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In microwave condition Ce~(4+) may oxidize sulfur compound such as the benzothiophene mainly in diesel fuel into sulfonea for the first time. By choosing proper solvent DMF to extract sulfonea, thus in microwave condition sulfur content in diesel fuel is reduced from 554ppm to 96ppm, up to 82.7% desulfurization ratio.

3微波条件下首次使用Ce~(4+)来氧化柴油中的硫化物并把这类硫化物氧化成砜类化合物,再选用合适的溶剂DMF,把这些砜类化合物通过萃取的方法除去,微波条件下的氧化脱硫可以将柴油中的硫含量从554ppm降到96ppm,达到82.7%的脱硫率。

In supersonic condition Ce~(4+) may oxidize sulfur compound such as benzothiophene mainly in diesel fuel into sulfonea for the first time. By choosing proper solvent to extract sulfonea, thus sulfur content in diesel fuel is reduced from 554mg/L to 25mg/L, up to 95.5 % desulfurization ratio and the sulfur content of diesel oil by oxidization meet to the quality standard of diesel oil in World Fuel standard III.

2在超声条件下首次使用Ce~(4+)来氧化柴油中的硫化物并把这类硫化物氧化成砜类化合物,再选用合适的溶剂DMF,把这些砜类化合物通过萃取的方法除去,从而将柴油中的总硫含量从554ppm降到25ppm,达到95.5%的高脱硫率。

Theenvironmental risk of leachate from landfill with different operation modes depend ontheir accumulation amount rather than their sudden concentrations and fraction.(7)The high SRB metabolism activity and the accumulation of metabolitewere the main reasons of in-situ precipitation phenomenon of Cu~(2+) and Zn~(2+) inlandfill refuse in bioreactor landfill. Heavy metals in bioreactor landfill havemechanism of in-situ immobilization controlling by SRB metabolism. Thepredominant SRB in landfill refuse belongs to Desulfovibrio vulgaris sp.

7生物反应器填埋场中较高的SRB代谢活性及其逐步累积的代谢产物硫化物是填埋垃圾中的Cu~(2+)和Zn~(2+)形成硫化物沉淀而发生重金属原位固定现象主要原因,生物反应器填埋场中重金属存在原位固定的硫酸盐还原菌调控机理,初步从形态判断填埋垃圾中的优势硫酸盐还原菌属普通脱硫弧菌属Desulfovibriovulgaris sp。

Heterogenic structure within the deposit has great influence on the distribution of the temperature fields. The distributions of black smokers in mature hydrothermal deposit are related with many factors, such as heat source and permeability.

4海底热液硫化物矿体的分层和不均一性在很大程度上控制着矿体内的温度场结构和流体运移模式;矿体底部边界的热源位置和介质渗透率是控制大型海底硫化物矿体黑烟囱流体喷出位置的两个重要因素。

These processes resulted i n the formation of peculiar dunites in the hyperbasite complexes ,development of low-sulfide horizons and hortonolite dunites in the basite-hyp erbasite layered intrusions (platinum-group metal deposits),and specific proces ses of transmagmatic sulfurization of the iron-rich igneous differentiates (Cu -Ni sulfide and Cu-Zn-Pb sulfide ores).

这些作用导致产在超基性杂岩中的特殊纯橄榄岩、基性超基性层状侵入体中的低硫层和铁镁橄榄石纯橄榄岩的形成,以及富铁火成分异岩的透岩浆硫化作用(Cu-Ni硫化物和Cu-Zn-Pb硫化物矿石)。

The metal elements of the volcanic-hosted massive sulfide deposit have two sources, the copper and zinc are derived from rhyolitic magmas whereas the lead are probably related to old sediments overlying the rhyolites.(4) It is suggested here that the volcanic rocks hosting massive sulfide deposit in the north Qilian orogen, which are previously considered as a bimodal suite of Neo-proterozoic to middle Cambrian age in a continental rift, are virtually related to subduction magmatism in Ordovician age, and there might have no continental rift magmatism of Neo-proterozoic to middle Cambrian in the north Qilian.

Th/Ta比高(5.0~11.7),εNd为较大的负值(-2.6~-8.4),流纹岩的形成可能是两个端元组分混合的过程、或是上地壳混染的结果,形成在活动陆缘环境;(3)北祁连块状硫化物矿床成矿金属物质具有两种来源,Cu、Zn等来源于流纹岩,而Pb的来源可能与古老沉积物有关;(4)本文认为,前人厘定的北祁连新元古代-中寒武纪赋存块状硫化物矿床的大陆裂谷双峰式火山岩应是与俯冲作用有关的奥陶纪火山岩,说明北祁连可能不存在新元古代-中寒武纪的大陆裂谷活动。

Since H〓S and SO〓 adsorbed on TiO〓 could react with each other and TiO〓 is the medium of their electron transfer, thus SO〓 could not be adsorbed quite strong on the active site of TiO〓, which makes it more resistant to sulfating and increase the stability of catalyst. Finally, the model and mechanism of the reduction of SO〓 by NH〓 to elemental sulfur is advanced as follows: on the sulfide catalyst, ammonia is decomposed to N〓 and H〓, and H〓 reacts with SO〓 to form the intermedium of H〓S; then H〓S and SO〓 react as Claus reaction on TiO〓 catalyst.

反应系统中过量水蒸气的存在使催化剂表面某些活性位被水蒸气抑制使活性和选择性有较大幅度降低,但这种影响是可逆的,不会造成催化剂永久性中毒;另外当单质硫和水蒸气同时存在时,在〓催化剂上能够生成硫化氢和二氧化硫,而且由于硫化氢和二氧化硫化学吸附能力不同而导致它们的脱附顺序不同,硫化氢的生成温度总是低于二氧化硫的生成温度,说明过量水蒸气的存在会导致氧化物催化剂上逆克劳斯反应的发生;而在硫化物催化剂上几乎没有硫化氢和二氧化硫生成,说明硫化物催化剂能够抑制逆克劳斯反应的发生。

To a certain extent, the oxidation of sulfide and releasing of heavy metals were controlled by the chemical characteristics of hydrological environment. This process gave rise to the formation of the metastable secondary metal-bearing minerals on the surface of sulfide in the sediment.

河流水体环境化学性质影响了沉积物中硫化物氧化作用的氧化速率,导致硫化物表面亚稳定的次生富重金属矿物相的形成,对水体质量的自净有一定的作用。

A detailed discuss in selection of detector, chromatographic column, method of preconcentration in gas chromatographic determinations, which is the most practical technique among analysis of sulphur-containing compounds, and prospects of analytical testing techniques for volatile organic sulfur in water are presented in this paper.

气相色谱技术是测试该类物质的实用技术,从检测器的选择、色谱柱的选择和预富集方法三个方面详细介绍了采用气相色谱分析水中微量挥发性有机硫化物过程中遇到的主要问题和解决方法,并展望了水中微量挥发性有机硫化物分析测试技术的发展方向。

A detailed discuss in selection of detector, chromatographic column, method of preconcentration in gas chromatographic determinations, which is the most practical technique among analysis of sulphur-containing compounds, and prospects of analytical testing techniques for volatile organic sulfur in water are presented in this paper. Contents

气相色谱技术是测试该类物质的实用技术,从检测器的选择、色谱柱的选择和预富集方法三个方面详细介绍了采用气相色谱分析水中微量挥发性有机硫化物过程中遇到的主要问题和解决方法,并展望了水中微量挥发性有机硫化物分析测试技术的发展方向。

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