硫脲

Chapter two 4-Hydroxybenzoic acid is connected with PEG6000 through defoliant DCC at rooom temperature, then the product is refluxed with chloroacetic acid in acetone to afford PEG-bound phenyloxyacetic acid, which is reacted with thionyl chloride, ammonium thiocyanate and arylamines in turn to give PEG-bound disubstituded thioureas. After the cleavage with sodium methoxide in methanol, the eleven disubstituted thioureas are obtained.

第二章 利用PEG6000作载体，通过脱水剂DCC在室温下将对羟基苯甲酸以酯键连接在PEG6000上，再与氯乙酸在较温和的条件下生成PEG6000支载的芳氧乙酸，然后，依次与亚硫酰氯、硫氰酸铵、芳胺反应，生成PEG6000支载的硫脲，最后用甲醇钠的甲醇溶液切割PEG，得到了十一种1，3-二取代硫脲。

P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.

丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物，用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2，4-二硝基氟苯2，4-dinitrofluorobenzene，二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应，生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid， DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate， PITC)在弱碱性条件下，与氨基酸反应在弱碱性条件下，生成苯乙内酰硫脲 PTH衍生物，(phenylthiohydantoin， PTH)衍生物，即PTH-氨基酸，此反应又称之Edman反应，该反应是蛋白质或多肽氨基酸序列测定常用的反应。

The quality and inhibition efficiency of thiourea, allylthiourea and phenylthiourea self-assembled films were studied by electrochemical impedance spectroscopy and polarization curves, respectively.

利用电化学阻抗谱和极化曲线研究了硫脲、烯丙基硫脲、苯基硫脲在金属铜表面上的自组装膜的质量和缓蚀效率，并通过量子化学计算进一步研究了各种分子和金属铜的相互作用。

These coordination compounds mostly have group ⅡB metals as center ions. The complexes are classified with ligand as three types: thiourea type, allylthiourea type and thiosemicarbazone type.

这类配合物大都以ⅡB族金属为中心离子，根据配体不同可分为硫脲类、烯丙基硫脲类及缩胺基硫脲类3种类型。

The complexation behavior of these compounds with linear or aromatic dicarboxylate was investigated by the means of absorption, emission spectra,〓H-NMR and molecular dynamics.

结果显示，二羧酸盐阴离子与双链萘基脲／硫脲哌嗪化合物发生络合形成新的物种导致双链萘基脲／硫脲哌嗪化合物的吸收和荧光光谱行为的变化。

Three new kinds of thiourea - type chelating cotton cellulose, thiourea cellulose, thiosemicarbazide cellulose and diphenylthiourea cellulose, were synthesized in our Lab, and their absorptive characteristics for copper was investigated.

将自制合成的三种新型硫脲型螫合纤维素——硫晚棉纤维，氨基硫脲棉纤维和二苯硫脲棉纤维应用于钢的吸附性能的研究，采用火焰原子吸收法测定选择了吸附和解吸的最佳条件。

The oxidant 〓 plays indirect role in dissolving gold, and mainly controls the mix potential of Au in the alkaline thiourea solution. In which the "mix potential"is the decisive factor affecting the dissolution of gold. The reaction driving force is enough to have formamidine disulfide oxidize Au to Au〓 at the potential of about 0.4V. And then thiourea molecular complexes with Au〓 ion soon, which causes the fast dissolution of gold in the alkaline thiourea media. The dissolved weight of gold in 0.25 M thiourea solution with 0.05M Na〓SO〓 and 0.1M 〓 of pH 12. 5 by air at the temperature of 303K is 7. 8mg·cm〓 within 1hr.

在碱性硫脲溶金过程不起直接作用，而是通过S〓O〓来控制二硫甲脒有效形成的金在溶液中的混合电位；&混合电位&是影响碱性硫脲溶液溶金与否的决定性因素，在0.4V左右，有足够的推动力致使二硫甲脒氧化Au成Au〓，随后硫脲与Au〓络合形成稳定的络离子Au〓，从而使金快速溶解；温度为303K、pH为12.5时，在含0.05MNa〓SO〓、0.1M 〓及0.25M硫脲的溶液中，鼓入空气，金的溶解量在1hr内为7.8mg·cm〓；铜只有微量溶解，银、镍、铁则几乎不溶解。

The purpose of this thesis is just to search a novel synthesis of thiourea, and to use thiourea in dealing with the waste water from the production of phthalic anhydride, and the application of thiourea in solid-state reactions at low heating temperature was also studied.

本论文研究的目的就是寻找一种合成硫脲新的工艺过程，且尝试以合成得到的产物硫脲应用于工业苯酐废水的处理，同时对硫脲在低热固相化学中的应用进行了初步的探索。

In the first part, five new 4-acyl pyrazolone 4-ethyl-thiosemicarbazones compounds: 1-Phenyl-3-methyl-4-(4-bromo)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone (PM4Br BP-ETSC), 1-Phenyl-3-methyl-4-(4-methyl)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbaz -one (PM4MBP-ETSC), 1-Phenyl-3-methyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarba -zone, 1,3-diphenyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone and 1-Phenyl-3-methyl-4-phenylacetyl-pyrazol-5-one N(4)-ethyl-thiosemi -carbazone have been synthesized and characterized by elemental analyses, IR, 1H NMR spectra and single-crystal XRD.

第一部分合成了五个4-酰基吡唑啉酮缩4-乙基-氨基硫脲化合物：1-苯基-3-甲基-4-（4-溴）苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4BrBP-ETSC)，1-苯基-3-甲基-4-(4-甲基)苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4MBP-ETSC)，1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲，1，3-二苯基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲和1-苯基-3-甲基-4-苯乙酰基-5-吡唑啉酮缩4-乙基-氨基硫脲，其中前四个具有光致变色性质。

On the basis of these principles and requirements,in this paper,a new modifier has been synthesized from pyromellitic dianhydride and thiosemicarbazide by the nucleophilic addition of anhydride,the cyclization of acyl thiosemicarbazide in alkaline solution,and the N-hydroxymethylation of the triazole-thione.

本文根据这一思路，以均苯四甲酸二酐和氨基硫脲为起始原料，通过酸酐的亲核加成反应、酰氨基硫脲的碱性环化反应、三唑硫酮环的N-羟甲基化反应合成出了一种新的N-羟甲基三唑硫酮酸改性剂。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。