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This paper first stated the hydrolysis law of organochlorosilane and the effect of various R/Si and ph/R on the properties of propolymer,there showed the mathematical calcu- lation method and computer progrom of the every monomer amount to synthetize propolymer, and provided the necessary theortical basis and quantitive calculation equation for the syn- thetise,In addition,the co-existing structure model of linear and trapezoid was put forward on the analysis of prepolymer micro-structure,which laid a found...

本文阐述了有机氯硅烷单体的水解规律及不同R/Si和ph/R值对预聚体性能的影响,在此基础上,提出了合成预聚体所需各单体用量的数学计算方法和计算机计算的程序,为合成提供了必要的理论依据和定量的计算公式。此外,文章在剖析预聚体微观结构的基础上,提出了线型与梯型结构并存的结构模型,为进一步更深入地认识预聚体的性能奠定了理论基础。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯-b-聚甲基丙烯酸十四酯-b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷,通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构,并研究了其对玻璃纤维/聚丙烯复合材料力学性能的影响。

And the healing agent containing both multiply vinyl group and double SiH bonds was prepared by reducing the oligomer by lithium aluminum tetrahydride.,dichloropolymethylvinylsiloxane was prepared by hydrolyzing partially of MeViSiCl2 under nitrogen protected in ether.

甲基乙烯基二氯硅烷在氮气保护下,以乙醚为溶剂进行非充分水解,得到,二氯聚甲基乙烯基硅氧烷,再经过LiAlH4还原可得兼有多个乙烯基和两个SiH键的自修复单体。

Mercaptopropyl methyldimethoxysilane was synthesized by thiourea in the presence of tetramethylammonium iodine as a catalyst and mixed liquid containing ethylenediamine and trichloroethylene as a neutralizer, without solvent, in which the reaction temperature, catalysts ,neutralizer and their amounts were optimized.

以四甲基碘化铵为催化剂,乙二胺和三氯乙烯的复合液为中和剂,在无溶剂体系中,用硫脲法合成了甲基巯丙基二甲氧基硅烷

The Limit Oxygen Index also can be raised from 16.5 to 22 and 23 respectively.The Octaphenyl POSS is synthesized via the hydrolysis and condensation of phenyltrichlorosilane (PhSiCl_3) and the subsequent rearrangement reaction catalyzed by tetramethylammonium hydroxide. Poly are easily synthesized from Ph-POSS via bromination with Br_2/Fe system.

以苯基三氯硅烷为起始原料,通过水解缩合、催化重排的办法制备了八聚苯基笼型倍半硅氧烷,在Fe粉催化条件下将溴元素引入Ph-POSS的苯环得到Br-POSS;使用该种Br-POSS和Sb_2O_3的混合物(3∶1,质量比)作为聚苯乙烯树脂的添加剂,采用熔融共混法制备(Br-POSS+Sb_2O_3)/PS复合材料。

In order to study the effect of microstructure on the superhydrophobic solid surface for its drag reduction charactertics, micro-ridges grating structures on the basis of K9 glass flat surface were fabricated using femtosecond laser. Experiments were carried out to measure the rheological characterization of 40% glycerin solution on flat and grating structured K9 glass surfaces using AR-G2 rheometer respectively. Both surfaces were modified with trichloro perfluoroocty silane in drying oven.

为了研究超疏水固体表面的微结构对减阻特性的影响,首先利用飞秒激光加工技术在光滑K9玻璃基面上加工出微脊光栅结构,然后将光滑K9玻璃与光栅结构K9玻璃置于干燥箱内进行硅烷化处理,以降低表面自由能,最后用AR-G2流变仪测量两表面的流变特性,试验用流体为体积分数40%的甘油溶液和水。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

The composite material is composed of knitted or unknitted natural fiber which is modified at the surface, polylactic acid and silane coupling agent.

该复合材料由经过表面改性的编织或未编织的天然纤维、聚乳酸和硅烷偶联剂组成。

The velocity of ventilation across all unwelded fittings should be adequate to prevent the accumulation of silane in the case of a leak.

通过所有无焊接装置的通风速度必须足以防止在泄露情况下的硅烷积累。

The micropheres activized by composite silane coupling agent can partly subsitute SRF and be doped in SBR/NR.

采用Si-1和Si-3协同处理微珠,其填充制品性能优于单一硅烷偶联剂处理微珠效果。

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