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硅酸盐

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The relationship between the crystal structure and their point of zero charge, the floatability of some silicate minerals with and without metal ions as activator, using sodium oleate as collector, the adsorption behavior of the metal ions on the silicate minerals, are investigated by analysis the crystal structure of the silicate minerals.

通过分析硅酸盐矿物晶体结构,研究硅酸盐矿物零电点与晶体结构的关系,硅酸盐矿物在油酸钠体系中的浮游特性,硅酸盐矿物对金属离子的吸附规律,金属离子活化的矿物可浮性规

Content structure of materials; crystal imperfection; structure of metallic surface, semiconductive oxide surface, structure of the molecular crystal surface, the rearrangement mechanism of the surface atoms and methods of surface analysis; fundamental theories about chemical processes and phenomena of plasma

课程内容:材料的结构;晶体缺陷;金属表面、半导体氧化物表面和分子晶体表面的结构和表面原子重排的机理,表面分析方法;等离子体的化学过程基础理论和化学现象及其特征;硅酸盐材料的通性和几种典型硅酸盐材料的结构,硅酸盐热力学和固相反应,硅酸盐固相烧结的过程和基本原理;典型高分子材料简介。

The most polluted areas is near Tianjin second gasworks and around sewage river as well as sewage irrigation area. So we can conclude the major sources of pollution is atmospheric deposition and sewage irrigation. Second, It is positive correlation between the heavy-metal contamination and layered silicate minerals, while it is negative correlation between heavy-metals and quartz , feldspar as well as other minerals.

二、重金属污染元素含量与层状硅酸盐矿物含量呈正相关,而与石英长石等矿物含量呈负相关,充分说明污染元素主要赋存在层状硅酸盐矿物中,这与矿物自身的结构有着密切的关系,层状硅酸盐矿物具有很大的层间域,有利于对其他物质的吸附作用。

As a whole,the notable characteristic of primary productivity in size-fractioned structure was that nanoplankton occupied comparatively significant advantage in Beibu Gulf.Nanoplankton has the largest contribution to gross primary productivity,and picoplankton was the secondary contributor,while microplankton the least.The contribution of microplankton for primary productivity in the north Gulf was more than that in the other waters.Nanoplankton and picoplankton contribute more to the gross primary productivity in offshore deep waters than in inshore shallow waters3.The Beibu Gulf can be divided into three ecoregions:Region-Ⅰis the ecoregion in inshore shallow waters of the north Gulf.In average,the water depth is 18m,DIN is 1.88μmol/L,DIP is 0.20μmol/L,N:P is 9.4:1,dissolved silicate is 5.17μmol/L,the Chl a conentration in surface layer is 2.27mg·m~(-3),the assimilation index in surface layer is 3.80mg/,the primary productivity is 198.78mgC/(m~2·d), and potential fishery production is estimated to be 0.24gC/(m~2·a) according to the primary productivity.The ecoregion is mainly affected by the northern coastal water systems,and may be fit for aquaculture;Region-Ⅱis the ecoregion in offshore deep waters of the north Gulf and the coastal shallow waters to the west Hainan Island.In average,the water depth is 35m,DIN is 2.01μmol/L,DIP is 0.18μmol/L,N:P is 11.2:1,disovled silicate is 4.23μmol/L,the chlorophyll a of surface layer concentration is 1.45mg·m~(-3),the assimilation index of surface layer is 4.12 mg/,the primary productivity is 276.60mgC/(m~2·d),and the estimated potential fishery production is 0.34gC/(m~2·a) according to the primary productivity. The ecoregion was mainly influenced by ocean current from the South China Sea, rivers in the west coast of Hainan Island and the water from Qiongzhou Strait.It may be fit for aquaculture and fishery;Region-Ⅲis the ecoregion in offshore deep waters of the mid and south Gulf.In average,the water depth is 75m,DIN is 0.77μmol/L, DIP is 0.15μmol/L,N:P is 5.1:1,disovled silicate is 3.05μmol/L,the chlorophyll a of surface layer concentration is 0.70mg·m~(-3),the assimilation index of surface layer averaged is 3.69mg/,the primary productivity is 350.89mgC/(m~2·d),and the estimated potential fishery production is 0.43gC/(m~2·a) according to the primary productivity.The ecoregion was mainly affected by the circulation inside Beibu Gulf, and may be fit for fishery.

初级生产力的粒级结构的一个显著特点是总体上微型浮游生物在全调查海区均占较明显优势,对总初级生产力的平均贡献最大;微微型浮游生物对初级生产力的平均贡献次之;小型浮游生物对总初级生产力的平均贡献最小;湾北部小型浮游生物对初级生产力的平均贡献高于湾中部和湾南部,而湾中部和湾南部微型和微微型浮游生物对初级生产力的平均贡献高于湾北部,远岸深水区高于近岸浅水区。3、北部湾可以分为三个生态区:湾北部近岸浅水区,该区的环境主要特点是平均水深19m,DIN浓度平均值为1.88μmol/L,DIP浓度平均值为0.20μmol/L,N:P为9.4:1,硅酸盐浓度平均值为5.17μmol/L,表层叶绿素a平均值高达2.27 mg·m~(-3),表层同化指数平均为3.80 mg/,初级生产力平均值198.78mgC/(m~2·d),根据初级生产力计算潜在渔业资源碳生产量平均为0.24 gC/(m~2·a),该区主要受湾北部沿岸水系影响,适合作为水产养殖区;湾北部深水区和海南岛西部沿岸浅水区,该区的环境主要特点是平均水深35m,DIN浓度平均值为2.01μmol/L,DIP浓度平均值为0.18μmol/L,N:P为11.2:1,硅酸盐浓度平均值为4.23μmol/L,表层叶绿素a平均值1.45 mg·m~(-3),表层同化指数平均为4.12mg/,初级生产力平均值276.60 mgC/(m~2·d),根据初级生产力计算潜在渔业资源碳生产量平均为0.34 gC/(m~2·a),该区主要受南部湾口区海流向湾内延伸,沿岸海南岛河流注入湾内和琼州海峡过道水的影响,适合作为渔业作业区和水产养殖区;湾中部和南部远岸深水区,该区的环境主要特点是平均水深75m,DIN浓度平均值为0.77μmol/L,DIP浓度平均值为0.15μmol/L,N:P为5.1:1,硅酸盐浓度平均值为3.05μmol/L,表层叶绿素a平均值0.70 mg·m~(-3),表层同化指数平均为3.69 mg/,初级生产力平均值350.89 mgC/(m~2·d),根据初级生产力计算潜在渔业资源碳生产量平均为0.43 gC/(m~2·a),该区主要受北部湾环流影响,适合作为渔业作业区。

The thermodynamic calculations of the Gibbs free energies for typical multiple phase equilibria in silicate systems were performed,including (1)melting reactions of silicate reactant in processing of the glass-ceramics;(2)sintering reactions in utilizations of nepheline syenite and high- flyash;(3)crystallizing reactions of tobermorite and xonotlite .

硅酸盐体系的典型多相平衡反应进行了热力学计算,包括:(1)微晶玻璃制备过程中的硅酸盐熔融反应;(2)霞石正长岩和高铝粉煤灰利用技术中的硅酸盐烧结反应;(3)S iO2-CaO-H2O体系和KA lS i3O8-CaO-H2O体系雪硅钙石、硬硅钙石的水热晶化反应;(4)高铝粉煤灰和霞石正长岩烧结产物的溶解反应;(5)Na[A l4]-A l3-H2O体系和Na2SO4-Ca2-H2O体系中α-A l3和CaSO4.2H2O的析晶反应。

It is the fluorosilicic ion that exsits in the slurry and plays an important role in flotation, fluorosilicic ion not only reacted with Fe〓 on the surface of aegirine to form ionic compound, but also formed stable Si-F bond in Si-O etching reaction. Only ionic compound was obtained when it was attached to hematite surface according to the theories of coordination chemistry, Compared with SiF〓, Fatty acid ion preferentially acts with Fe〓 on the minerals surface, therefore, SiF〓 Can't obstruct the adsorption of collector on the surface of hematite completly, but can reduce the flotation recovery of aegirine selectively.

运用FTIR、XPS等测试方法仔细研究了氟硅酸盐抑制剂对含铁硅酸盐钠辉石的选择性抑制作用机理,氟硅酸盐在弱酸性条件下对赤铁矿浮选的抑制作用很微弱,而对含铁硅酸盐钠辉石强烈抑制,从而扩大了两者之间的浮选差异;SiF〓是矿浆中起抑制作用的主要成分,SiF〓不仅与钠辉石表面的Fe〓形成离子型配合物,而且还与Si-O键形成稳定的Si-F共价键,而与赤铁矿表面只能形成离子型配合物,根据晶体配位场理论,与SiF〓相比较羧酸根离子将优先与矿物表面Fe〓发生配位作用,因此SiF〓的存在并不能完全阻碍捕收剂在赤铁矿表面的吸附作用,却能够选择性地抑制钠辉石的上浮。

Inosilicate: Any of a class of inorganic compounds that have structures characterized by silicate tetrahedrons (a central silicon atom surrounded by four oxygen atoms at the corners of a tetrahedron) arranged in chains .

链状硅酸盐:旧称偏硅酸盐。由硅酸盐四面体(四面体角上的四个氧原子围绕着一个中心硅原子)排成链状结构的化合物。

Inosilicate: Any of a class of inorganic compounds that have structures characterize d by silicate tetrahedrons (a central silicon atom surrounded by four oxygen atoms at the corners of a tetrahedron) arranged in chains.

链状硅酸盐:旧称偏硅酸盐。由硅酸盐四面体(四面体角上的四个氧原子围绕着一个中心硅原子)排成链状结构的化合物。

Watering concrete curing time, the introduction of Portland cement, ordinary portland cement or slag cement concrete mixing shall not be less than 7d; retardation of mixed type with admixtures, the impermeability requirements, or ash cement, fly ash cement concrete mixing shall be not less than 14d; of mixing using alumina cement concrete not less than 3d.

混凝土的浇水养护时间,对采用硅酸盐水泥、普通硅酸盐水泥或矿渣硅酸盐水泥拌制的混凝土不得少于7d;对掺用缓凝型外加剂、有抗渗性要求、或用火山灰水泥、粉煤灰水泥拌制的混凝土不得少于14d;对采用矾土水泥拌制的混凝土不少于3d。

Since silicate minerals are major rock-forming minerals and some silicate minerals have also very high value, so silicate minerals are the important research object of mineral processing, but because structue of silicate minerals is very complex, separation problem between silicate minerals and valuable minerals become one of difficult problems which puzzle engineers of mineral processing.

由于硅酸盐矿物是主要的造岩矿物,某些硅酸盐矿物本身还具有很高的价值,因此硅酸盐矿物是矿物加工研究的重要对象,但由于硅酸盐矿物结构复杂,故硅酸盐矿物与有用矿物之间的分离问题成为一直困扰矿物加工界的难题之一。

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