硫

To get more insight into the mechanism and kinetics of the RAFT process,it would be helpful to build a small molecular model reaction mimicking the RAFT process but free of a chain-propagation event. We hereby propose a model cross reaction between dithioester and alkoxyamine as a probe of the RAFT process,in which the alkoxyamine plays the role of the radical source.The generating rate of the transient alkyl radical and the nitroxyl radical can be described by the law of persistent radical effect.Thus,the advantage of the model cross reaction is that it affords a radical concentration determined by the known equation of the persistent radical effect.

为了更深入的理解RAFT聚合过程，我们构建了一个模型反应：即由烷氧基胺与双硫酯进行交换反应，烷氧基胺均裂产生的烷基自由基将会向双硫酯进行链转移，双硫酯的引入对纯烷氧基胺分解动力学造成的影响可以提供RAFT过程的许多信息。

Generally, these compounds are derived from accessible α–oxoketen dithioacetals and the common methods of preparation involve regioselective sodium borohydride 1,2-reduce of α–oxoketen dithioacetals, 1,2-nucleophilic addition of organomatals such as organomagnesium, organolithium, Reformatsky regent to α–oxoketen dithioacetals, Baylis-Hillman reaction between polarized ketene dithioacetals and aldehydes.

主要方法包括：使用硼氢化钠1，2-选择性还原α-羰基二硫缩烯酮；利用有机金属化合物（如有机镁试剂，有机锂试剂，Reformatsky试剂等）对α-羰基二硫缩烯酮进行1，2-亲核加成；通过α-羰基二硫缩烯酮与芳醛进行Baylis-Hillman反应等获得。

The purpose of this thesis is just to search a novel synthesis of thiourea, and to use thiourea in dealing with the waste water from the production of phthalic anhydride, and the application of thiourea in solid-state reactions at low heating temperature was also studied.

本论文研究的目的就是寻找一种合成硫脲新的工艺过程，且尝试以合成得到的产物硫脲应用于工业苯酐废水的处理，同时对硫脲在低热固相化学中的应用进行了初步的探索。

A new desulfurization apprach for pulverized coal combustion is introduced in this paper; pulverized coal is first burn in a precombustion furnace under oxygen deficient condition (about 30% air needed in boiler is provided for precombustion), in precombustion moust of sulfur in coal is decomposed and oxidized, and evolved, the sulfur evolved is trapped in a desulfurizing fluidized bed by calsuim, and then the char and gas are introduced to the boiler furnace for complete combustion.

本文提出了一种煤粉燃烧脱硫新方案，利用煤中硫优先氧化分解释出的原理，用少量的空气（大略为锅炉实际空气用量的30％），在一前置燃烧室中，使煤粉中硫的绝大部分被分解氧化，释放出来，释放出来的硫在脱硫流化床中被石灰脱硫剂脱除，未燃烧的炭粒与烟气再吹进锅炉膛中完全燃烧。

METHOD The serum concentrations of AZP metabolite 6-Mercapto prine(6-MP) in different time were determined by reverse phase HPLC,when AZP was used alone and combined with Pred in nine rabbits.The pharmacokinetic parameters of the two groups wer statistically analysed by paired t test.

采用反相高效液相色谱法对单用硫唑嘌呤及醋酸泼尼松与硫唑嘌呤合用后，对家兔体内硫唑嘌呤的代谢产物六巯基嘌呤(6-MP)的血清药物浓度进行了测定，并对两组药物动力学参数进行配对t检验统计处理。

In order to solve these problems, supported by Foundation for University Key Teacher by the Minisity of Education, we study on distribution of sulfur in coal samples of ShenYang HongYang No. 3 coal mine and find that the sulfur in pyrite is more than 72％ in the total sulfur of the coal. The pyritic sulfur immerges in coal and is diffcult to be removed by common methods.

针对上述问题，我们在教育部高等学校骨干教师资助计划的支持下，以沈阳红阳三矿煤为试样，对其中硫的的赋存状态进行了研究，发现该试样中的硫有72％以上为黄铁矿硫，而且黄铁矿多数呈细小颗粒浸染于煤的有机质中，用常规分选方法脱除比较困难。

An increase of organic sulfur in pyrolysis of Hongmiao coal indicates that the lack of the indigenous hydrogen may be the key factor determining the transformation of pyritic sulfur into organic sulfur.

红庙煤在热解条件下有机硫明显增加表明，内在氢的不足可能是决定黄铁矿无机硫向有机硫转化的关键因素。

These experiment investigztions indicate: When coal is under high heating pyrolytic condition, the pyrite in coal decomposes very quickly, some amount of pyritic sulfur is transformed to organic sulfur and 〓 char, the volatile waterial in coal will restrain the transformation.

根据这一些试验研究得出：煤在快速热解条件下，煤中的黄铁矿的热分解极快，黄铁矿热分解的一部分硫转化成有机硫而存留在残炭中，煤中挥发份对这种硫的转化起抑制作用。

Second, residues in the reactive site of the inhibitor were replaced by the consensus substrate recognition sequence of furin, namely, Arg at P_1, Lys at P_2, Arg at P_4 and Arg at P_6. In addition, the P_7 residue Asp was substituted with Ala to avoid possible electrostatic interference with furin inhibition. Finally, the extra N and C terminal residues beyond the doubly conjugated disulfide loops were further truncated. However, all resultant synthetic peptides were found to be temporary inhibitors of furin and kexin during a prolonged incubation, with the scissile peptide bond between P1 and P'1 cleaved to different extents by the enzymes.

高活性、低分子量的furin酶抑制剂有可能发展成为新型的抗细菌内毒素和抗病毒感染的药物，我们以绿豆胰蛋白酶抑制剂Lys片段长链22肽为模板，设计了一系列能抑制furin和kexin活性的突变体，采用如下三种方法逐步优化：一、去除Lys片段长链三对二硫键中的一对，用Ser替换Cys，减少可能存在的二硫键错误配对；二、抑制剂的活性中心根据furin底物的专一性逐步改变，即P1、P2、P4和P6位分别变为Arg、Lys、Arg和Arg，同时为了避免P7 Asp和P6 Arg之间可能存在的相互作用，将P7位Asp替换为Ala；三、将两对二硫键形成的双环的外面5个氨基酸残基去除。

Sulfide layer was made on the surface of high speed steel (W6Mo5Cr4V2) by means of low temperature ion sulfurization. The tribological properties of the sulfide layer under dry sliding were investigated on an MM 200 friction and wear test rig. An atomic force microscope and a scanning electron microscope equipped with an energy dispersive spectrometer attachment were adopted to analyze the morphologies and compositions of the original and worn surfaces of the sulfide layer. The phase structure of the sulfide layer was determined by X ray diffraction.

采用低温离子渗硫工艺在 W6 Mo5 Cr4 V2高速钢表面制备了硫化物固体润滑层，在 MM- 2 0 0型摩擦磨损试验机上对渗硫层的摩擦学性能进行了干摩擦试验研究，用原子力显微镜及扫描电子显微镜和 X射线光电子能谱分析渗层表面、截面、磨面的形貌及成分，用 X射线衍射仪分析了渗硫层相结构。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。