硫酸化

This article provided a new route to produce 4-dimethoxy phenethylamine. In basic condition, the product could be obtained through etherization, bromation, Grignard reaction, hydroxyethylation, esterification and Gabriel reaction with phenol as raw material, the overall yield is 45.0%.

提出了合成4-甲氧基苯乙胺的新方法，即在碱性条件下，苯酚首先与硫酸二甲酯反应，再选用高选择性的溴化剂溴化后，经格氏反应、羟乙基化反应和酯化反应，最后经Gabriel反应可以制备目标产物，反应总收率为45.0%。

The method is realized by that polyether ether ketone is added into concentrated sulfuric acid to carry out sulfonation reaction, thereby obtaining sulfonated polyether ether ketone, then the sulfonated polyether ether ketone is dissolved in organic solvent, N, N (1)-Carbonyldiimidazole is added to stir for one to three hours, coupling agent is mixed for stirring the reaction for 1.5 to 4 hours, then inorganic crosslinking agent is mixed to react under the temperature of 50 to 80 DEG C. Proton conductors are mixed to continue getting the mixed solution of the sulfonated polyether ether ketone or the inorganic crosslinking agent or proton conductors under the temperature. Finally the proton exchange membrane for a direct methanol fuel cell is obtained by that the mixed solution of the sulfonated polyether ether ketone or the inorganic crosslinking agent or proton conductors is/are processed through membrane forming, drying and exuviation.

该方法首先将聚醚醚酮加入浓硫酸中进行磺化反应得到磺化聚醚醚酮；然后将磺化聚醚醚酮溶于有机溶剂中，加入N，N′-羰基二咪唑搅拌1～3小时后加入偶联剂搅拌反应1.5～4小时，再加入无机交联剂在50～80℃下反应，然后加入质子导体继续在此温度下反应得到磺化聚醚醚酮/无机交联剂/质子导体的混合溶液；最后将磺化聚醚醚酮/无机交联剂/质子导体的混合物溶液成膜，干燥，脱膜即得到所述的直接甲醇燃料电池用质子交换膜。

The method on trans fatty acids analysis in food is very important. The effects of methylate sodium, potassium hydroxide, sulfuric acid and boron trifluoride in methanol and their different concentration and dosage on TFA analysis were studied. The chromatographic condition and the influence of time and temperature on the esterifation of TFA using boron trifluoride in methanol were optimized. A method for analyzing TFA were established by GC based on boron trifluoride in methanol and RT-2560(100m×0.25mm×0.2μm) capillary column.

研究了甲醇钠－甲醇、氢氧化钾－甲醇、浓硫酸－甲醇和三氟化硼－甲醇4种甲酯化试剂的浓度、用量及甲酯化时间和温度对反式脂肪酸检测的影响，优化了色谱条件，建立了以三氟化硼－甲醇法甲酯化，RT-2560(100m×0.25mm×0.2μm)毛细管柱为基础的反式脂肪酸气相色谱检测方法，C18：1-9 t， C18：1-11 t， C18：2-9 t， 12 t和C22：1-13 t 4种反式脂肪酸的最小检出浓度在0.774.08 mg/kg之间。4种反式脂肪酸不同添标浓度回收率为98.44%101.23%，重复测定的相对标准差在0.22%1.31%之间，有较好的准确度和重现性。

Through lots of tests, the new technology of preparing the polymeric ferric aluminum silicate sulfate by using the waste-acid of Ti02-industriy and the coal fly ash has been designed. The highest Al-acid stripping rate can be achieved by the waste sulfate acid under boiling degree for 1. 5h when the mass ratio between NaCl and Coal Fly ash is 0. 05:1, as well as that between Coal Fly ash and Waste Acid ratio is 1:10. By means of the oxidation-polymerized reaction under 40-50*C and normal pressure, using NaNCkas catalyst and air as oxidation, the polymeric ferric aluminum sulfate can be obtained. The poly-silicic acid is polymerized with soluble glass in the optimum conditions of pH=5-6 and the concentration of Si02 is about 3%. The inorganic high molecule coagulant of PFASS is synthesized with the poly-silicic acid into the solution of polymeric ferric aluminum sulfate.

本论文通过大量的试验，研究开发出了用粉煤灰及钛白废酸制取聚合硫酸硅酸铁铝的新工艺，其最佳工艺条件为：于沸点温度，以NaCl为助溶剂(NaCl与粉煤灰质量比为0.05：1)，以钛白废酸浸取粉煤灰(固液比为1：10)中的铝1.5小时，最大浸取率可达40％；经过滤洗涤后，调节滤液pH至2.0左右，以NANO_2为催化剂(NaNO_2用量为滤液中FeSO_4·7H_2O量的3％)，空气为氧化剂，于40-50℃进行常压催化氧化反应，制取聚合硫酸铁铝，催化氧化时间为2小时；将工业水玻璃稀释至3％左右，调节其pH于5-6，室温下制备活性聚硅酸；将活性聚硅酸与聚合硫酸铁铝按照一定比例复合，经熟化，即制得新型无机高分子混凝剂PFASS。

Based on single factor experiment including esterify ing temperature, esterify ing time,and vitriol dosage,the conditions for esterify ing free fatty acid were optimized by response surface methodology and by determining acid value and content of V_E as evaluation indexes.

本研究在酯化温度、酯化时间和浓硫酸用量三个单因素试验的基础上，利用响应面分析法，以酯化后脱臭馏出物的酸价和VE含量为评价指标，对游离脂肪酸酯化条件研究。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

Acidic aqueous ferric sulfate was abstained by heating maturating, dissolving and filtration process of mixture of pyrite cinders and sulfur acid.

摘 要：硫铁矿烧渣是硫酸制备过程中产生的固体废弃物。将硫铁矿烧渣与硫酸混合后，经过熟化、水溶、过滤得到酸性硫酸铁溶液。

I plant perennial supply of chemical plating material: nickel sulphate, chloride nickel, nickel nitrate, ammonium chloride, sodium hypophosphite, sodium citrate, ammonium citrate, potassium citrate, chromium oxide, red Lead oxide, palladium chloride, SnCl2, crystal tin tetrachloride, the resistance of fuse, lithium fluoride, sulfuric acid cadmium, Na2HPO4, bismuth chloride, bismuth oxide, oxide Thallium sulfate Cobalt, cobalt nitrate, cobalt chloride, barium hydroxide, calcium hydroxide, fine chemical products.

我厂常年供应化学镀材料：硫酸镍、氯化镍、硝酸镍、氯化铵、次亚磷酸钠、柠檬酸三钠、柠檬酸三铵、柠檬酸钾、三氧化铬、红色氧化铅、氯化钯、氯化亚锡、结晶四氯化锡、电阻熔断剂、氟化锂、硫酸镉、磷酸氢二钠、氯化铋、三氧化二铋、三氧化二铊、硫酸钴、硝酸钴、氯化钴、氢氧化钡、氢氧化钙等精细化工产品。

The physical,chemical character and usage of magnesium sulphate were introduced in this paper,the production method and process of magnesium sulphate were also expounded.

介绍了硫酸镁的物理、化学性质和用途，阐述了硫酸镁的生产方法及工艺流程：硫酸法，盐湖苦卤法，苦卤复晒法，高温盐溶浸法，震荡转化法，碳酸化法，二氧化硫催化法。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。