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硫氰酸酯

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The electrochemical device using the sulfonate-based compound containing a cyano group, an isocyanate group, a thiocyanate group and/or an isothiocyanate group as an additive for electrolytes can provide significantly improved high-temperature lifespan characteristics.

所述电化学装置使用含有氰基、异氰酸酯基、硫氰酸酯基和/或异硫氰酸酯基的磺酸酯基化合物作为电解质用添加物,因而能够提供明显改善的高温寿命特性。

P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.

丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物,用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2,4-二硝基氟苯2,4-dinitrofluorobenzene,二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应,生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid, DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate, PITC)在弱碱性条件下,与氨基酸反应在弱碱性条件下,生成苯乙内酰硫脲 PTH衍生物,(phenylthiohydantoin, PTH)衍生物,即PTH-氨基酸,此反应又称之Edman反应,该反应是蛋白质或多肽氨基酸序列测定常用的反应。

According to the current researches its ingredients are volatile(isothiocyanate,thymol,palmitic acid etc),indole,flavonoid,sitosterol,glucosinolate and some novel compounds; Capparis spinosa possesses other activities,such as antimicrobial and antifungal,anti-inflammatory,antihepatotoxic,antioxidant,hypolipiddemic and hypoglycaemic,diuretic,treating gout.

野西瓜中含有挥发油(异硫氰酸酯、麝香草酚、棕榈酸等)、吲哚类、类黄酮类、谷甾醇类、葡萄糖异硫氰酸盐及一些结构新颖的化合物;野西瓜除具有抗风湿的作用外还具有抗菌、抗炎、抗氧化、抗高血压、降血糖血酯、利尿、治疗痛风等方面的作用。

Part two: Using chloroformic ester reacted with potassuim thiocyanate to get thiocyanic esters. Then reacted with biological substituted pyrimidinamine to synthesize forty two thiourea compounds, thirty eight of them are new compounds. Their structures have been charactered by IR, 1H NMR and elemental analysis.

第二部分:先以氯甲酸酯和硫氰酸钾为原料合成异硫氰酸酯,再与有生物活性的取代氨基嘧啶反应,合成了一系列新的取代嘧啶基硫脲类化合物,合成的42个化合物中有38个为首次合成的新化合物,结构经元素分析、IR及~1H NMR得到确证。

Benzyl isothiocyanate and phenethyl isothiocyanate, are derived isothiocyanates from cruciferous vegetable, including watercress, broccoli and cabbage.

苯甲基异硫氰酸酯和苯乙基异硫氰酸酯是来自於十字花科蔬菜的衍生物,常见的十字花科蔬菜包含了花椰菜、甘蓝菜、芥菜…等。

A reversed-phase high performance liquid chromatographic method was established for determination of isothiocyanates in human urine , which used the reaction of propyl isothiocyanate with 1,2-benzenedithiol as reference instead of the synthesis of 1,3-benzodithiole-2-thione.

省去合成1,3 苯二硫杂环五烯 2 硫酮这一步骤,直接用异硫氰酸丙基酯与1,2 苯二硫酚反应作标准,建立了尿液中异硫氰酸酯的反相高效液相色谱测定方法。

Benzyl isothiocyanate and phenethyl isothiocyanate induced apoptosis of DU-145 cells which also were confirmed by DAPI staining and DNA gel electrophoresis.

除此之外,苯甲基异硫氰酸酯和苯乙基异硫氰酸酯也会造成人类前列腺癌细胞株DU-145粒线体膜电位的改变,活性氧化物质和钙离子的释放以及造成DNA的损伤。

Western blotting show that benzyl isothiocyanate and phenethyl isothiocyanate treatment gradually decreased the level of anti-apoptotic proteins, but increased the level of pro-apoptotic proteins.

接著,由西方点墨法的结果发现苯甲基异硫氰酸酯和苯乙基异硫氰酸酯会造成人类前列腺癌细胞株DU-145凋亡蛋白的增加和Caspase活性的上升。

In this study, we investigate the effect of benzyl isothiocyanate and phenethyl isothiocyanate on human prostate cancer DU-145 cells, the results demonstrate that benzyl isothiocyanate and phenethyl isothiocyanate induced cause G2 / M phase arrest and apoptosis. These effects are in a dose- and time-dependent manners.

但是苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的凋亡机转则尚未有较详细的报导,所以本研究即是探讨苯甲基异硫氰酸酯和苯乙基异硫氰酸酯造成人类前列腺癌细胞株DU-145的相关凋亡机转。

Firstly, headspace solid-phase microextraction was established to determine AITC by orthogonal design. Extraction temperature, stir speed, extraction time, and desorption time were set at 40℃, 900r/min, 30min, and 5min, respectively. Under these optimal conditions, volatile flavor compounds in mustard oil, wasabi, and 'Chongcai'leaf mustard product were identified by SPME/GC/MS. In these three samples, 6,12,17 constituents were identified respectively; Allyl isothiocyanate was the main flavor compound, which accounted for 73.45%, 64.25%, 32.74% of total volatile compounds, respectively. Carbon disulfide, a hydrolysis product of AITC, accounted for 14.37% 25.40%, 51.67% of total volatile compounds respectively. There were some other isothiocycannates, such as butane, 1-isothiocyanato-, isobutyl isothiocyanate, 1-benzene, 4-isothiocyanato-, benzene (2-isothiocyanatoethyl)-, etc.

首先采用正交实验设计优化固相微萃取技术的前处理条件,结果表明,以萃取温度40℃、搅拌速度900r/min、萃取时间30min、解吸时间5min为最佳条件;在此最优条件基础上,利用SPME/GC/MS联用技术分析芥末油、青芥辣、冲菜的挥发性风味成分,分别检出6、12、17种化合物,主要风味物质均为AITC,相对丰度分别为73.45%、64.25%、32.74%;AITC的水解产物二硫化碳的相对丰度分别为14.37%、25.40%、51.67%;还检测到了其它几种异硫氰酸酯,如异硫氰酸丁酯、异硫氰酸异丁酯、异硫氰酸丁烯酯、2-苯乙基异硫氰酸酯等。

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