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For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有:乙二醛、伯胺和多聚甲醛的缩合反应;卤代烷与咪唑及其取代咪唑的烷基化反应;原甲酸酯与1,2-二胺的成环反应;肼或酰胺与酸酐的环化反应;用Na/K对环硫脲化合物的还原反应。

All results showed that three kinds of medicament on controlling sweetpotato black rot is effective, the control effect of 70% thiophanate-methyl and 50% carbendazim were above 90%, 50% amobam was above 80%. The four kinds of medicament on controlling sweetpotato stem nematode with 40% isofenphos-methyl, 50% phoxim, 5% aldicarb and 5% ethoprophos in the field showed obvious effect, the control effect were 88.81%, 83.29%, 93.63% and 90.35%.

在贮藏期间对甘薯黑斑病的药剂防治试验中,70%甲基托布津、50%多菌灵和50%代森铵三种药剂对甘薯黑斑病均有较好的防治效果,70%甲基托布津和50%多菌灵的防治效果达90%以上,50%代森铵的防治效果达80%以上;在田间对甘薯茎线虫病的药剂防治试验中,40%甲基异柳磷、50%辛硫磷、5%神农丹和5%茎线灵四种药剂对甘薯茎线虫病的防治效果明显,防效分别为88.81%、83.29%、93.63%和90.35%。

Nowak J Petrological coal seam accumulation model for the Zacler Formation of the Lower Siesian coal basin,Southwestern Poland 10.1144/GSL.SP.1996.109.01.20 London:The Geological Society , 1996,null

代世峰%任德贻%唐跃刚%艾天杰%周强%马凤学%李宝春乌达矿区高硫煤中菌藻类体的发现及意义 10.3321/j.issn:1000-1964.1999.01.014 中国矿业大学学报, 1999,01

A process for preparing the olefine sulfide includes addition reaction between sulfur monochloride and C3-C12 olefine under existance of low-carbon alcohol as catalyst to obtain addition compound, mixing it with C1-C15 haloalkane, sulfide of alkali metal, sulfur powder, and aqueous solution of emtrol, sulfurizing, dechlorinating, and refining.

一种硫化烯烃的制备方法,包括:(1)使一氯化硫和C 3 ~C 12 烯烃在低碳醇催化剂的存在下进行加合反应,生成加合物;(2)将(1)步的加合物与C 1 ~C 15 卤代烷、碱金属硫化物、硫磺粉、脂肪醇水溶液混合,进行硫化脱氯反应后,精制处理,得到硫化烯烃产品。

It has been demonstrated that the methods are successfully used for QSRR studies of quinazoline derivatives, alkypyridine, haloid alkane, ketone, alcohol, sulfur alcohol compounds.

本文成功地用该方法对喹唑啉类、烷基吡啶化合物、卤代烃、醇、羰基化合物和硫醇化合物的结构保留关系进行了探讨。

CFB (Circulaiing Flued-bed Boiler), which could desulphurize by adding the lime stone in boiler, was adopted in the project of petroleum coke taking the place of oil; IGCC was adopted in coal to gas project; PC+FGD, such as limestone/plaster wet type desulfurization, liquid spray flue gas desulfurization, electron beam flue gas desulfurization and sprayed dry type desulfurization etc., was adopted in the other projects of thermoelectricity. Desulfurization inside boiler needs less running expenses but high investment and lower desulfurization efficiency.

主要为:高硫焦代油项目燃用石油焦,采用循环流化床炉内加石灰石脱硫;煤造气采用整体煤气化联合循环工艺;其余热电项目则采用煤粉炉加炉外烟气脱硫,具体的脱硫工艺选择有石灰石/石膏湿法脱硫、液柱喷射烟气脱硫、电子束法烟气脱硫以及旋转喷雾干燥法脱硫。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中,开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应,为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法;在此反应体系中,离子液体不仅起到了反应溶剂的作用,而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

Hepatocytes were treated with 25 or 50 μg/mL of ethanol or ethyl acetate extracts of Ap or 10 or 20 μM andrographolide, which is the major active diterpene lactone of Ap, for 48 h.

因此,本实验利用大鼠初代肝细胞培养模式,探讨穿心莲对诱发 pi 属麸胱甘硫转移(pi class of glutathione S-transferase, GSTP)的作用。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。