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The results show that, after treated with microwave radiation, the surface free energy of the powder is enhanced from 39.6mJm^(-2) to 41.8mJm^(-2), This is mainly caused by the rearrangement of electric charges on the grain crystal surface, and this phenomenon is coincident with the theory of electron transition caused by energy band splitting of the grain crystal surface.

测定结果显示微波辐射后硫酸钙粉末的表面自由能得到提高,从39.6mJm^(-2)增加到41.8mJm^(-2),其主要原因是使硫酸钙表面能的极性成分得到了较大的提高。这一结果归于微波幅射引起晶粒表面的电荷重排,与晶粒表面能带分裂引起的电子跃迁理论是相吻合的。

The stabilization process of hemihydrate calcium sulfate whiskers with several additives was studied in different additive amounts, reaction times and temperatures.

使用多种稳定剂对半水硫酸钙晶须进行稳定化处理,研究了稳定剂用量、稳定化处理温度和时间等对半水硫酸钙晶须稳定性的影响。

Testing methods including SEM, FT-IR and XRD were adopted to analyze the surface topography, surface groups and phase composition of the hemihydrate calcium sulfate whiskers before and after the stabilization treatment.

采用SEM,FT-IR,XRD等测试方法分析了油酸钠稳定化处理前后半水硫酸钙晶须的表面形貌、表面基团、物相组成,在此基础上研究了油酸钠对半水硫酸钙晶须的稳定化机理。

According to such a trend, the best molar ratio of microcline:CaSO4:CaCO3 is 1:1:14, which is further validated by experiments.

根据这种趋势得出钾长石-硫酸钙-碳酸钙热分解体系最佳的物料(钾长石/硫酸钙/碳酸钙)摩尔配比为1: 1:14,并对此进行了实验验证。

Through the experiments on hydration of AH in the following sulphate(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4), dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程,以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究,说明复盐理论不正确;CaSO_4在(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4)溶液中水化,水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化,与激发剂阳离子Z/R值大小无关,阳离子的Z/R参数影响水化率的规律并不存在; 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行,CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度,CaSO_4·2H_2O获得结晶的驱动力,可溶性硫酸盐起到形成晶核的作用:水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相,作为异质微粒使母相中存在不均匀性,这些不均匀性有效地降低成核时的表面能位垒,使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成,因此这些物质起成核催化剂作用。

MIIGX3 was absorbed 4 weeks postoperatively and generally completely absorbed 12 weeks postoperatively. Injecting region of MIIGX3 was coincidence with normal cancellated bone 6 months postoperatively. The Rasmussen score was 25.8 of 20 patients after 6 months and 26.9 of 12 patients after 12 months.

术后4周高强度可注射硫酸钙开始明显吸收,术后12周基本吸收,术后6个月高强度可注射硫酸钙植入区域与正常松质骨一致。20例术后半年Rasmussen膝关节功能平均25.8分,12例术后1年Rasmussen膝关节功能平均26.9分。

Wound exudations were observed in two cases and the bacterial culture was negative. MIIGX3 was absorbed 4 weeks postoperatively and generally completely absorbed 12 weeks postoperatively. Injecting region of MIIGX3 was coincidence with normal cancellated bone 6 months postoperatively.

术后4周高强度可注射硫酸钙开始明显吸收,术后12周基本吸收,术后6个月高强度可注射硫酸钙植入区域与正常松质骨一致。20例术后半年Rasmussen膝关节功能平均25.8分,12例术后1年Rasmussen膝关节功能平均26.9分。

MethodsCaS/PLA/GM implant tablets were made from composite of citrated calcium sulfate and polylactic acid mixed with gentamycin at a certain ratio. According to ISO 10993-1 standards, following biological experiments were performed to evaluate the biocompatibility and safety of the CaS/PLA/GM delivery system, as well as haemolysis, cytotoxicity, pyrogenic, and intramuscular implanting tests.

本实验以已研制的生物可降解柠檬酸化硫酸钙[2]作为抗生素载体,研制新型抗生素释放系统-硫酸钙/聚乳酸/庆大霉素释放系统(calcium sulfate/polylactic acid/genta-mycin CaS/PLA/GM),对其生物相容性进行评价。

Purpose The clinical prospects of injectable calcium sulfate were verified through the mechanical tests, degradation and osteogenesis abilities' experiments, and the physicochemistry characteristics and biomechanical appreciation were evaluated.

对可注射式硫酸钙理化性能和生物相容性进行检测,通过动物实验研究其力学稳定性、降解性能及成骨性能,探讨可注射式硫酸钙的临床应用能力。

The borate surfactant SBW-181 was used for the modification experiments of calcium sulphate whiskers on the conditions of individual factors.

采用硼酸酯表面活性剂SBW-181对硫酸钙晶须进行了单因素条件改性试验,分别考察了改性剂用量、改性温度、改性时间和搅拌速率等工艺因素对硫酸钙晶须表面改性的影响。

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