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The results show high selectivity when the temperature is controlled at 50 CC , and the nitrated reaction time is 90 mm, toluene is nitrated by using 95% nitric acid as nitrating reagent at the presence of acetic anhydride, 1.0g silicotungstic acid catalyst is calcinated at 300℃ for 1.5h. The o/p (ratio of ortho to paro isomer of toluene nitration) ratio is 0.89 in product distribution of toluene nitration, lower than 1.67 using sulfonitric acid as catalyst. The yield of products is 91.6%.

结果表明,在醋酐存在条件下,以CCl4为溶剂,以质量分数为95%的硝酸为硝化剂,反应温度控制在50℃,反应60 min, 1.0g经300℃焙烧1.5h后的硅钨酸催化剂,对甲苯表现出强的区城选择性,甲苯硝化产物o/p值(甲苯硝化产物邻位和对位异构体的质量比)达0.89,较硝硫混酸的1.67显著降低,产物收率达到91.6%。

The activated sludge autotrophic denitrifying BR process can realize stable operation after start-up and cultivation (mainly is endogenous denitrifying process) for 114d and the aerobic nitrifying sludge、anaerobic sludge、garden soil transudate as the inoculation sludge.

7以好氧硝化污泥、厌氧污泥、花园土壤渗出液为接种污泥,经过长达114天的启动培养阶段(以污泥的内源反硝化过程为主),自养反亚硝化活性污泥法BR工艺能够成功实现并稳定运行。

The results showed that the ammonifying rate, nitrifying rate, nitrosifying rate and denitrifying rate of bacteria in pond silt were significantly affected by the biomass and population composition of bacteria, physio-chmical characteristics of pond silt and water quality.

结果表明:淤泥中细菌的氨化率、亚硝化率、硝化率和反硝化率在很大程度上受淤泥中有机物的含量、细菌数量和种群组成、淤泥的理化性质及水质情况的影响。

The population distribution of physiological groups of bacteria,including ammonifying bacteria, denitrifying bacteria, nitrobacteria and nitroso bacteria, organic ph

用最大可能数法和平板计数法,于2002年1月~2003年3月对苏州河水体和底泥中的主要微生物功能菌群——包括有机磷分解菌、无机磷分解菌、氨化菌、亚硝化菌、硝化菌和反硝化菌等进行了生态调查,并分析探讨了它们在苏州河水生态系统中的作用。

Ammonifying rate, nitrosifying rate,nitrifying rate and denitrifying rate were determined by measurement of conversion efficiency and accumulating rate of nitrogenous matter by ammonifying bacteria, nitrobacteria, nitrifying bacteria and denitrifying bacteria in the surface 0-1.5 cm of pond sediment from the intensive fish culture ponds.

通过对精养鱼池表层淤泥中氨化细菌、亚硝化细菌、硝化细菌和反硝化细菌对含氮物质转化率的测定,定量了解了上述细菌的氨化率、亚硝化率、硝化率和反硝化率。

The population distribution of physiological groups of bacteria,including ammonifying bacteria, denitrifying bacteria, nitrobacteria and nitroso bacteria, organic phosphate dissolving bacteria and inorganic phosphate dissolving bacteria in water body and sediment of Suzhou Creek are studied with MPN and flat account method from Jan. 2002 to Mar. 2003. The role of these physiological groups of bacteria in Suzhou Creek aquatic ecosystem is discussed.

用最大可能数法和平板计数法,于2002年1月~2003年3月对苏州河水体和底泥中的主要微生物功能菌群——包括有机磷分解菌、无机磷分解菌、氨化菌、亚硝化菌、硝化菌和反硝化菌等进行了生态调查,并分析探讨了它们在苏州河水生态系统中的作用。

The kinetics process and temperature impact of natural groundwater denitrified by sulfur autotrophic was investigated. The results revealed that the denitrification rate of up-flow sulfur autotrophic denitrification filter followed a half-order kinetics model; and the reaction rate constant was mainly affected by the temperature. Based on the Arrhenius calculation, the activated energy was 80.38 kJ/mol.

研究实际地下水硫自养反硝化动力学过程,考察季节因素对动力学的影响,实验结果表明,地下水升流式硫自养滤柱反硝化动力学符合1/2级动力学模型,其反应速率常数受温度的影响很大,用阿仑尼乌斯方程计算硫自养反硝化活化能为80.38 kJ/mol。

Yield of nitrated porphyrins vibrated fiercely with different concentrations of nitric acid. It was found that nitration with 80% nitric acid (w/w, d = 1.45) could afford over 90% yield of mono nitrated TPP.

不同浓度的硝酸对硝化产物收率有较大的影响,论文首次以80%的硝酸为硝化试剂,适当条件下获得了收率超过90%的单硝化产物。

The results showed that BSA could be nitrated and oxidized by hemin-NO2--H2O2 system in all tested buffers, and the pH influence on BSA nitration was contrary to that of BSA oxidation: in pH range of 6.0-8.0, protein nitration was decreased with the increasing of pH, while protein oxidation was significantly increased.

实验结果表明,在五种缓冲溶液中,氯高铁血红素均能够有效催化NO2--H2O2体系引起的牛血清白蛋白的硝化和氧化,并且其导致的BSA硝化程度和氧化程度随pH值变化趋势相反:硝化程度随pH值的升高而降低;氧化程度随pH的升高而升高。

Toluene nitration was carried out with supported heteropolyacids as catalysts and N2O5 as nitrating agent.

用负载型杂多酸为催化剂,N2O5为硝化剂的新型硝化体系,对甲苯的硝化反应进行研究。

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