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After thermodynamic studies on the former two typical fine disseminated gold deposits, the following facts are found: both existent and transferring form of gold in mineralizing hydrothermal solution are predominated by Au 〓 and AuH〓SiO〓; the contribution of AuCl〓〓 is negligible to mineralization; and those contribution of gold bearing complexes including Au with As-S and Sb-S are much less than that of Au 〓 and AuH〓SiO〓, organic complex take effect in some degree during the relatively low temperature activating period of gold.

对以上两个典型微细浸染型金矿床的热力学研究,发现成矿热液中金的存在和迁移形式均以Au〓和AuH〓SiO〓为主,AuCl〓对金迁移成矿的贡献微不足道,金砷或金锑等复合配合物对金成矿的作用远不及Au〓和AuH〓SiO〓,有机配合物在温度较低的金的活化期有一定作用。

The activated or leached process and their influence elements are studied by 1DREACT software package of coupled mass/heat transfer and chemical reaction dynamics of water-rock interaction, according to the geological and geochemical characters of fine disseminated gold deposits.(1) Water-rock reaction time is not the important influence element of activating gold;(2) At first, activating capability of hydrothermal solution increases with the increasing of total sulfur activity; after lga〓≥-4, the content of activated gold in solution is mainly related to original content of gold in wall rock, and does not visibly dependent on total sulfur activity.(3) It is a complicated nonlinear process of influence of activating gold capacity of hydrothermal solution with the change of temperature, in general, 220 ℃ is most favorable to gold activation.(4) The influence of oxygen fugacity on gold activation has a multiple functions coupling nonlinear effect, in general, Igfo〓=-41 is most favorable to gold activation.(5) Solubility of gold in fluid decreases with the increasing of velocity of flow, the product of velocity and aurous solubility reaches maximum when velocity is 0.2~0.5m〓m〓. yr〓, i. e. this scope of velocity is most favorable to gold activation.

利用1DREACT水-岩相互作用反应-输运耦合动力学软件包,根据微细浸染型金矿床地质地球化学特征,计算机模拟研究了金的活化、浸取过程及其影响因素,发现:(1)金活化过程中水-岩反应时间不是其主要制约因素;(2)热液对金的活化能力开始随总活度的增高而增高,当lg a〓≥-4后,热液中活化金的含量将主要与围岩中金的初始丰度有关,而对总活度无明显依赖关系;(3)温度对热液浸金能力的影响是一个复杂的非线性过程,总体而言,220℃最有利于金的活化;(4)氧逸度对金活化的影响呈现出一种多因素叠加的非线性效应,总体而言,lgfo〓=-41最有利于金的活化与浸取;(5)流体中金的浓度随流体流速的加快而降低,流速与金浓度的乘积在流速为0.2~0.5m〓m〓。yr〓时达到极大,即0.2~0.5m〓m〓。yr〓的流速范围最有利于本类矿床的金的活化。

Belite– calcium barium sulphoaluminate cement is a new type of cementitious material.

贝利特–铝酸钡钙水泥是一种新型的水泥材料,通过在贝利特熟料矿物体系中引入铝酸钡钙矿物,达到提高贝利特水泥早期强度的目的。

Firing belite sulphoaluminate cement with dusulphurize ash displacing gypsum and part of limestone was studied in this article.

刘辉敏,利用脱灰烧制贝利特-铝酸盐水泥研究了脱灰替代石膏和部分石灰石烧制贝利特-铝酸盐水泥。

By way of f-CaO chemical analysis and thermal analysis, the article studied the influence of K_2O on the mineral of C_2S or C_4A_3 which chiefly formed a cement of high silicon belite sulphur aluminate cement .

目的为研究K2O对高硅贝利特铝酸盐水泥主要矿物C2S和C4A3 S的影响,为含有钾的低品位矿物原料生产高硅贝利特铝酸盐水泥奠定了基础。

This paper mainly discussed the hydration mechanism of calcium barium sulphoaluminate mineral, belite cement and belite-calcium barium sulphoaluminate cement.

阐述铝酸钡钙矿物、贝利特水泥和贝利特-铝酸钡钙水泥的水化机制。

By combining calcium barium sul- phoaliminate with a belite mineral system.

贝利特–铝酸钡钙水泥是一种新型的水泥材料,通过在贝利特熟料矿物体系中引入铝酸钡钙矿物,达到提高贝利特水泥早期强度的目的。

As the cement includes sulphoaluminate clinker,it will an make important effect to the hydration and hardening of Portland cement when adding sulphoaluminate in clinker,such as accelerating the hydration rate of alite and belite clinker,improving the degree of hydration and the quantity of hydrates,and advancing early strength.

阿利特-铝酸盐水泥是一种早强性能优良的新型材料,由于在水泥熟料矿物体系中含有铝酸盐矿物,将对以阿利特为主导矿物的硅酸盐水泥的水化硬化产生重要影响:加速硅酸盐熟料水化,加快水化进程,促进水化产物生成量,提高早期强度。

This thesis includes five parts as follows.1. The backgrounds and some relative concepts of this work are briefly introduced. The photochemistry of benzamides and compounds with thiourea functional group is also concisely reviewed.2. Total of fourteen benzamides with different substituted groups have been synthesized and structurally characterized. Better photoreaction time for that kind of compounds at given concentrations is confirmed by tracking its'UV spectrum and GC chromatogram. A representative dibenzophenone photoproduct has been determined by X-ray crystallography. The mechanisms of photoreaction of benzamide have been proposed.3. Total of seven N-chloro(phenylmethylenebenzenamines with different substituted groups and sixty-one thiourea derivatives have been synthesized and structurally characterized.

论文的主要内容如下:1、简要介绍本论文工作的研究背景,并对苯甲酰胺和具有脲官能团类化合物的光化学研究进展进行简要的总结。2、合成与表征了14个具有不同取代基的苯甲酰胺类化合物,利用紫外光谱和气相色谱确定了此类化合物较佳光照时间,测定了一个具有代表性光解产物的单晶结构,提出了苯甲酰胺类化合物的光反应机理。3、合成与表征了7个带有不同取代基的氯代苯甲酰亚胺中间体及61个脲衍生物,测定了两个具有代表性化合物的单晶结构。

In this thesis, two series compounds of thiadiazole (2a~2f) and benzothiazole (5a~5f) were synthesized by using the reagent of iodobenzene diacetate. We also bound the iodobenzene diacetate reagent to the resin and applied it to synthesize thiadiazole and benzothiazole compounds.

本文利用二醋酸碘苯试剂分别与1-芳甲酰基-5-芳基-2-代缩二脲及1-芳甲酰基-3-芳基脲反应合成了噻二唑(2a~2f)和苯并噻唑(5a~5i)两个系列的杂环衍生物,并通过把二醋酸碘苯负载在高分子上合成了一类新型的固相氧化剂,同时考查了该固相氧化剂在噻二唑,苯并噻唑类化合物合成中的应用以及该固相氧化剂的循环使用。

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