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硫酰

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A reaction pathway for ammonolysis of O,O-dimethylphosphorochloridothioate without catalyst was proposed,based on the reaction mechanism of acyl halide ammonolysis ,and the pseudo-homogeneous reaction kinetics were founded.

模型表明:在反应前期,O,O-二甲基硫代磷酰氯浓度对速率影响很小,反应速率呈拟一级反应特征;但在反应后期,反应速率呈明显的二级反应特征。

In the first step of thedouble annulation route, 2-amino-3-carbamoyl-5,6-dihydro-4-pyridones 2 werecreated in high to excellent yields by a formal [5C + 1N] annulation reaction ofketene--acetals 1 with ammonia.

第一步,二硫缩烯酮1和氨源通过[5C + 1N]加成反应产率极高的得到了2-氨基-3-氨基甲酰基-5,6-二氢-4-吡啶酮2。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有:乙二醛、伯胺和多聚甲醛的缩合反应;卤代烷与咪唑及其取代咪唑的烷基化反应;原甲酸酯与1,2-二胺的成环反应;肼或酰胺与酸酐的环化反应;用Na/K对环硫脲化合物的还原反应。

Objective To observe the effects of Astragalus injection of different doses on TAA-induced acute liver injury in rats.

目的 观察不同剂量黄芪注射液对硫代乙酰胺所致大鼠急性肝损伤的影响。

In this thesis, a series of benzamides and thioureas derivatives have been designed and prepared. By reasonable photoreaction conditions, a series of benzophenone and quinazoline compounds have been synthesized and structurally determined by NMR, MS and X-ray crystallography, respectively.

本文设计并合成了一系列苯甲酰胺和硫脲衍生物,通过选择合理的光反应条件,合成了一系列二苯甲酮和喹唑啉类化合物,应用核磁、质谱以及X-射线衍射技术对这些化合物的结构进行表征。

CdS nanoarods have been synthesized by using Cetyltrimethyl Ammonium Bromide as the soft template under γ-irradiation through the reaction of cadmium sulphide (CdSO4·8/3H2O) and thiacetamide in acidic condition for pH value of 3. The physical and chemical properties and the structure of CdS nanorods were characterized by XRD, UV-Vis, SAED, TEM and PL.

在pH=3的酸性条件下,以硫酸镉和硫代乙酰胺为反应前驱体,采用十六烷基三甲基溴化铵自组装形成的管状胶束为模板,通过γ射线辐照法成功合成了CdS纳米棒,并通过XRD、UV-Vis、SAED、TEM和PL等技术对反应中间产物及最终产物进行了表征。

The Nterminal cyclization of peptides, as one of a variety of modification introduced in sample preparation, has been preliminarily studied in this work.

目前,肽段鉴定时常用的添加残基修饰有甲硫氨酸的氧化和半胱氨酸的氨乙酰化,而对其它修饰研究很少。

The role of arginine to assist protein refolding was similar to that of acetone, both of them were able to combine with the denature lysozyme and improve the refolding yield.

结果表明,与自发复性收率(40%)相比,复性液中添加精氨酸、甘油、乙酰胺、丙酮、硫脲、海藻糖和甜菜碱均能有效提高变性溶菌酶的复性收率。

Hepatic sinusoid capillarization plays an important role in occurrence of portal hypertension. The fenestra of endothelial cells in hepatic sinusoid reduces and the diameter of fenestra decreases. The formation of basement membrane impaires the substance exchange between blood and hepatic cells,which results in oxygen deficiency, metabolic product accumulation and cell necrosis.

肝窦毛细血管化在硫代乙酰胺诱导的肝硬化门脉高压发生中起重要作用,肝窦内皮细胞窗孔减少并减小,内皮细胞下基底膜形成使肝细胞与外界物质交换减少,导致细胞缺氧、代谢产物聚集,肝细胞坏死,最终导致门脉高压的发生。

objective to explore the protection effect of genistein on hepatic injury induced by taa and its possible clinical application.

目的 探讨染料木素对硫代乙酰胺所致肝损伤的保护作用,并分析其可能的临床应用价值。

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