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In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2,3-d]嘧啶的方法,此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵,二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

In this thesis, a series of benzamides and thioureas derivatives have been designed and prepared. By reasonable photoreaction conditions, a series of benzophenone and quinazoline compounds have been synthesized and structurally determined by NMR, MS and X-ray crystallography, respectively.

本文设计并合成了一系列苯甲酰胺和硫脲衍生物,通过选择合理的光反应条件,合成了一系列二苯甲酮和喹唑啉类化合物,应用核磁、质谱以及X-射线衍射技术对这些化合物的结构进行表征。

A kinetic study on the photopolymerization of MMA with benzophenone/triethylamine/mer-captan system as initiator has been carried out in the presence of oxygen.

采用二笨甲酮/三乙胺/硫醇体系作为引发剂,在含氧条件下进行了MMA光聚合反应的动力学研究。

The columna soil study showed that strain NBT had the ablity of potassiumuptake ,making losed potassium from the soil inoculated with the bacterium wasdecreased by

通过土柱试验发现,硅酸盐细菌NBT菌株还具有保钾功能,供试土壤接菌处理后的土壤滤液中流失的钾比对照减少35.5-56.5%,经方差分析,差异达显著水平;另外,硅酸盐细菌NBT菌株与农药的相容性试验表明,无论在大田农药施用浓度和残留浓度内的丁草胺、绿黄隆、三唑酮粉、多菌灵、马拉硫磷等农药对NBT菌株没有抑制作用;乐果、甲基1605在大田施用浓度下,对NBT菌株有一定抑制作用,而在残留浓度下,对NBT菌株无明显抑制作用。

By applying density functional theory, the relationships between the electron structures and the complexation of the two types of bis-β-diketone ligands (dithiol-γ-linked or alkyl-γ-linked) were investigated, based on the polarized continuum model of the self-consistent reaction field. Using the model B3LYP/6-31G**, the geometries of the ligands were optimized and the electron structure changes calculated.

基于自洽反应场中的极化连续介质模型,采用密度泛函理论B3LYP/6-31G**计算了以二硫醚和芳环为桥基的两类双β-二酮配体的空间构型和电子结构,结合其配合物晶体结构数据,研究配体分子电子结构与配位性的关联性。

Cancer patients receiving drugs, long-term use of certain chemicals such as common gentamycin, received allopurinol, hyperthyroidism, sulfur uracil, three pairs of ketone, propranolol, dilantin sodium, aspirin, indomethacin, contraceptive and cause trichomadesis.

肿瘤病人接受抗癌药物治疗,长期使用某些化学制剂如常用的庆大霉素、别嘌呤醇、甲亢平、硫尿嘧啶、三甲双酮、普萘洛尔、苯妥英钠、阿司匹林、消炎痛、避孕药等常引起脱发。

In another direction, the radical cyclization of thioimide with acylsilane produced simple cyclization product in low yield without expected enol silyl ether compound.

对於硫醯亚胺与矽基酮的自由基反应,则是得到低产率的简单环化产物,而不是预期的烯醇矽醚化合物。

The most adverse effects of risperdal were weight gain, liver dysfunction and extrapyramidal side effects.

利培酮组主要不良反应为体质量增加、肝功能损害和锥体外系症状;奎硫平组主要不良反应为嗜睡和头昏。

Orange in the flavonoids in the intestine into hydroxy benzoic acid and ferulic acid, which can strengthen the role of thyroid suppression thiocyanate, which induce or cause goiter.

橙色的黄酮类化合物在肠道成羟基苯甲酸和阿魏酸,可加强硫氰酸抑制甲状腺,而诱发或导致甲状腺肿大的作用。

Therefore, studies on the synthesis and the applications ofα-alkenoyl ketene dithioacetals should be a valuable research project.

因此,α-烯酰基二硫缩烯酮的合成及其在合成中的应用研究是一重要的研究课题。

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I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时,滚道或滚动元件褪色是很常见的特征。

The lawyer's case blew up because he had no proof.

律师的辩护失败,因为他没有证据。