硫酰基

The Nterminal cyclization of peptides, as one of a variety of modification introduced in sample preparation, has been preliminarily studied in this work.

目前，肽段鉴定时常用的添加残基修饰有甲硫氨酸的氧化和半胱氨酸的氨乙酰化，而对其它修饰研究很少。

The results show that it only takes 8 min for the reaction, when the initiator is potassium persulfate/sodium thiosulfate which forms an oxidation-reduction initiator system; N,N-methylene diacrylamide is as cross-linker; neutralization degree is 70%, under the microwave power of 360 W.

结果表明，在360W的微波辐射功率下，采用过硫酸钾与硫代硫酸钠的氧化还原引发体系，N，N-亚甲基双丙烯酰胺为交联剂，接枝单体的中和度为70%时，只需8min就可以完成纤维素基高吸水树脂的接枝共聚合成。

The method applied is in accordance with that of the PRC National Standard for the determination of urease activity in soya bean products.

参考了中华人民共和国国家标准大豆制品中尿素酶活性测定方法，进行了正丁基硫代磷酰三胺活性的测定。

Methods Naloxone was synthesized starting from oxidation of thebaine, followed by hydrogenation, acylation, cyanidation, O-demethylation, hydrolyzation and N-allylation. The alternative method of O-demethylation, methane sulfonic acid/DL-methionine and hydrobromic acid were investigated.

在以蒂巴因为原料，经氧化、氢化、酰化、氰化、去氧甲基、水解、N-烯丙基化得到纳洛酮的合成路线中，分别采用甲磺酸／DL-甲硫氨酸和氢溴酸代替三溴化硼进行去氧甲基化和后续水解反应。

Objective: To investigate the arrest effect of diallyl disulfide in the cell cycle of human nasopharyngeal carcinoma CNE2 cell line and its molecular mechanism.

目的：在前期工作的检测上，进一步探讨二烯丙基二硫(diallyl disulfide， DADS)对人鼻咽癌CNE2细胞周期的阻滞作用，并研究组蛋白乙酰化状态及其调控p21WAF1蛋白表达改变的情况。

For the smelting slags of exhausted automobile catalyst, a method for determination of trace amounts of platinum and palladium by plus-dual-wavelength overlapping spectrophotometry in dibenzyl dithiooxamide-SnCl2 system was developed.

针对失效汽车催化剂火法熔炼渣，研究了采用正峰双波长叠加，二苄基二硫代乙二酰胺-SnCl2体系萃取光度法测定渣中痕量铂钯的方法。

The alternative method of O-demethylation,methane sulfonic acid/DL-methionine and hydrobromic acid were investigated.

方法在以蒂巴因为原料，经氧化、氢化、酰化、氰化、去氧甲基、水解、N-烯丙基化得到纳洛酮的合成路线中，分别采用甲磺酸/DL-甲硫氨酸和氢溴酸代替三溴化硼进行去氧甲基化和后续水解反应。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合，采用双氧水为氧化剂，在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应，手性亚砜的对映选择性为72％-95％ee，产率为42％-83％。

The side chain of thioacetic acid has been sythesized from the material of acetic acid via four steps, then synthesized the key intermediate of 2-hydroxypenem via displacement, P〓induced cyclization and hydrolyzed reaction from the material of azetidinone.

以羟乙酸为原料，经四步反应合成了侧链化合物硫基取代的羟乙酸，发生取代反应导入到经七步合成的单环氮杂环丁酮中，然后发生酰化，Wittig诱导环化，水解等五步反应合成关键中间体2-羟甲基青霉烯。

On the basis of the above N-vinylaiton of amides,the Cu-catalyzed intramolecular C-S coupling of thiols was implemented for the first time with CuI (10 mol%) as the catalyst and K_3PO_4·3H_2O2 equiv.

在酰胺氮烯基化研究的基础上，我们进而开展了烷基硫醇分子内烯基化反应研究。

They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.

他们没有侵略性，但我大喊，并在他们的方向扔石头让他们过的线索，远离我，以防万一。

In slot 2 in your bag put wrapping paper, quantity does not matter in this case.

在你的书包里槽2把包装纸、数量无关紧要。