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硫酰胺

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Acetamide and thiouera had the parallel effect with GdnCl on the renaturation of lysozyme , both of them were able to prevent the aggregation of peptide, and at the high concentration they were able to restrain the refolding of peptide , but the structure of lysozyme under experiment condition could not be destroyed by them.

乙酰胺和硫脲则起着和盐酸胍近似的作用,能够抑制肽链间的聚集和肽链内的折叠,但是两者在本实验浓度内不能使溶菌酶变性。

By the reactions ofα-acylamino ketene--acetals and oxalyl chloride, a serie of pyrrolidinetriones were prepared.

通过α-酰胺基二硫缩烯酮和草酰氯的反应,成功制备了一系列吡咯烷酮类化合物。

A series of 2-acetylformanilides were prepared,followed by thiolation with Lowesson reagent to afford 2-acetylthioformanilides,which further reacted with Mn3·2H2O in glacial acetic acid under microwave irradiation to afford 2-acetyl benzothiazole s.

合成了一系列的硫代酰胺,研究了它们在微波辐射醋酸锰作用下发生氧化自由基环化反应,成功地合成了一系列2-乙酰基苯并噻唑衍生物,其结构经红外光谱、核磁共振谱和质谱得到了证实

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能,共由以下六部分组成:1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应;2、亚甲基环丙烷类化合物开环产物的偶联反应;3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应;4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应;5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应;6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1,3-偶极环加成反应。

A new chelating fiber containing thioamide group is synthesized by cross-linking of polyacrylonitrile fiber with ethylene-dimine and following with chemical modification with sodium sulfide using DMF as solvent.

以腈纶纤维为起始原料,经乙二胺预交联后,以DMF作溶剂与硫化钠反应,合成了一种硫代酰胺功能基可达6.8mmol/g干纤维的螯合功能纤维,其对贵金属金、银离子具有良好的吸附性能。

Base on the analysis, organophosphate inducible system has been established by treatment of the swimming seedling and drenching roots with organophosphate solution. This inducible system consists of model plant Arabidopsis thaliana and methamidophos, folimat or methyl parathion which are the representative types of highly toxical OPs. Meanwhile, the responses of the esterase isozymes and the total soluble proteins to OPs in Arabidopsis thaliana have been detected by Native-PAGE and SDS-PAGE.

在此基础上,采用模式植物拟南芥和甲胺磷、氧化乐果和甲基对硫磷三种极具代表性的高毒高残留有机磷农药,通过水培和灌根的方法,建立了有机磷诱导系统,并应用变性与非变性聚丙烯酰胺凝胶电泳技术,研究了拟南芥酯酶同功酶和可溶性总蛋白对有机磷胁迫的响应。

Mesoporous zincum sulfide is synthesized by gentle wet chemosynthesis method, with DDA as templates and Zinc acetate and TAA as precursors. The effect to the synthesis of the ratio of reactive components, the volume of pH, reactive time and reactive temperature has been dicussed systematically, and structures of the as-synthesized samples have been characterized by X-ray diffraction, N2 adsorption-desorption, scanning electron microscopy, Fourier transform-infrared spectra, UV-vis diffuse reflectance spectroscopy, transmission electron microscopy.

以十二胺为模板,醋酸锌及硫代乙酰胺为前驱体,温和湿化学法合成了硫化锌无序介孔结构,系统研究了反应物配比、pH值、反应温度、反应时间对材料合成的影响,运用X射线衍射、N2吸附-脱附、扫描电镜、红外光谱、紫外-可见吸收光谱、透射电镜等分析手段对介孔材料的结构进行了详细的表征。

Preferably, at least one member selected from among heterocyclic compounds having any of hydroxyl, carbonyl, carboxyl, amino, amido and sulfinyl and containing at least either a nitrogen or a sulfur atom is contained in the polishing solution.

优选其中包含杂环化合物,所述杂环化合物含有羟基、羰基、羧基、氨基、酰胺基和亚磺酰基中的任1种,且含有氮和硫原子中的至少1种。

Amine catalysts are used for preparation of thioamides by the addition reaction of nitriles with hydrogen sulfide.

在胺催化下,硫化氢和腈加成反应生成硫代酰胺,其原子经济性为100%,是一个绿色化学合成方法。

It undertakes fuel oil, polymer, paraffin wax and chemical fibre, with the main products of non-lead gasoline, light diesel fuel, 20# heavy diesel fuel, topped oil, naphtha, aviation kerosene, cracked diesel oil, fuel oil, base oil, isomer dewaxing oil, liquid petroleum gas, propane, propylene, MTBE, benzene, toluene, xylene, paraffin wax, polyacrylamide, acrylonitrile, ammonia sulfate, semi-refined asphalt, acrylon, furfural extract oil, liquid nitrogen, etc, totaling 338 varieties and more than 100 kinds of brands.

它的主要产品有:高标准清洁汽油、无铅汽油、轻柴油、重柴油、航空煤油、化工轻油(拔头油、裂化原料油、石脑油)、燃料油、&老三套&基础油、异构脱蜡基础油、液化石油气、丙烷、丙稀、MTBE、石蜡、聚丙稀酰胺、丙稀腈、硫胺、硫磺、三苯、半炼沥青、腈纶、糠醛抽出油、液氮等38种100多个牌号的石油化工产品,产品辐射全国25个省、市、自治区。2000年销售收入119.9亿元。

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They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性,但我大喊,并在他们的方向扔石头让他们过的线索,远离我,以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。

Store this product in a sealed, lightproof, dry and cool place.

密封,遮光,置阴凉干燥处。