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硅烷

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The composition comprises: 35 to 65 wt % of an anionic detergent or surfactant selected from alkyl benzene sulphonic acids, alpha olefine sulfonates, long chain fatty acid sulphates, higher fatty acids, as well as the alkali metal and alkaline earth metal salts thereof, and natural detersive agents, and mixtures of any of these; 3 to 15 wt % of a non-ionic detergent or surfactant selected from alkoxylated alkyl phenols and alkoxylated fatty alcohols; 5 to 10 wt % of a water-swellable cellulose derivative or a salt thereof, wherein the cellulose derivative exhibits a viscosity of at least about 1500 cps, measured in a 1 % aqueous solution at 25 DEG C with a Brookfield viscometer having spindle 3, speed 30rpm, factor 40 for viscosities of 2500-3500 cps; 6 to 20 wt % of a solubility regulator selected from alkali metal and alkaline earth metal chlorides, carbonates and sulphates, aluminosilicates and starch; and 0 to 20 wt % of a fragrance or perfume in solid, liquid or microencapsulated form.

该组合物包含:a35―65%重量的阴离子洗涤剂,其选自烷基苯磺酸、α-链烯烃磺酸盐、长链脂肪酸硫酸盐、高级脂肪酸以及其碱金属和碱土金属盐和天然的去污剂,和任何这些组分的混合物;b)3―15%重量的非离子洗涤剂,选自烷氧基化烷基酚和烷氧基化脂肪醇;c)5~10%重量的水可溶涨的纤维素衍生物或它们的盐,其中纤维素衍生物按1%水溶液在25℃下用Brookfield粘度计(3号转轴,转速30rpm,2500―3500cps粘度的因子是40测定;具有粘度至少约1500cps;d)6―20%重量的溶解性调节剂,选自碱金属和碱土金属氯化物、碳酸盐和硫酸盐、硅铝酸盐和淀粉;和e)0~20%重量的为固体、液体或微囊包封形式的香精。

To avoid the low yield in direct hydrosilylation addition of allyamine, 1, 1, 1, 3, 3, 3-hexamethyldisilazane is used to protect the amino groups, and the protective groups are removed easily after hydrosilylation addition, then the high yield of ladderlike copolymethyl-aminpropylsilsesquioxane was obtained.

为了克服将烯丙基胺直接与聚氢基甲基倍半硅氧烷进行硅氢加成反应接枝效率低的缺点,探索用六甲基二硅氮烷对烯丙基胺预保护,硅氢加成反应后再脱保护,从而以较高产率制备了含胺丙基、甲基的反应性梯形共聚倍半硅氧烷。

The best results 98% ee, 94% ee and 59% ee were obtained in silylcyanation of aldehydes, borane reduction of prochiral ketones and ketimines, respectively.

醛的硅氰化反应ee值最高达到98%,酮的硼烷还原反应ee值达94%,而亚胺的硼烷还原反应ee值只有59%。

The recent progress in molecular design and synthesis of polyborosilazane precurosors for SiBCN ceramics is reviewed.Especially the borazine modified polyborosilazane,monofunctional borane modified polyborosilazane on side chai...

本文分4个方面,即基于硼吖嗪的聚硼硅氮烷、侧基含有环硼氮烷或单硼烷的聚硼硅氮烷、基于多官能硼烷构筑的聚硅氮烷和含硼聚硅基碳化二亚胺,从聚硼硅氮烷分子结构设计、改性、合成及在多维尺寸材料中初步应用的角度综述了该领域国内外研究的新进展,指出了聚硼硅氮烷陶瓷前驱体设计合成研究发展中值得关注的新方向。

Thirty-one new chiral phosphorus compounds have been synthesized starting from D-camphor,-alpha-phenylethylamine,-Betti base,-1-(4-nitrophenyl)-2-amino- propane-1,3-diol, L-amino acids (such as serine, phenylalanine, proline etc.) and their application as organocatalysts in asymmetric trimethylsilylcyanation of aldehydes and asymmetric borane reduction of prochiral ketones and ketimines were investigated.

该项目从D-樟脑、-alpha-苯乙胺、-Betti碱、-氯酶胺、L-氨基酸(如丝氨酸、苯丙氨酸、脯氨酸等)出发合成了31个新的手性磷化合物,研究了它们作为有机催化剂在醛的不对称硅氰化反应、潜手性酮的不对称硼烷还原反应以及亚胺的不对称硼烷还原反应中的催化效果。

In our knowledge, only a few macromolecules have been used as coating materials.

对于硅烷化磁性微粒的制备及其在分子生物学中的应用,尚处于空白。

Then dendrimer-like polyamidoamine on the silica gel surface was prepared using Micheal addition of the amino and methyl acrylate,and ester-exchange of ethylene diamine and the ester group.

硅烷偶联剂对硅胶表面进行氨基功能化,利用氨基与丙烯酸甲酯发生的Michael加成反应和乙二胺与酯进行的交换反应在硅胶表面合成了聚酰胺-胺树状大分子。

Then dendrimer-like polyamidoamine s based on the silica gel surface were prepared using Micheal addition of the amino and methyl acrylate,and ester-exchange of ethylene diamine and the ester group.

硅烷偶联剂对硅胶表面进行氨基功能化,利用氨基与丙烯酸甲酯发生的Michael加成反应和乙二胺与酯进行的交换反应在硅胶表面合成了聚酰胺-胺树状大分子;利用红外光谱对PAMAM-SG的结构进行了表征,研究了溶液pH值、ρ(Ni2+)和温度对PAMAM-SG吸附Ni2+能力的影响。

Amino functional silica gel was synthesized by reacting silane coupling agent with silica gel. Then dendrimer-like polyamidoamine on the silica gel surface was prepared using Micheal addition of the amino and methyl acrylate, and ester-exchange of ethylene diamine and the ester group.

硅烷偶联剂对硅胶表面进行氨基功能化,利用氨基与丙烯酸甲酯发生的Michael加成反应和乙二胺与酯进行的交换反应在硅胶表面合成了聚酰胺-胺树状大分子。

The synthesis methods of hexamethyldisilane, such as reductive coupling reaction, Grignard reagent alkylation, electrochemical reduction et al, were recounted in details.

综述了近年来国外关于六甲基二硅烷的合成工艺(还原耦合法、格氏试剂法、电解还原法等);并就其未来的研究方向提出了建议。

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