硫

The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明，采用氯乙酸甲酯作为醚化试剂，反应时间4h，反应温度100℃，二苯甲硫醇：氯乙酸甲酯=1：1.5，室温下氨解反应20h，二苯甲硫乙酰胺收率76%；采用过氧化氢作为氧化试剂，反应时间3h，反应温度60℃，过氧化氢：二苯甲硫乙酰胺=1：l，莫达非尼收率79%，反应总收率可达48%。

Though the microorganisms capable to metabolic H〓S and CH〓SH respectively are Thiobacillis, their physiological characteristics are different. The former is acidophile, the optimum range of pH for which is 1～4; whereas, the latter is neutrophile.

代谢H〓S和CH〓SH的微生物菌群从形态上均有杆状硫细菌的特征，但两种菌群的生理特征不同，代谢H〓S的硫杆菌属嗜酸性微生物，代谢CH〓SH的硫杆菌属嗜中性微生物。

In chapter three, the activating agents of ytterbium have been examined. Barbier-type reaction promoted by ytterbium metal was examined. The experimental results shown that the yield of Barbier reaction of imines with allylic bromide promoted by ytterbium is higher than that of aldehydes and ketones with allylic bromide under the same reaction conditions. In this chapter, the reductive cleavage of Se-Se and S-S bond induced by ytterbium metal was also studied.

首先研究了金属镱的活化剂以及活化方法，接着考察了金属镱促进的Barbier反应及其在合成高烯丙基胺和高烯丙基醇中的应用，以及影响该反应的主要因素；究了金属镱促进的二硫醚和二硒醚的S—S键和Se—Se键的还原断裂，继而与氯代烃，胺基甲酰氯反应生成相应的硫醚，硒醚，胺基甲酸硫代酯和硒代酯。

Armed with this information and further analyses, Rumble, lead author Bekker, and colleagues propose the following scenario today in Science . Early in Earth's history, volcanic eruptions spewed massive amounts of sulfur dioxide into the atmosphere, where UV sunlight broke down the gas and created the odd sulfur isotope ratios. The sulfur descended with the rain and accumulated into sedimentary beds on the sea floor. Once there, superheated water from geothermal vents at various locations on the sea floor cooked the sulfur into sulfide. Finally, nickel-bearing magma welled up from Earth's mantle, combining with the sulfide to form nickel sulfide and encasing the compound inside volcanic rock called komatiite.

凭借这份资料和进一步的分析，朗布尔、研究论文的第一作者贝克及同事们今天在《科学》杂志上提出了如下的推测：在地球早期的历史上，火山爆发将大量的二氧化硫气体喷射到空中，太阳的紫外线将其分解，产生了奇特的硫同位素比值，这种硫随雨降下，积存于海底沉积层中；一旦到达海底，海底各处的地热出口所产生的温度过高的水把硫加热成硫化物；最终含有镍的岩浆从地幔中涌出，跟硫化物结合形成硫化镍，并将硫化镍包裹在一种叫做"科马提岩"的火山岩中。

There is no electron transfer from tetrakis(2-thienyl)tetrathiafulvalene to [60]fullerene containing piperidinoxanthate dyad in benzonitrile in steady-state.

四硫富瓦烯及其衍生物是良好的有机导体及电子给体，噻吩基取代的四硫富瓦烯可作为合成含噻吩及四硫富瓦烯两种电子给体的聚合物的单体。

At first the energy of the microwave will energized the argon to be ionization, and the generated heat make the sulfur volatilizing into bivalency sulfur or dipolymer sulfur high pressure steam. The molecule transition will happen under the microwave energization, and the visible light will be emitted when the sulfur states change into the low energy level. The spectra of the plasma lamp is nearly centering at the visible lights, and there are very little ultraviolet and infrared spectrum, the Fig 3 shows the spectra of the sun and the plasma lamp from which we can see the spectrum character clearly.

微波能量首先激励氩气使其电离，产生的热量使硫挥发成为二价硫分子或二聚物高压蒸汽，在微能量的激励下使它形成分子跃迁，当返回到较低能级的状态时以连续光谱的形式放射出光线，它的光谱基本上集中在可见光，红外线和紫外线的辐射量很少，（图3）硫的放射光谱和太阳光谱的比较图片，可以很清晰地表达这一特性。

According to the properties of substituted thiourea derivatives,4 symmetric and 12 unsymmetric thiourea compounds were synthesized by reaction of alkyl amine or substituted aniline with carbon bisulfide or some isothiocyanates .

针对不同活性的取代硫脲，采用脂肪胺或取代苯胺与二硫化碳或不同种类的异硫氰酸酯反应，合成了4种对称的和12种非对称的硫脲衍生物。

All of these results confirmed that the quenching effect of sulfur atom. The distance between sulfur atom and chromophore played an important role in the self-quenching effect.

通过实验，进一步证实了硫原子对发光基团的荧光淬灭作用，说明二硫代酯与发光基团之间的距离对硫的荧光淬灭作用有很大的影响。

SMM is the main precursor substance of DMS, and Cystine is one of the precursor substances of DMS in vegetables.

硫甲基蛋氨酸是蔬菜中甲硫醚主要的前体物质，胱氨酸是蔬菜中甲硫醚的前体物质之一。

This specific preparation methods including: parathion of the initial reaction in acid and zinc metal in the common under redox reaction, a product of the reduction of parathion - parathion, with the sodium nitrite in the cold under diazotization reaction, and bovine serum protein tyrosine on the o-hydroxy combination of the adult immune original and immune rabbit polyclonal antibody preparation.

本发明制备方法具体包括：以对硫磷为反应初始物，在酸和金属锌的共同参与下进行氧化还原反应，得对硫磷还原产物对氨基对硫磷，再与亚硝酸钠在低温下进行重氮化反应后，与牛血清蛋白酪氨酸上羟基的邻位结合，制备成人工免疫原，并免疫新西兰大白兔制备多克隆抗体。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐