物的结构参数和热力学参数，利用SPSS11.5 for windows 统计软件和GQSARF2.0 软件，采用多元逐步回归法拟合得到与溶质-溶剂相互作用有关的物理化学性质与结构参数和热力学参数之间的QSAR 方程，这些物理化学性质包括辛醇/水分配系数、色谱容量因子、毒性(EC50和LC50)、溶解度等。

Result The results showed that its components were quite complex, and 89 organic compounds were identified. There were 72 kinds of oxygen-containing organic compounds which included esters, phenols, aethers, ketones and alcohols in the depolymerization product, small amounts of alkanes, alkenes, arenes, thiophenol and nitrogen-containing organic compounds were also detected, which showed that characteristics of the product with high oxygen content, low nitrogen and sulphur content.

结果］超临界乙醇解聚产物成分十分复杂，GC/MS分析鉴定出89种有机化合物，其中72种为含氧化合物，主要有酯、酚、醚、酮和醇等，还检测出少量烷烃、烯烃、芳烃、苯硫酚和含氮化合物，反映了解聚产物的高含氧量和低含氮硫量的特性。

According to the current researches its ingredients are volatile(isothiocyanate,thymol,palmitic acid etc),indole,flavonoid,sitosterol,glucosinolate and some novel compounds; Capparis spinosa possesses other activities,such as antimicrobial and antifungal,anti-inflammatory,antihepatotoxic,antioxidant,hypolipiddemic and hypoglycaemic,diuretic,treating gout.

野西瓜中含有挥发油(异硫氰酸酯、麝香草酚、棕榈酸等)、吲哚类、类黄酮类、谷甾醇类、葡萄糖异硫氰酸盐及一些结构新颖的化合物；野西瓜除具有抗风湿的作用外还具有抗菌、抗炎、抗氧化、抗高血压、降血糖血酯、利尿、治疗痛风等方面的作用。

Apart from the clear effects on crop growth and grain yield, limiting availability of S has been shown to favour the synthesis and accumulation of S-poor or low-S storage proteins such as ω-gliadin and high molecular weight subunits of glutenin at the expense of S-rich proteins. These changes in protein composition are associated with alterations of dough rheology. Significant responses of breadmaking quality to the addition of S fertilisers have been observed under field conditions.

hm^(-2)左右。缺硫除了对小麦生长和产量有影响，籽粒偏向于合成和积累贫硫或低硫贮存蛋白，如ω-醇溶蛋白和高分子量谷蛋白亚基，而蛋白质组成的变化与面团流变学特性改变有关，大田条件下增施硫肥显著改善了面包品质。

SDS-PAGE showed ,these two proteins' molecular weight is respectively 26KDa and 18KDa,both of which do not have intermolecular disulphide group.

经SDS-PAGE鉴定，这两种蛋白质的分子量分别为26.0 KDa和18.0 KDa，在经还原剂二硫苏糖醇处理后的电泳结果表明这两种蛋白均为不含有分子间二硫键的蛋白单体。

Fresh algal extracts prepared in 0.5 M HCl were neutralised, purified on a SPE column (RP-18, Merck), lyophilised in the presence of 1 mM dithiothreitol to prevent the formation of disulphide bridges and stored at -/20℃.

食藻提取物中拟定0.5米盐酸被瓦解，纯化的固相萃取柱（RP-18， Merck），lyophilised，在场的1毫米二硫苏糖醇，以防止形成二硫键桥梁和储存在-/20℃。

The beta-thioalkoxyalcohols could be obtained in good yields by the reaction of dialkyl-substituted propargylic dithioacetals with a series of carbonyl compounds.

我们发现在铁触媒和格林那试剂的存在下，利用双烷基取代炔丙基硫缩酮和羰基化合物反应生成的beta-硫烷氧基醇，可以进行不常见的beta-氧消去反应，而得到烯炔衍生物。

Results Eleven compounds were obtained and identified as sarcodonin A, scabronine B, 3β-hydroxy-5α, 8a-epidioxyergosta-6, 22-dien,(22E, 24R)-ergosta-7, 22-diene-3β, 5α, 6β-triol,(22E, 24R)-ergosta-7, 22-diene-3β-ol, benzoic acid, 4-hydroxylben-zaldehyde, 4-monopropanoylbenzenediol, ethy1-β-D-glucopyranoside, thioacetic anhydride,(2S, 2'R, 3S, 4R)-2-(2-hydroxyoctadecanoylamino) docosane-1, 3, 4-triol.

结果共分离鉴定了11个化合物，分别是：sarcodonin A、scabronine B、3β羟－5α，5α-过氧麦角甾－6，22-二烯－3β-醇、(22E，24R)-麦角甾－7，22-二烯－3β，5α，6β三醇、(22E，24R)-麦角甾－7，22-二烯－3β-醇、苯甲酸、对羟基苯甲醛、对羟基苯甲酸乙酯、乙基－β-D-吡喃葡萄糖苷、硫代乙酸酐、（25，2'R，3S，4R）-2-（2-羟基－十八碳酰胺）二十二碳烷－l，3，4-三醇。

The research presented here is aimed at exploring the effect of DTT on the in vitro fibril formation of hen egg-white lysozymes with four disulfide bonds. In this work, we specifically addressed the effect of DTT concentration under different incubation temperatures on the hen lysozyme structure and fibril formation, the effect of addition of DTT at later time points on the amyloid fibrillization of hen lysozymes, and the effect of concentration ratio between reduced and oxidized forms of DTT on the fibril formation of lysozymes.

本研究以具有四对双硫键的母鸡蛋白溶菌酶为蛋白质模式系统，在含盐类之酸性溶液环境下诱导生成类淀粉纤维，再配合二硫代苏糖醇破坏溶菌酶中的双硫键，探讨：（1）不同温度下加入不同DTT浓度对溶菌酶类淀粉纤维形成之影响，（2）不同生长时期加入DTT对溶菌酶类淀粉纤维形成之影响，（3）不同比例之DTT和氧化态DTT浓度对溶菌酶类淀粉纤维形成之影响。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。