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The adsorptions of SiH_2, SiH_2 with a hydrogen adatom (SiH_2+H) and SiH_2 with two hydrogen adatoms (SiH_2+2H) on the Si (100) surface near SDV structure have been calculated. Three possible sites are found in each case, and the presenting of hydrogen may reverse the relative stability of these sites.

本文首先计算分析了SiH_2、SiH_2+H和SiH_2+2H等硅烷分解后的产物在硅表面的吸附特性,我们发现每种情况都有三个可能吸附的位置,并且表面附着氢原子的出现可以造成这些吸附位置相对稳定性的逆转。

The titanium silicide fims were prepared on glass substrate by atmospherical pressure chemical vapor deposition using SiH_4 and TiCl_4 as the precursors and diluted N_2,simulated the technics of coating on line,in the deposition reaction temperature about 640-730℃.

模拟在线镀膜工艺,采用APCVD方法,以普通载玻片作为基板,硅烷(SiH_4)、四氯化钛(TICl_4)为先驱气体,氮气(N2)稀释,沉积反应温度在640~730℃之间,制备硅钛化合物薄膜。

Further more, to make the hybrid microspheres with good dispersibility in aqueous media, 3-propyl triethoxysilane was added to copolymerize with St and DVB, and after hydrolization the microspheres with silanol groups on the surface were obtained, which can be well dispersed in water and used for cell imaging.

进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体,得到了表面硅羟基功能化的聚苯乙烯荧光微球,改善了微球在水相中的分散性,并将此类荧光功能微球成功用于细胞成像。

The main products are lndustrial Crotonaldehyde,Mixture of Organosilicon Monomer,Industial Sodium Polyacrylate and acrylate bond.

目前,主要产品有松江牌丁烯醛、有机硅混合单体、甲基氯硅烷等系列产品、工业聚丙烯酸钠、丙烯酸酯类粘合剂等系列产品。

Hyperbranched polymer; siloxysilane; metallic haloid catalyst; UV curing; kinetics

超支化聚合物;硅氧基硅烷;金属卤化物催化;紫外光固化;动力学

The monochloro methane is used for the methyl chloresilane element original material and organo silicone.

一氯甲烷主要用作甲基氯硅烷单体原料,用于有机硅行业。

Three part of research works had been carried out in the dissertation. The first part: a kind of multidentate amine modified silica gel was synthesized through the following steps:(1) introduce the amino groups onto the surface of silica-gel by the treatment of surface silanol groups withγ-aminopropyl trimethoxy silane;(2) michael addition of excess trihydroxymethyl propyl triacrylate to amino groups on the silica gel surface;(3) amidation of the unreacted double bonds of TMPTA on the surface of TMPTA modified silica gel with diethylenetriamine;(4) the multidentate amine modified silica gel was finally obtained by the reaction of amino groups on the surface of DETA modified silica gel with double bond of butyl acrylate.

本论文进行了三部分研究工作,第一部分:通过多步反应对硅胶进行改性合成了一种多齿胺改性硅胶配体,合成过程如下:1通过γ-氨丙基三甲氧基硅烷与硅胶表面的硅羟基反应,使硅胶表面带有氨基;2利用硅胶表面氨基与过量的三羟甲基丙烷三丙烯酸酯发生Michael加成反应;3利用二乙烯三胺与TMPTA改性硅胶表面未反应的双键发生反应使硅胶表面氨基化;4最后用丙烯酸正丁酯与DETA改性硅胶表面氨基充分反应成功合多齿胺改性硅胶配体。

So the development of organosilicon industry depends on synthesize technology of organochiorosilanes (especially for methylchlorosilane) mainly.

换言之,一个国家有机硅工业的发展水平,很大程度上取决于甲基氯硅烷的主产水平。

The objective in this study is to reduce the aggregate phenomenon of SiO2-sol and improve the storage/release thermal properties of the composite phase change materials. Silicane coupling agent was used to modify the SiO2sol during preparing CPCMs by sol-gel method.

为改善溶胶-凝胶法复合相变材料过程中硅溶胶易团聚的问题,采用硅烷偶联剂对SiO2溶胶进行改性,提升复合相变材料的热储、放性能。

A pair of FRET(frequency resonance energy transfer) donor-acceptor chromophores were simultaneously labeled on immunoglobulin G at varied ratios to prepare the spectroscopically encoded core materials,which were then housed inside a silica shell by the hydrolysis and polycondensation of tetraethoxysilane in water-in-oil microemulsion to synthesize the optically encoded silica nanomaterials.

采用两种FRET供受体荧光染料按不同的比例与载体材料人免疫球蛋白作用制备荧光编码的载体材料,以荧光编码的载体材料为内核材料,利用氨水催化硅烷化试剂在反相微乳液中水解包裹内核材料制备成一系列多色光学编码硅壳纳米材料。

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