硫

(1)SCG is a sensitive, simple and economic method in evaluating the cytotoxicity of SM in toxication and the degree of intoxication, and with good prospects in early diagnasis;(2)The cytotoxicity caused by the elevation of NO induced by the NOS activity after intoxication might be one of the mechanisms of SM intoxication;(3)Apoptosis participates in the process of SM intoxication also might be one of the mechanisms of SM intoxication.

(1)SCG法敏感、经济、简便，可用于硫芥中毒细胞毒性、中毒程度的评价，在早期诊断上有良好的应用前景；（2）中毒后因NOS的活性升高导致NO的升高而产生细胞毒作用可能是硫芥的中毒机制之一；（3）细胞凋亡参与了硫芥的中毒过程，亦可能是其中毒机制之一。

Two analogues of Trichosanthes trypsin inhibitor I with the Cys14- Cys26 or Cys8- Cys20 disulfide bonds replaced by Tys or Phe and two negative control analogues substitution serine for cysteine at 14 and 26 or 8 and 20 positions were synthesized, respectively. The C14F-C26Y mutant had 1/140 inhibitory activity of native Trichosanthes trypsin inhibitor I to trypsin.

第二章是对天花粉胰蛋白酶抑制剂的两对二硫键的作用进行了研究，二硫键在蛋白质的折叠和功能中有重要的作用，芳香族氨基酸的芳环之间形成π-π共轭能否部分补偿二硫键的作用？

Through Friedel-Crafts reaction, We have prepared highly purified triphenylphosphine sulfide by using benzene, phosphorus trichloride, sulfur, and aluminum trichloride, which is desulfurized with metal powder to produce triphenylphosphine.

实验方法为以苯、三氯化磷、硫和三氯化铝为原料，利用Friedel-Crafts反应，合成三苯基硫膦，收率为79.4％；然后用金属将三苯基硫膦还原制得三苯基膦，收率为80％。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

CTTC undergoes ring-opening process to incorporate a trithiocarbonate moiety. The trithiocarbonate moiety in turn, functions as a reversible addition fragmentation chain transfer agent.

即环状三硫酯受到自由基进攻以后，发生开环反应并转化为线形三硫酯进入到聚合物的链中；线形三硫酯基团可以进一步作为RAFT试剂控制其后的聚合反应。

Catalytic techniques for deep desulfurization, denitrogenation and dearomatization in production of clean gasoline and diesel fuels were reviewed, especially those for producing low-sulfur and extra-low-sulfur gasoline and diesel oil, among which technologies arousing most attention are sulfur-reducing FCC catalyst and additives, selective hydrogenation catalysts and technology, adsorptive desul-f urization of gasoline and diesel oil, biologically catalytic desulf urization of diesel oil, and selective oxid...

为面对新世纪清洁燃料生产的新机遇和新挑战，各种生产清洁燃料的催化技术正在竞相开发之中，尤其是生产低硫、超低硫汽油与柴油技术。其中，催化裂化降硫催化剂和助剂、选择性加氢处理新催化剂及工艺、汽柴油吸附脱硫、柴油生物催化脱硫和选择性氧化脱硫等新技术尤其引人注目。我国应加快清洁燃料生产催化新技术的开发研究，为生产更清洁的汽油和柴油燃料提供技术储备。

As CAAX-mimetics, 1, 3-dihydro-5-phenyl-2-H-1, 4-benzodiazepin-2-one was modified by linking carboxyl groups with various carbon through N-1 and C-3, 3-(imidazol-4-yl) propion amido group with different substituents was connected at C-7; In the synthesis of bisubstrate analogues, thiocarbamido compounds was alkylated by alkyl iodide and then hydrolyzed to give alkylthiol benzoate compounds.

1，4-苯并二氮杂草-2-酮类化合物的合成过程中分别对其1、3、4和7位进行了基团变化，在1和3位连接不同长度含羧基或酯基的侧链，在7位连接不同取代的咪唑丙酰氨基。在苯甲酸硫醇酯化合物合成过程中，建立了一种硫原子连有不同长度碳链的苯甲酸硫醇酯的合成方法。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明：Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应，同时溶剂极性和薄膜含水量对负载量也影响相当大；本课题首次使用硫代乙酰胺代替传统无机硫源（H2S、Na2S）合成CdS纳晶，研究了各种硫源的组装机理，克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点，得到了有利于光催化传质需要的体相均匀分布CdS/Nafion；研究了多种Nafion膜内纳米粒子晶化途径，找到了简单可靠的水热晶化法，TiO2纳晶最高负载量达43％；初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性，在本实验条件下最高降解率达86％。

The kinetics process and temperature impact of natural groundwater denitrified by sulfur autotrophic was investigated. The results revealed that the denitrification rate of up-flow sulfur autotrophic denitrification filter followed a half-order kinetics model; and the reaction rate constant was mainly affected by the temperature. Based on the Arrhenius calculation, the activated energy was 80.38 kJ/mol.

研究实际地下水硫自养反硝化动力学过程，考察季节因素对动力学的影响，实验结果表明，地下水升流式硫自养滤柱反硝化动力学符合1/2级动力学模型，其反应速率常数受温度的影响很大，用阿仑尼乌斯方程计算硫自养反硝化活化能为80.38 kJ/mol。

The application of sulfur isotope tracing involves the physical and chemical conditions, origin of ore-forming minerals, denudating degree of orebody, ore enriching position and genesis types of deposits. In the application, the geology of the hydrothermal deposit should be well understand to distinguish metallogenic epochs and judge the isotopic fractional equilibrium state, combined with the Ohmoto mode to study the factors possibly affecting hydrothermal fluid system.

在总结前人研究基础上，综述了硫同位素在热液成矿作用中成矿物理化学条件、成矿物质来源、矿体剥蚀程度、矿化富集部位、矿床成因类型等的示踪意义，认为硫同位素示踪应用须在了解热液矿床基础地质前提下，准确区分成矿期次，判别硫同位素分馏平衡状态，结合Ohmoto模式综合研究影响成矿热液体系的各种因素才可以赋予同位素准确的地质内涵。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。