硫

Generally speaking, the reaction types involvingα-oxoketene--acetals mainly include the regioselective addition-aromatization with organometallic reagents, conjugate addition-cyclization with nitrogen nucleophilicspecies, nucleophilic reactions ofα-carbon, acting as odorless dithiol equivalentsin thioacetalization, Michael additions and [5+1] annulation, as well as the synthetic applications based on the above reactions.

一般来说，基于α-羰基二硫缩烯酮化学的反应主要为：与金属有机试剂的选择性加成反应，与氮亲核体的共轭加成反应，α-碳原子的亲核性及相关反应，烷硫基作为硫醇的替代试剂的应用，α-羰基二硫缩烯酮在碳环、杂环化合物合成中的应用等。

The present invention relates to the depolymering cyclization reaction of aromatic dithio ether polymer to prepare aromatic cyclic dithio ether compound under the presence of mercapto group containing compound and alkali matter.

本发明涉及利用芳香双硫醚聚合物的解聚成环反应来制备芳香双硫醚环状化合物的方法。该方法采用芳香双硫醚聚合物在含巯基的化合物和碱性物质存在的条件下发生解聚成环反应生成双硫醚环状化合物。

Chapter two 4-Hydroxybenzoic acid is connected with PEG6000 through defoliant DCC at rooom temperature, then the product is refluxed with chloroacetic acid in acetone to afford PEG-bound phenyloxyacetic acid, which is reacted with thionyl chloride, ammonium thiocyanate and arylamines in turn to give PEG-bound disubstituded thioureas. After the cleavage with sodium methoxide in methanol, the eleven disubstituted thioureas are obtained.

第二章 利用PEG6000作载体，通过脱水剂DCC在室温下将对羟基苯甲酸以酯键连接在PEG6000上，再与氯乙酸在较温和的条件下生成PEG6000支载的芳氧乙酸，然后，依次与亚硫酰氯、硫氰酸铵、芳胺反应，生成PEG6000支载的硫脲，最后用甲醇钠的甲醇溶液切割PEG，得到了十一种1，3-二取代硫脲。

Vulcanization thing in sulphur natural gas, take off to exclude, Make organic sulfur content and the vulcanization hydrogen of the natural gas of raw material accord with relevant technical index requirement , satisfy production needs,Today of the chemical swift development of natural gas the desulphurization method of natural gas also emerge endlessly , In traditional a ethanol amine the foundation of wet desulphurization and the dry law desulphurization of zinc oxide on, have arisen the desulphurization of normal temperature of ferric oxide, the dry law desulphurization of activated carbon and member sift desulphurization, DDS biochemical wet desulphurization wait for new technology .

硫的存在造成合成氨工艺中催化剂中毒，因此需将含硫天然气中的硫化氢、有机硫等硫化物脱除，使产品天然气的硫化氢和有机硫含量符合有关技术指标要求，满足生产需要。在天然气化工迅猛发展的今天，天然气脱硫方法也层出不穷。在传统一已醇胺湿法脱硫，氧化锌干法脱硫的基础上，出现了常温氧化铁脱硫，活性炭干法脱硫，分子筛脱硫，DDS生化湿法脱硫等新技术。

The method comprises:(1) weighing lead acetate hexahydrate and thioacetamide, and preparing aqueous solutions respectively, so that the concentration ratio of Pd2+ to S is 1:(1-4);(2) adding acetic acid into thioacetamide solution to adjust the pH value to 2-4;(3) adding poly surfactant into lead acetate solution, ultrasonicating to mix uniformly and obtain a colorless and transparent sol;(4) mixing the sol and thioacetamide solution;(5) placing the mixed solution in a sealed container, irradiating by 2.5 MeV and 40 mA electron accelerator with irradiation dose of 25-40 Mrad;(6) washing the product, centrifuging for separation, and drying to obtain black PdS nanoparticles.

本发明方法的工艺过程如下：首先称取一定量的六水合醋酸铅和硫代乙酰胺，各自配制成水溶液，其浓度比为使其中的铅离子浓度与硫原子浓度的比例为1∶1～1∶4；在硫代乙酰胺溶液中加入适量醋酸调节其pH值至2～4；醋酸铅溶液中加入少量表面活性剂聚乙烯醇，然后超声振荡，混合均匀，制成无色透明溶胶；随后将溶胶与上述的硫代乙酰胺溶液混合；将该混合液置于密闭容器中，并将其放置于2.5MeV、40mA的电子加速器产生的电子束辐照下进行辐照处理，其辐照剂量为25～40Mrad；然后将反应生成物清洗，并用高速离心机离心分离，然后干燥，最终得到黑色纳米硫化铅颗粒。

Chapter 4 describes the synthesis, structural characterization and properties of anovel organic-inorganic hybrid compound, F〓〓BEDT-TTF =bis(ethylenedithiotetrathiafulvalene, which has been synthesized through thereaction of the pre-intercalate Fe〓PS〓〓(phen = 1.10-phenanthroline) with〓 Compared with the pristine FePS〓, the lattice spacing isexpanded by about 4.0〓, indicating that the molecular ring plane of BEDT-TTF isarranged parallel to the layer of the host.

通过红外光谱推测客体BEDT-TTF在层间以中性状态存在。X-线光电子能谱揭示在夹层化合物Fe〓PS〓〓中磷原子和硫原子在硫代亚磷酸根负离子簇中各存在两种化合价态，其中一种价态与纯主体或预夹层化合物〓〓中的磷原子和硫原子价态一致，而另一种价态却比纯主体FePS〓或预夹层化合物Fe〓中的磷原子和硫原子价态高。

The paper commencing with analyses of the basic property of the hydrate, structure and sort, analyzes micro kinetics, formation condition, gas hydrate formation mechanism and influencing factor in high sulfur; also proceed analysis in depth for existent hydrate prediction model; according to gas dissolving, hydrate lattice deformation, synergistic action of inhibitor, carry out analytical study for existent error between normal forecast model and physical condition; introduce key parameter theory to establish and modify prediction model of hydrate formation condition to suit for high sulfur gas reservoir and inhibitor system, analyses different kinds of prevention and cure measures to influence of hydrate; finally, through field application in high sulfur gas reservoir hydrate.

本文从分析水合物的基本性质、结构与分类出发，分析了水合物生成过程中的微观动力学、生成条件、高含硫天然气水合物生成机理以及影响因素；并对现行的水合物预测模型进行了深入剖析，根据气体溶解、水合物晶格变形、抑制剂协同作用等因素对常规预测模型与实际条件之间存在的误差进行了分析研究；通过引入关键参数理论，建立并改进了适合高含硫气藏水合物生成条件预测模型及抑制剂体系的高含硫水合物生成条件预测模型，分析了各种防治措施对水合物的影响；最后通过高含硫气藏水合物实例计算，分析了含硫化氢、二氧化碳组分的天然气与常规气体对水合物生成条件的影响，并对各种水合物防治措施进行了实例计算。

Besides, it can degrade the sulfur in phenyl sulfide and dodecanethiol.

除此之外，它还可以脱除苯硫醚和硫醇类含硫化合物中的硫。

Was admitted to hospital on October 6, 2007, diagnostic schizophrenia, the sulfur that use Kui is smooth increase by degrees law, be admitted to hospital sulfur of 3 weeks of Kui is smooth add send 600 Mg/d, patient spirit symptom is improved somewhat, already dare contact with people, but be certain the husband has an affair, the sulfur that add Kui makes the same score 800 Mg/d, when treating the 7th week, the patient becomes aware the whole body is faint, accept is poor, measure temperature 9 ℃ of 37 ·, morrow double legs appears erythema to weighing out, local strut, the about 1 hip inside week, back, prothorax appears group by group erythema, patient skin itchs somewhat feeling, temperature 39 ℃, kui sulfur makes the same score out of service to fight constituent amine medicaments, vein is pushed note dextrose acerbity calcium and vein drop to note vitamin C, remedial 10d, erythema disappears.

于2007年10月6日入院，诊断精神分裂症，用奎硫平递增法，入院3周奎硫平加致600 mg/d，患者精神症状有所改善，已敢和人们接触，但坚信丈夫有外遇，增奎硫平800 mg/d，治疗第7周时，患者觉全身无力，纳差，测体温37·9℃，次日双下肢对称出现红斑，局部肿胀，约1周内臀部、背部、前胸分批出现红斑，患者皮肤略有痒感，体温39℃，停用奎硫平给抗组织胺药物，静脉推注葡萄糖酸钙及静脉滴注维生素C，治疗10d，红斑消失。

It was found that the endo-type sulfonium salts were also worked but afforded the corresponding cyclopropanes with opposite absolute configuration compared with that from the exo-type salt.

考察了硫盐结构对反应的影响，当硫盐中碳-硫键位于樟脑骨架 endo 位置和碳-硫键位于 exo 位置时所得环丙烷化反应主产物的绝对构型相反。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。