硫

Results show that Calamagrostis angustfolia wetland is higher than cropland in content of total sulfur and available sulfur, which indicates cultivation depletes soil S, and soil total sulfur and available sulfur show a decreasing trend with each passing year.

结果表明，小叶章湿地土壤总硫和有效硫含量高于开垦后的农田土壤，开垦导致土壤硫含量下降，且随着耕种年限的增加，土壤总硫和有效硫含量呈逐年下降趋势。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Ergothioneine is a kind of precious amino acid, and it is also a natural antioxidant. It plays an important role to prevent the oxidative damage in organism. Ergothioneine cannot be biosynthesized in humans, only can be absorbed from the diet. In recently the research discovered the high content of ergothioneine in the mushroom. Content of ergothioneine of Pleurotus eryngii is the highest from 28 kinds of mushrooms, therefore the research untilized P. eryngii to make the products of P. eryngii-fermented adlay and P. eryngii-fermented buckwheat which content high ergothioneine. Also, we analyzed their proximate composition, nutritional components, taste and physiologically active components, antioxidant properties and evaluation of anti-imflammatory effect.

中文摘要麦角硫因为一种稀有的胺基酸，也是天然的抗氧化剂，其在生物体内对氧化压力伤害之预防扮演著重要角色，麦角硫因不能在动物体内合成，仅能由食物中摄取，近年来发现在菇类中含有高含量的麦角硫因，从28种食药用菇类中筛选出麦角硫因含量较高的菌种，以杏鲍菇子实体最高(1521.6 mg/g dw)，因此本论文以杏鲍菇为媒介，利用固态发酵方式，制备出高麦角硫因之杏鲍菇薏仁和杏鲍菇荞麦，并针对薏仁、杏鲍菇薏仁、荞麦、杏鲍菇荞麦和杏鲍菇菌丝体，进行一般成分、营养、物性、呈味、生理活性物质、抗氧化性质之分析及抗发炎反应之评估。

It depicts the species of microbesThibacillus ferrooxidans,SRB,filaceous sulfur bacteria,synthetic sulfur bacteria,colorless(sulfur bacteria and thiobacillus denitrificans,their metabolism pathway,treatment capability and key affecting factors of processes,and their disadvantages and advantages.

叙述了烟气吸收和吸收尾液的处理工艺所利用的脱硫微生物种类，并阐述了氧化亚铁硫杆菌、硫酸盐还原菌、丝状硫细菌、光合硫细菌、无色硫细菌和脱氮硫杆菌的代谢途径、作用效果和关键影响因素，并且指出其优缺点。

It depicts the species of desulfurizing microbes (Thibacillus ferrooxidans, SRB, filaceous sulfur bacteria, synthetic sulfur bacteria, colorless sulfur bacteria and thiobacillus denitrificans), their metabolism pathway, treatment capability and key affecting factors of different processes, and their disadvantages and advantages.

叙述了烟气吸收和吸收尾液的处理工艺所利用的脱硫微生物种类，并阐述了氧化亚铁硫杆菌、硫酸盐还原茵、丝状硫细菌、光合硫细菌、无色硫细菌和脱氮硫杆菌的代谢途径、作用效果和关键影响因素，并且指出其优缺点。

A reversed-phase high performance liquid chromatographic method was established for determination of isothiocyanates in human urine , which used the reaction of propyl isothiocyanate with 1,2-benzenedithiol as reference instead of the synthesis of 1,3-benzodithiole-2-thione.

省去合成1，3 苯二硫杂环五烯 2 硫酮这一步骤，直接用异硫氰酸丙基酯与1，2 苯二硫酚反应作标准，建立了尿液中异硫氰酸酯的反相高效液相色谱测定方法。

Synthesis of organic sulfuric compounds in aqueous media is carried out by: using thio-olefin compounds with carbonyl compounds, acetal/keltone, hydrazone, oxime, osazone and enamine to synthesize mercaptal/keltone compounds in aqueous media; using thio-olefin compounds with alpha-hydroxyaldehyde/keltone or alpha-halogenated aldehyde/keltone to synthesize thia-olefin derivatives in a queous media; using thio-olefin compounds with alpha, beta-unsaturated hydroxy compounds, C-C treble bond, C-N treble bond, C-C double bond, N-N double bond, C-N double bond, C-S double bond, epoxy and its derivatives, aziridine and its derivatives, cyclopropane and its derivatives and halogenated carboxy to synthesize sulfoether compounds in a queous media.

含水介质中有机硫化合物的合成方法，本发明属于有机合成方法，用硫缩烯酮类化合物与羰基化合物、缩醛/酮、腙、肟、脎、烯胺在含水介质中合成缩硫醛/酮化合物，与α-羟基醛/酮或α-卤代醛/酮在含水介质中合成噻烯类衍生物，与α，β-不饱和羰基化合物、碳碳叁键、碳氮叁键、碳碳双键、氮氮双键、碳氮双键、碳硫双键、环氧乙烷及其衍生物、氮杂环丙烷及其衍生物、环丙烷及其衍生物、卤代烃等在含水介质，中合成硫醚化合物。

It is necessary to carry out a thorough study on pest control technology with DMDS, with an expectation of obtaining a new fumigant of methyl bromide alternative.2. Investigation of the toxicity of fumigation on adult and mixed stages of the three most tolerant insect species -- Sitophilus oryzae, Rhyzopertha dominica and Tribolium castaneum -- under a range of EtF、DMS and DMDS doses in a Flow-through Fumigation System shows that the FTFS procedure offers a constant concentration of fumigant with low CO2 concentrations and ensures that the fumigant toxicity is effectively not compromised by CO2. In comparison with chamber fumigation method, the toxicity data of EtF、DMS and DMDS obtained from this experiment is more accurate by using FTFS.

主要研究结果如下：1、甲酸乙酯和二甲基二硫对仓储害虫具有良好的控制作用，应加快甲酸乙酯替代溴甲烷防治仓储害虫开发应用，同时，二甲基二硫是很有潜力的仓储害虫防治熏蒸剂，要深入进行二甲基二硫控制有害生物的技术研究，以期获得新的溴甲烷替代熏蒸剂。2、利用循环熏蒸系统测定了甲酸乙酯、二甲基二硫和甲硫醚对米象Sitophilus oryzaeL。

The mechanism of thiocarbonyl compounds with thiourea function group has been proposed according to the photoreaction products.5. Total of one heterocyclothione intermidate and four heterocyclothione compounds have been synthesized and structurally characterized.

根据所得到的产物对具有硫脲基团的硫羰基化合物的光反应机理进行合理的推测。5、合成与表征了1个环硫酮中间体和4个杂环硫酮类化合物，摸索出合成杂环硫酮中间体较佳反应条件。

The removal of organic sulfur such as thiofuran , thioether and mercaptan is the main objective of dry desulfurization , and hydroconversion of organic sulfur and preventing the methanation side reaction are the technological difficulties of hydroconversion desulfurization. The combination of two-level conversion and two.1evel absorption is the preferential scheme for refined removal of high-concentration organic sulfur.

脱除噻吩、硫醚、硫醇类有机硫是干法脱硫的主要目标，加氢转化有机硫并防止发生甲烷化副反应是加氢转化脱硫的技术难点，组合式两级转化、两级吸收是精脱高浓度有机硫的优选方案。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐