硫代

Sodium thiosulfate and carbon disulfide were used as sulfur sources in water and absolute alcohol systems, respectively.

在水溶液体系和乙醇溶液体系中，于常温常压下不加入任何催化剂，用γ射线辐照技术可以成功制备出纳米ZnS晶体，其中硫代硫酸钠和二硫化碳分别为上述两体系的硫源。

The synthesis method comprises the following steps: adding 2-( 5-(dimethylamino methyl- 2- furyl methyl sulpho ethylamine and 1- methylthio- 1- methylamino- 2- nitro ethylene with a molar ratio of 1.04: 1 into water, heating to 48- 52 Deg. C, reacting 4.5 hours with a vacuum degree of 0.02- 0.05 MPa, cooling, adding sodium-hydroxide of concentration of 10% to regulate the PH value to 11.0- 11.4, filtrating and cooling the filtrate to 0- 2 Deg. C, crystallizing for 12 hours, centrifugally filtrating, and rinsing filter cake with purity water to prepare wet ranitidine alkali; dissolving ranitidine alkali in alcohol and reacting with chlorhydric acid to prepare ranitidine hydrochloride.

合成方法包括：将摩尔比为1.04∶1的2-(5-(二甲氨基甲基-2-呋喃基甲基硫代乙胺与1-甲硫基-1-甲胺基-2-硝基乙烯加入水中，升温至48-52℃，于真空度0.02～0.05MPa反应4.5小时，反应完毕降温，用10％氢氧化钠溶液调pH＝11.0-11.4，抽滤，滤液降温至0～2℃，结晶12小时，离心甩滤，用纯化水漂洗滤饼，得雷尼替丁碱湿品；将雷尼替丁碱溶于乙醇中与盐酸反应，制备得到盐酸雷尼替丁，产品符合欧洲药典标准。

The Onsager solvate theory model was employed for aqueous solution calculations.

Onsager反应场溶剂模型用于水相的计算，计算结果表明，2，6-二硫代黄嘌呤在气相和水相中主要以双硫酮形式存在。

Part 3 : determination of chromate, iodide, sulfite, thiocyanate and thiosulfate.

第3部分：铬酸盐、碘化物、亚硫酸盐、硫氰酸盐和硫代硫酸酯的测定

Adenosine was used as the raw material, dissolved in triethyl phosphate and then esterified with thiophosphoryl chloride under 0~5℃ for 8h without water and oxgen, in alkaline condition provided by 2,6-dimethylpyridine, introducing thiophosphoryl ester to adenosine.Then superfluous triethylamine was added and reacted under 5℃ for 1h to synthesize rough 5'-AMPS.The unpurified product was appled to a DEAE Sephadex A-25 column and eluted with triethylammonium bicarbonate.

用腺苷为起始原料，溶解于磷酸三乙脂中后，在无水无氧环境中及2，6-二甲基吡啶提供的碱性条件下与三氯硫磷以0~5℃下发生酯化反应8h，将硫代磷酸酯引入腺苷，然后再与过量三乙胺在5℃下反应1h，合成粗产品，再用碳酸氢三乙胺作洗脱液，过DEAE Sephadex A-25凝胶柱纯化。

Expanded MSCs were induced to differentiate into nerve cells withthree different treatment protocol in the prensent study . On the following day, the medium was replaced with preinduction medium consisting of DMEM, 20% FCS, and 10 ng/ml basic fibroblast growth factor. After 24 h, the preinduction medium was removed, the cells were washed twice with PBS, and neuronal induction medium containing DMEM supplemented with 2% DMSO and200 m bu-tylated hydroxyanisole was added. In later experiments, we used DMEM with 5 mM p - mercaptoethanol or sulfo - glycerine as an alternative neuronal induction medium for the same incubation.

将待诱导分化的MSCs按0.4x10~6／ml接种于事先放置有消毒盖玻片的六孔板内制备细胞爬片，分别采用三种不同的方法诱导第2代至10代的MSCs向神经细胞分化，即方法1先用含bFGF的培养基进行预诱导，之后再用含叔丁基对羟基茴香醚，和二甲亚砜的无血清培养基进行诱导；方法2和方法3用B-巯基乙醇和硫代甘油进行预诱导，然后不同浓度的上述物质进行正式诱导。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明：Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应，同时溶剂极性和薄膜含水量对负载量也影响相当大；本课题首次使用硫代乙酰胺代替传统无机硫源（H2S、Na2S）合成CdS纳晶，研究了各种硫源的组装机理，克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点，得到了有利于光催化传质需要的体相均匀分布CdS/Nafion；研究了多种Nafion膜内纳米粒子晶化途径，找到了简单可靠的水热晶化法，TiO2纳晶最高负载量达43％；初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性，在本实验条件下最高降解率达86％。

The research presented here is aimed at exploring the effect of DTT on the in vitro fibril formation of hen egg-white lysozymes with four disulfide bonds. In this work, we specifically addressed the effect of DTT concentration under different incubation temperatures on the hen lysozyme structure and fibril formation, the effect of addition of DTT at later time points on the amyloid fibrillization of hen lysozymes, and the effect of concentration ratio between reduced and oxidized forms of DTT on the fibril formation of lysozymes.

本研究以具有四对双硫键的母鸡蛋白溶菌酶为蛋白质模式系统，在含盐类之酸性溶液环境下诱导生成类淀粉纤维，再配合二硫代苏糖醇破坏溶菌酶中的双硫键，探讨：（1）不同温度下加入不同DTT浓度对溶菌酶类淀粉纤维形成之影响，（2）不同生长时期加入DTT对溶菌酶类淀粉纤维形成之影响，（3）不同比例之DTT和氧化态DTT浓度对溶菌酶类淀粉纤维形成之影响。

In the contaminated lard sample, 6 organic compounds have been thus identified to be the raw materials or byproducts in the production of organic tin compounds. Based on the identified contaminants, it can be postulated that the chemical structure of the organic tin compound is dibutyltin-bis-(2-isooctyl thioacetate). The method is simple and precise, and has not been reported in the local literature.Keywords Organic tin compound, Lard, SPME－GC－MS

经过摸索研究，采用固相微萃取方法富集挥发性杂质，直接注入色谱中，经色谱分离，质谱测定，确定了杂质的结构，由杂质成分推断生产有机锡所用的原料，然后判断合成路线，最后确定有机锡的结构，从有毒猪油中鉴定出2－巯基醋酸异辛酯、双（2－醋酸异辛酯）二硫、双醋酸异辛酯硫醚等6种与有机锡有关的杂质，并与相应的有机锡工业品对照，发现工业品中也含有这些杂质，与其合成过程的原料及副产物相符，从而确定有机锡化合物为二硫代醋酸异辛酯二丁基锡。

The attack causes the cleavage of P-S double bonds, then the decomposition products reacting with the surface of Fe metal lead to the formation of the anti-wear and anti-friction film largely composed of polyphosphates and sulphides.

计算表明二烷基二硫代磷酸锌的活性元素为6位和7位硫原子，其与铁发生摩擦化学反应时，最可能的断键位置是6位和7位硫原子的双键。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。