硝基苯胺

With the catalyst TiO2/SO(superscript 2- subscript 4), 2, 4, N-trinitroanilinoacetic acid was synthesized from chlorobenzene and glycine with yield of 71.6%.

以纳米固体酸TiO2/SO(上标 2-下标 4)为催化剂，氯苯和氨基乙酸为原料直接合成了2，4，N-三硝基苯胺基乙酸，收率为71.6%。

Some of yellow azo pigments have been synthesized by coupling of acetoacetarylide derivates with different substituted nitroaniline diazonium salts. The relationship between pigment structure and shade, m. p., and thermal stability, and the, effect of addition of surface active agent on coupling reaction product have been studied. TGA and differential thermal analysis in air of the pigments and the variance of visible spectra reflectance have also been determined.

以不同取代的硝基苯胺衍生物为重氮组分与乙酰基乙酰芳胺衍生物为偶合组分，合成数种黄色颜料，观察了不同表面活性剂对其偶合产物性能的影响；研究了颜料分子结构与色光、熔点及热稳定性之间的关系；测定了颜料热重曲线及加热试样对可见光反射性能的变化。

Here we found the optimum situation to determine LAP: the concentration of Tris-HCl is 125 mmol L^(-1) and the optimum pH is 7.2, temperature is 37℃, under this condition, Michaelis constant is 0.15 mmolL^(-1), ground substance concentration is 6.0 mmol L^(-1), with 157 health people serum samples (81 from male, 76 from female),x± s=35.7 UL^(-1)±8.2 UL^(-1), we established the method and reference value for clinical application and automatic analysis.

测定亮氨酰氨基肽酶的最适条件：选用浓度为125mmolL^(-1)的Tris-Hcl缓冲液，最适pH为7.2，温度取37℃，得出在此实验条件下的米氏常数Km为0.15mmolL^(1)，亮氨酰对硝基苯胺浓度取6.0mmolL^(-1)，取健康体检者血清157例（男81例，女76例），测得x±s为35.7UL^(-1)+8.2UL^(-1)，建立了适合于临床应用及有动生化分析仪的方法和参考值。

Methods Using 4-chloro-2-nitroaniline as a starting compound, followed by substitution, reductive cyclization, oxidation, and chlorination, to give the key intermediate 2,7-dichloroquinoxaline (7), which reacted with different phenolic compounds to afford quinoxaline derivatives.

方法以4氯2硝基苯胺为起始原料经取代、还原关环、氧化、和氯代合成了中间体2，7二氯喹喔啉(7)，再在喹喔啉的2位引入不同的取代酚结构单元，合成了一系列共9个新喹喔啉衍生物。

It was prepared from \%o\% nitroaniline and \%m\% aminophenol by diazotisation, coupling reaction and reduction, yield was 89%.

以邻硝基苯胺和间氨基酚为原料，经重氮化、偶合、还原制备了 2 (2 羟茎 4 氨基苯基)氢化苯并三唑，产率为 89%。

Poly{[2-(4-biphenylamino)phenyl]phenylenevinylene} was prep-ared with 4-nitroanline which was coupled with p-xylene,throughreduction、idionization、Ullmann reaction、bromization、condensepolymerizationto get the final product.

本文提出了两条合成聚(2-芳基苯撑乙烯)的新路线，即聚{ 2-[4-苯基]苯撑乙烯}是以对硝基苯胺为原料，其与对二甲苯经改良的Gomberg-Bachmann反应偶联、再通过还原、碘化、Ullmann反应、溴化、缩聚反应得到。

According to the result, we believed that the reason resulted in the low sensitivity was that the marker residue compound MQCA structure has changed after conjugated with protein and the antibody induced by the conjugation could not recognize the free MQCA in the ci-ELISA. Therefore we designed some hapten which could reserve the marker residue structural speciality mostly. After synthesis route selection and optimum, the hapten 7-Hydroxymethyl-3-methyl-quinoxaline-2-carboxylic acid was synthesized, used 4-methyl-2-nitroaniline as the start material via six steps, such as oxidation cyclization, bromize reaction, hydrolysis, Beirut reaction, reduction, hydrolysis. This work established basis for producing the high affinity antibody and developing the sensitive ELISA residue detection method.

本论文认为导致ELISA检测灵敏度较低的原因，是残留标示物和蛋白偶联后的特征结构发生改变，诱导产生的抗体不能够对游离MQCA很好的识别，因此，本论文设计了能够最大化保留MQCA结构特征的系列半抗原结构，并对其合成路线进行了筛选和优化，最终以对甲基邻硝基苯胺为起始原料，经氧化环化、溴代、水解、Beirut缩合、还原、水解六步反应制备含羟甲基结构的MQCA衍生物7-羟基甲基-3-甲基-喹噁啉-2-羧酸，为制备对游离残留标示物高亲和力的抗体，高灵敏度的ELISA残留检测方法的建立奠定基础。

The results showed that solubility of nitrobenzenamine and etherate increased with temperature increasing.

实验结果表明硝基苯胺和醚化物在二甲苯和甲苯中的溶解度均随温度的升高而增加。

Solubility of nitrobenzenamine in ternary system was higher than that in binary system,but the solubility of etherate did not change.

与二元体系相比，硝基苯胺在三元体系的溶解度增加，但醚化物的溶解度未发生变化。

Preparation of Nanosolid Superacid and Synthesis of 2,4,N-Trinitroanilinoacetic Acid Directly

篇名 纳米固体酸的制备及2，4，N-三硝基苯胺基乙酸的合成

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。