硫化物

The stability of alkaline earth sulfides can be improved by two methods, one is by coating with fluoride or oxides, and another is by forming of complex sulfides with Ga.

可通过两种方法改善碱土硫化物的稳定性，其一是通过用氟化物或氧化物的包覆，另一是通过与Ga生成的复合硫化物。

Meanwhile, the concentration of Pb,Zn and other heavy metals is rather high in the oxidation zone and decreasesdownward to levels that are unbelievably low for Pb-Zn mine tailings. Theseobservations suggest that heavy metals should be re-immobilized by secondaryminerals, rather than primary minerals, in the oxidation zone, and could be leachedout from suboxic environment due to low rate oxidative dissolution which preventsthe precipitation of secondary minerals in significant amount. Thus, cover scenarioswhich establish a suboxic environment beneath the cover layer might not always beeffective in preventing heavy metal release from mine tailings.Sequential extraction studies indicate that, in addition to heavy metal leaching,oxidation of the mine tailings increased the mobility of residual Zn, and Cu, while Pb remains immobile due to the formation of anglesite (PbSO4). Using the seven-step extraction technique developed by Dold (J. Geochem. Explor., 2003, 80: 55-68), galena dissolves in significant amount at step 2 most probably due to the strong complexing of Pb2+ by acetate, while other metal sulfides dissolve at step 6, which suggest that this extraction technique could not be used to evaluate the mobility of lead in natural environment

重金属含量均低于新鲜尾矿，但以硬化层中的含量最高(Pb、Zn含量分别为0.47%和0.93%)，往下大幅度降低，表明尾矿风化过程中形成的次生矿物对Pb、Zn等重金属元素有较强的固定作用，而次氧化带的淋溶作用造成了金属元素的大量流失；(4)与新鲜尾矿相比，硬化层中铅的可迁移性大大降低，硬化层之下尾矿样品中铅的可迁移性也不同程度降低，这是由于硫化物氧化产生的硫酸根与尾矿中的铅反应形成铅矾(PbSO_4)的缘故；(5)氧化作用使尾矿中的zn、Cu等重金属的可迁移性不同程度地增大，其中对锌的可迁移性影响最大，铜的可迁移性与铁比较相似，铅则容易与硫化物氧化形成的SO_4~(2-)反应形成铅矾(PbSO_4)；(6)为了减少尾矿污染和修复矿山环境，人们提出了各种不同的尾矿覆盖方案，本文的研究结果表明，这些方法不一定能够有效地阻滞污染元素的迁移。

Based on a systematic study of a considerable number of polished ore sections as well as ICP-MS and electron microprobe analyses, the authors have found that the main sulfide minerals include galena, iron-poor sphalerite and chalcopyrite, whereas silver minerals are composed chiefly of native silver, pyrargyrite, argentite, polybasite, and argentiferous freibergite.

文章首次对其矿石矿物进行了系统的研究，通过对大量矿石光薄片观察、等离子质谱和电子探针分析，表明具有工业意义的硫化物主要有方铅矿、贫铁闪锌矿、黄铜矿，银矿物主要有自然银、深红银矿、辉银矿、硫锑铜银矿、含银黝铜矿，它们与硫化物共生，多沿方铅矿、贫铁闪锌矿等颗粒间或者裂隙产出。

Armed with this information and further analyses, Rumble, lead author Bekker, and colleagues propose the following scenario today in Science . Early in Earth's history, volcanic eruptions spewed massive amounts of sulfur dioxide into the atmosphere, where UV sunlight broke down the gas and created the odd sulfur isotope ratios. The sulfur descended with the rain and accumulated into sedimentary beds on the sea floor. Once there, superheated water from geothermal vents at various locations on the sea floor cooked the sulfur into sulfide. Finally, nickel-bearing magma welled up from Earth's mantle, combining with the sulfide to form nickel sulfide and encasing the compound inside volcanic rock called komatiite.

凭借这份资料和进一步的分析，朗布尔、研究论文的第一作者贝克及同事们今天在《科学》杂志上提出了如下的推测：在地球早期的历史上，火山爆发将大量的二氧化硫气体喷射到空中，太阳的紫外线将其分解，产生了奇特的硫同位素比值，这种硫随雨降下，积存于海底沉积层中；一旦到达海底，海底各处的地热出口所产生的温度过高的水把硫加热成硫化物；最终含有镍的岩浆从地幔中涌出，跟硫化物结合形成硫化镍，并将硫化镍包裹在一种叫做"科马提岩"的火山岩中。

Species of metallic deposits are quite complicated: Besides commonly-seen pyrite ,chalcopyrite and bornite, there exist varied copper-bismuth sulfosalt minerals(sandber}erite, Bi-tennantite, Bi-tetrahedrite, aikinite, wittichenite),tungsten-tin sulfidesand polymetallic sulfides.

金属矿物种类复杂，除常见的黄铁矿、黄铜矿、斑铜矿外，还有多种铜铋硫盐矿物（锌砷黝铜矿、铋砷黝铜矿、铋锑黝铜矿、针硫铋铅矿、硫铋铜矿）、钨锡硫化物（硫铁锡铜矿、硫钨锡铜矿）及多金属硫化物。

Consequently, sulphidic bottom waters on continental shelves may be more common than previously believed, and could therefore have an important but as yet neglected effect on benthic communities.

关于硫化物会被亚表层海水中的细菌完全耗尽、从而会被浅层沿海水域的遥感或监测活动忽略的发现表明，大陆架上含硫化物的海底水域也许要比我们所想的更普遍，所以有可能对底栖生物群落产生一个重要的、但以前却被忽略的影响。

Vapor makes the activity and selectivity of the catalyst decrease a great deal yet this disvalue is reversible; When the elemental sulfur and vapor exist simultaneity in the system, it might generate H〓S and S on 〓 catalyst since the anti-Claus reaction, but this phenomena is not observed on CoS〓-TiO〓 catalyst showing that sulfides could check the anti-Claus reaction.

对硫化物催化剂CoS〓-TiO〓来说，助剂La和Ce的引入对CoS〓-TiO〓催化剂的氧化还原性能有一定影响，硫化物催化剂平均粒径要小，但助剂并未改变催化剂的电子结构，对于氨分解克劳斯反应的活性改变不大明显。

Thermodynamic process of direct aluminium extraction from aluminium sub-sulphide, which is unstable and easily decomposed into Al and Al2O3 at a low temperature, was analytically studied. The temperature, at which alumina, FeS and carbon react to form aluminium sub-sulphide in different pressure, was evaluated with "Substance Gibbs' Free Energy Functional Determinant" method.

本文利用铝的低价硫化物在高温下存在，低温下不稳定容易分解得到金属铝的特性，从热力学角度引入"物质吉布斯自由能函数法"讨论在不同压力下，氧化铝、硫化亚铁与还原剂碳的反应生成低价硫化物的条件。

Alkaline earth sulfides MS, alkaline earth selenides MSe, MS1-xSex,gallium sulfide Ga2S3, oxysulfide MLaGa3OS6, complex sulfides MGa2S4 and Ba2ZnS3 doped with rare earth ions Eu2 , Ce3 , Tb3 , Ho3 , Tm3 were synthesized and their spectroscopic properties were studied.

合成了掺Eu2 ， Ce3 ， Tb3 ， Ho3 ， Tm3 等稀土离子的碱土硫化物MS，碱土硒化物MSe，碱土硒硫化物MS1-xSex，硫化镓Ga2S3，氧硫化物MLaGa3OS6，和复合硫化合物MGa2S4， Ba2ZnS3，并研究了它们的光谱性质。

Shihu gold deposit in Hebei Province, belonging to pyrite sulfide type,is characterized by multistage mineralization,but the main stage of mineralization is almost coincident with the mass separation of sulfideThe sulfur in sulfide and mineralizing hydrothermal solution is derived from anatectic granitic magma.

河北省石湖金矿属于黄铁矿硫化物型金矿，具有多期次成矿的特点。但金的主要成矿阶段与硫化物的大量析出阶段在时间上基本一致。硫化物及成矿热液中的硫来自深熔花岗质岩浆。从微观结构和晶体学理论上对金的赋存机理进行了讨论。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。