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硝氨基

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3-Nitrodiphenylamine is generally synthesized by the Ullmann condensation of N-(3-nitrophenyl) acetamide with bromobenzene.

摘 要:间-乙酰氨基硝基苯与溴苯发生Ullmann缩合反应是制备3-硝基二苯胺最常用的方法。

In this paper,3-methoxy-5,6-diamino-2-nitropyridine was synthesized from 3,5-dichloropyridine by substitution,oxidation,nitration and ammoniation .

研究了以3-氯-5-甲氧基-2,6-二硝基吡啶为原料,通过甲氧化、硝化、氨化合成3-甲氧基-5,6-二氨基-2-硝基吡啶,该化合物的结构通过IR,1H NMR,MS和元素分析进行了表征,确认为目标化合物。

The obtained compound (2) was treated with borane-tetrahydrofuran (B2H6–THF) complex under nitrogen atmosphere in excessive THF for 18 h to give a kind of dark brown oil,followed by ammonolysis with NH3·H2O in autoclave at 100 ℃ for 6 h to produce 2-(5-amino-2- nitrophenyl) ethanol (3) in 84.4% yield.

用硼烷还原5-氟-2-硝基苯乙酸后,接着用氨水在高压釜中加热到100 ℃氨解,得到2-(5-氨基-2-硝基苯)乙醇(84.4%)。

In conclusion, the nitro group is the main toxic group for both nitrobenzenes and nitroanilines. Wrapping or reducing the nitro groups will decrease the toxicity of the subject chemicals.

总之, 硝基是这两类化合物致毒的主要基团,将硝基包覆或还原为氨基应为此类化合物解毒的重要途径。

The results indicate that the type and number of the substituents affect the toxicity of these compounds directly. A nitro group substitution increases the toxicity of the compounds, and on the contrary, an amido group substitution decreases their toxicity. For multi-nitrobenzenes, the toxicity of the o - or p -substituted nitrobenzene is bigger than that of the m -substituted one.

苯环上取代基的类型、数目和取代位置直接影响到标题化合物的毒性大小,强吸电子基如硝基会降低 Q -NO2和 E LUMO大小,使化合物毒性增强,且邻对位硝基取代的毒性高于间位取代;相反,给电子基团氨基的存在则会使化合物的毒性降低。

Nitrations of both hydroxyl- and acetamino-substituted porphyrins were found to take place at the adjacent position of the substituent in the very aryl ring, whereas nitro group was guided into para positions of unsubstituted phenyl ring during the nitration of nitro-substituted porphyrin.

结果表明,羟基和乙酰氨基卟啉的硝化反应发生在与该取代基处于同一芳环的meta位,而硝基卟啉进行硝化时,硝基取代于其他未取代苯环的para位。

Based on the mechanism of coupling reaction,the reaction of melt metallocene-based Poly(Ethylene-α-Octene) initiated by dicumyl peroxide was studied at elevated temperature in oscillatory shear flow field.

以苯胺、环氧丙烷为原料制备了N,N 二(2 羟丙基)苯胺,然后NHPPA与对硝基苯胺通过重氮偶合反应制备了一种具有推拉电子结构的偶氮化合物4 硝基 4′ N,N 二(2 羟丙基)氨基偶氮苯。

Nonlinear optical organic materials have more advantages than inorganic materials. Based on the molecule design, a new D-π-A structure NLO chromophore molecule [4-nitro-4'-N,N-di aminoazobenzene] 3 with nitro, azobenzene and epoxy is synthesized.

以环氧氯丙烷、苯胺、对硝基偶氮苯胺为原料,设计并合成了一种具有推拉电子结构、含双环氧基的偶氮类有机非线性光学发色团分子4-硝基-4'-N,N-二缩水甘油氨基偶氮苯。

The new research progress in synthesis of p aminophenol by chemical reduction,catalytic hydrogenation,electrochemical reduction and carbonic oxide reduction from nitrobenzene was reviewed.

评述了硝基苯化学还原法、催化加氢法、电化学还原法和一氧化碳还原法等合成对氨基苯酚的最新研究进展,认为对硝基苯还原法新技术的深入研究有利于医药和染料等行业的进一步发展,具有很好的社会和经济效益。

The nanocrystalline film was composed of a three-diminsional network of interconnected particles.Reodx behavior and electrocatalytic activities of the Ti/nano-TiO2 electrode were investigated by cyclic voltammetry from oxalic acid and nitrobenzene to glyoxalic acid and p-aminionphenol. The Ti/Ti redox system,as a medium,shows highly electrocatalytic activities and stable characteristic to indirect electroreduction of organic compounds(e.g.:oxalic acid and nitrobenzene).

循环伏安法研究了纳米TiO2膜电极对草酸还原为乙醛酸、硝基苯还原为对氨基苯酚反应的电催化活性,结果发现纳米膜中的Ti/Ti氧化还原电对起一种中介作用,可使有机物如草酸和硝基苯间接电还原,且电极催化活性高,性能稳定。

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