硫化物

PART 3 : DETERMINATION OF HYDROGEN SULFIDE, MERCAPTAN SULFUR AND CARBONYL SULFIDE SULFUR BY POTENTIOMETRY.

硫化物的测定。第3部分：用电位计对碳酰基硫化物和硫醇，硫化氢的测定

According to gold deposit minerogenetic process,there are many kinds of altered mineral associated silicolites,pyrites and multiple metal sulfides.

根据金矿床成矿过程中有各类蚀变体—硅化体、黄铁矿化和多金属硫化物伴生，针对测区存在覆盖层厚和高压线密集的客观环境，勘查金矿时选择CSAMT和TDIP单极-偶极测深进行构造及硫化物空间位置的圈定，在勘探区应用地球物理方法取得了较好地质效果。

Isotherms of benzothiophene on the activated carbon were separately measured at different temperature, and then the variation of the adsorption of benzothiophene on the activated carbon was discussed with the help of the hard and soft acid and base principle.

结果表明，活性炭表面负载Ag^＋、Ni^2＋、Cu^2＋或Zn^2＋离子，可提高活性炭吸附苯并噻吩硫化物的能力，而活性炭表面负载Fe^3＋或Co^3＋离子，反而降低了活性炭吸附苯并噻吩硫化物的能力，这主要是活性炭表面的酸碱性质发生变化。

In microwave condition Ce~(4+) may oxidize sulfur compound such as the benzothiophene mainly in diesel fuel into sulfonea for the first time. By choosing proper solvent DMF to extract sulfonea, thus in microwave condition sulfur content in diesel fuel is reduced from 554ppm to 96ppm, up to 82.7% desulfurization ratio.

3微波条件下首次使用Ce~(4+)来氧化柴油中的硫化物并把这类硫化物氧化成砜类化合物，再选用合适的溶剂DMF，把这些砜类化合物通过萃取的方法除去，微波条件下的氧化脱硫可以将柴油中的硫含量从554ppm降到96ppm，达到82.7％的脱硫率。

The results showed that loading Ag^＋, Ni^2＋, Cu^2＋ or Zn^2＋ ion on the activated carbon obviously improved its adsorption of benzothiophene, while loading Fe^3＋ or Co^3＋ ion on the activated carbon caused a decrease in its adsorption of benzothiophene in comparison with the original unloaded activated carbon, which was due to the variation of the nature of soft and hard acid on the surface of the activated carbon.

采用密度泛函数理论法计算结果表明，苯并噻吩的电负性χ为2.638，属软碱类物质；由于Ag^＋为软酸，活性炭负载Ag^＋离子，增加了其局部表面的软酸，从而增强了对苯并噻吩硫化物的吸附；由于Ni^2＋、Cu^2＋和Zn^2＋离子属交界酸，负载Ni^2＋、Cu^2＋、Zn^2＋离子增加了活性炭表面的交界酸，也在一定程度上提高了其表面对苯并噻吩硫化物的吸附；当活性炭表面负载了硬酸性Fe^3＋或Co^3＋离子，其局部表面硬酸增大从而降低了其对苯并噻吩的吸附。

Under supersonic condition Ce(superscript 4+) may oxidize sulfur compound such as benzothiophene in diesel fuel into sulfonea. By choosing a proper solvent to extract sulfonea, the sulfur content in diesel fuel is reduced from 554 mg/L to 25 mg/L with a desulfurization ratio of 95.5% and the sulfur content of diesel oil by oxidization is in line with the quality standard of diesel oil in World Fuel standard Ⅲ.

首次超声条件下使用Ce(上标 4+)氧化柴油中的硫化物，并把这类硫化物氧化成砜类化合物，再选用合适的溶剂将这些砜类化合物通过萃取方法除去，使柴油中的总硫含量从554mg/L降到25mg/L，达到了95.5%的高脱硫率。

In supersonic condition Ce~(4+) may oxidize sulfur compound such as benzothiophene mainly in diesel fuel into sulfonea for the first time. By choosing proper solvent to extract sulfonea, thus sulfur content in diesel fuel is reduced from 554mg/L to 25mg/L, up to 95.5 % desulfurization ratio and the sulfur content of diesel oil by oxidization meet to the quality standard of diesel oil in World Fuel standard III.

2在超声条件下首次使用Ce~(4+)来氧化柴油中的硫化物并把这类硫化物氧化成砜类化合物，再选用合适的溶剂DMF，把这些砜类化合物通过萃取的方法除去，从而将柴油中的总硫含量从554ppm降到25ppm，达到95.5％的高脱硫率。

The metallogenic series in time can be divided into three metallogenic pe riods (cassiterite silicate period, cassiterite sulfide period and base metal sulfidr period ) and six metallogenic stages.

该成矿系列时间递变可分为三个成矿期(锡石硅酸盐成矿期、锡石硫化物成矿期和贱金属硫化物成矿期)和六个成矿阶段。

So the cobalt can not only form cobalt self-existent mineral by combining with sulphur or analogous sulphur elements, but also form cobaltiferous sulphides or analogous sulphides and cobaltiferous silicates minerals by isomorphism with Fe, Ni, Mn, Mg, etc.

因此钴不仅可以与硫或类硫元素等离子形成独立钴矿物，而且还可以与铁、镍、锰、镁等离子类质同像，进入铁、镍、锰和镁等矿物晶格，形成含钴的硫化物、类硫化物或硅酸盐。

Vanadium mainly exists as independent minerals or in clay minerals in the form of isomorphism, with a small amount absorbed by clay minerals and limonite. Nickel mainly exists as independent minerals. Molybdenum occurs as colloidal sulfides with carbon, sulfur and clay, and forms molybdenite through thermal metamorphism. Uranium is unevenly scattered in collophanite and carbonaceous_argillaceous materials in the form of isomorphism or adsorption. REE mainly occur in collophanite in the form of isomorphism. Copper, lead and zinc chiefly exist in sulfides or sulfo_arsenides and are concentrated in the metallic layer.

钒或以独立矿物存在，或以类质同象赋存在粘土矿物中；镍主要以独立矿物存在；钼主要与碳、硫、粘土一起呈钼硫化物胶状集合体，经热接触变质作用后形成辉钼矿；铀呈不均匀分散在胶磷矿和碳泥质中，呈类质同象或吸附状态存在；稀土元素主要呈类质同存在于胶磷矿中，部分呈吸附状态存在；铜、铅、锌主要以硫化物和硫砷化物等存在，多富集在金属层中。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。