硫氰酸基的
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The electrochemical device using the sulfonate-based compound containing a cyano group, an isocyanate group, a thiocyanate group and/or an isothiocyanate group as an additive for electrolytes can provide significantly improved high-temperature lifespan characteristics.
所述电化学装置使用含有氰基、异氰酸酯基、硫氰酸酯基和/或异硫氰酸酯基的磺酸酯基化合物作为电解质用添加物,因而能够提供明显改善的高温寿命特性。
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P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.
丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物,用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2,4-二硝基氟苯2,4-dinitrofluorobenzene,二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应,生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid, DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate, PITC)在弱碱性条件下,与氨基酸反应在弱碱性条件下,生成苯乙内酰硫脲 PTH衍生物,(phenylthiohydantoin, PTH)衍生物,即PTH-氨基酸,此反应又称之Edman反应,该反应是蛋白质或多肽氨基酸序列测定常用的反应。
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Part III, 12-benzyl dehydroabietyl thioisocyanate was synthesized from methyl 12-benzyl dehydroabietic acid, by hydrolysis, chloride, Curtius reaction to give isocyanate which was hydr- olysied to amine under acidic condition, and with the method of CS2 at last, the maximal excitat- ion wavelength was bathochromic shifted 14nm compared to DDHA-NCS.
第三部分,从12-苯甲酰基脱氢松香酸甲酯出发,经过水解,酰氯化、Curtius reaction得到异氰酸酯,在酸性条件下水解成胺,最后由二硫化碳法得到一种新的荧光衍生试剂12-苯甲酰基脱氢松香酸异硫氰酸甲酯,与DDHA-NCS相比,最大激发波长红移了14nm。
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Part two: Using chloroformic ester reacted with potassuim thiocyanate to get thiocyanic esters. Then reacted with biological substituted pyrimidinamine to synthesize forty two thiourea compounds, thirty eight of them are new compounds. Their structures have been charactered by IR, 1H NMR and elemental analysis.
第二部分:先以氯甲酸酯和硫氰酸钾为原料合成异硫氰酸酯,再与有生物活性的取代氨基嘧啶反应,合成了一系列新的取代嘧啶基硫脲类化合物,合成的42个化合物中有38个为首次合成的新化合物,结构经元素分析、IR及~1H NMR得到确证。
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In this paper, quantum chemistry methods were used to investigate themicrocosmic reaction mechanisms and dynamics of a series of activatenitrogen-, sulfur- and halogen-containing radicals and some smallmolecules in the gas phase theoretically, including isocyanic acid,isothiocyanic acid and ketenyl radical.
本研究论文是采用量子化学理论和计算方法,对异氰酸 HNCO、异硫氰酸 HNCS 及其自由基、乙烯酮自由基 HCCO 与若干气相含氮、硫、卤素的活性小分子自由基反应的微观反应动力学进行理论计算研究。
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In this paper, quantum chemistry methods were used to investigate the microcosmic reaction mechanisms and dynamics of a series of activate nitrogen-, sulfur-and halogen-containing radicals and some small molecules in the gas phase theoretically, including isocyanic acid , isothiocyanic acid and ketenyl radical .
本研究论文是采用量子化学理论和计算方法,对异氰酸HNCO、异硫氰酸HNCS及其自由基、乙烯酮自由基HCCO与若干气相含氮、硫、卤素的活性小分子自由基反应的微观反应动力学进行理论计算研究。
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In this paper, the structures and the synthesis methods of glycosyl isothiocyanates are summarized, including the application as intermediates in the preparation of glycosylthioureas, glycosylheterocycles, glycosylguanidins and glycosylconjugates and so on.
本文对糖基异硫氰酸酯的结构、制备方法,以及作为中间体在糖基硫脲、糖基杂环、胍基糖苷、糖基缀合物等重要化合物的合成中的应用作了较详尽阐述。
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A reversed-phase high performance liquid chromatographic method was established for determination of isothiocyanates in human urine , which used the reaction of propyl isothiocyanate with 1,2-benzenedithiol as reference instead of the synthesis of 1,3-benzodithiole-2-thione.
省去合成1,3 苯二硫杂环五烯 2 硫酮这一步骤,直接用异硫氰酸丙基酯与1,2 苯二硫酚反应作标准,建立了尿液中异硫氰酸酯的反相高效液相色谱测定方法。
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The volatile components were separated and identified using GC-MS technique. RESULTS Seven ingredients were. isolated: 2-ethyl-hexyl-adipate (66.5%), 1-methoxy-4-(1-propenyl)benzene (12.5%), isopropyl isothiocyanate (6%), isobutylisothiocyanate (6%), 6-methyl-5-heptene-2-one (3.5%), benzaldehyde (1.4%), phenylacetaldehyde (0.8%).
结果 分离出7个成分,采用峰面积归一化法确定了各成分的相对含量,分别为66.5%双-2-乙基己基-己二酸、12.5%1-甲氧基-4-(1-丙烯基)苯、6%异硫氰酸异丙酯6%、6%异硫氰酸异丁酯、3.5%6-甲基-5-庚烯-2-酮、1.4%苯甲醛、0.8%苯乙醛。
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A novel polymeric organic thermal stabilizer for PVC was designed and synthesized by acryloylthiourea grafting on polystyrene which was nitrified by HNO3 and then reducted by Sn powder to amine.
以经部分硝化和还原的低分子量聚苯乙烯为母链,利用其胺基和丙烯酰基异硫氰酸酯加成,合成了一种新型有机高分子型PVC 热稳定剂——丙烯酰基硫脲接枝聚苯乙烯,其结构经IR和元素分析表征。
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For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether
年美国个人破产法的一个改动使得破产登记急速下降,而后引起了信用卡大规模的亏损。
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Eph. 4:23 And that you be renewed in the spirit of your mind
弗四23 而在你们心思的灵里得以更新
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Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.
老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。