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硅烷

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The rubber compound comprises a rubber which has at least two functional groups which can be cross-linked by hydrosilylation, a cross-linking agent consisting of hydrosiloxane or a hydrosiloxane derivative or a mixture of several hydrosiloxanes or derivatives, which comprise at least two SiH-groups per molecule in the centre, a hydrosilylation catalyst system, at least one filling material and a coagent which can be cross-linked by hydrosilylation.

为此该橡胶混配物包括:具有至少两个可通过氢硅烷化交联的官能团的橡胶;作为交联剂的氢硅氧烷或氢硅氧烷衍生物或者由数种氢硅氧烷或其衍生物组成的混合物,所述氢硅氧烷或其衍生物平均每个分子具有至少两个SiH基团;氢硅烷化催化剂体系;至少一种填料;和可通过氢硅烷化交联的助剂。

Two ferrocenyl and trimethylsilyl substituted cyanohydrin ethers have been prepared by the addition of trimethysilyl cyanide to two acetyl-substituted ferrocenes: 1-(1-cyano-1-trimethylsilyloxyethyl)-ferrocene (1) and 1, 1'-bis(l-cyano-1-trimethylsilyloxyethyl)ferrocene (2). The structures of these two compounds were characterized by elemental analysis, IR, 1H NMR and X-ray crystallography.

通过两种取代的乙酰基二茂铁与三甲基氰硅烷的加成反应,得到两种取代二茂铁基三甲基硅烷基氰醇醚的晶体:1-(1-氰基-1-三甲基硅烷氧基乙烷基)二茂铁(1),1,1-二(1-氰基-1-三甲基硅烷氧基乙烷基)二茂铁(2),用X射线单晶衍射、元素分析、红外光谱和核磁共振氢谱对分子结构进行了表征。

Base on analysis on production and development of silane coupling agent and polysilicon in China . it is forecast that by 2010 the market demand on trichlorosilane in China will reach above 300,000t, by then , silane coupling agent and polysilicon may go halves on the market of trichlorosilane By 2015 , the demand on trichlorosilane will amount to more than 80,000t .

根据对我国硅烷偶联剂及多晶硅生产发展的分析,预训2010 年,我国二氯氢硅的市场需求量应达到30万t 以上,届时,硅烷偶联剂和多晶硅有可能平分三氯氢硅的市场。2015 年,我国三氯氢硅的需求量应达到8 万t 以上。

Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives

三甲基一氯硅烷、二氯甲烷、AE活性酯、三甲基碘硅烷、特戊酸、特戊酰氯、三乙胺、噻二唑、四氮唑乙酸、二甲基乙酰胺、四氢呋喃、四甲基胍、异丙醇、五氯化磷、异辛酸钠、苯乙酸、苯乙酸钠、六甲基二硅胺烷、乙酰乙酸乙酯、甲基异丁酮、磷酸二氢钾、三氧化二铝、DL蛋氨酸、N,N-二甲基苯胺、NN-二乙基苯胺、乙二胺四乙酸四钠、无水硫酸钠、硫酸铵、硫酸钾、醋酸钠、碳酸钠、碳酸二甲酯、甲酸、药用氯化钠、草酸、片碱、丙酮、正丁醇、冰醋酸、醋酸乙酯、醋酸丁酯、甲醇、乙醇、甲醛、液碱(30%)、盐酸(工业级、精制级、试剂级)、硫酸(98%)、氨水、碳酸钙、二氧化氯、6-APA、7-ACA、7-ADCA 、7-ANCA、舒巴坦、头孢他啶活性酯、邓盐(羟甲基钾、前体酸钾、二氢甲基钠)、树脂、生物酶、水处理剂、消沫剂、破乳剂、絮凝剂、活性碳、各种药用辅料、各种添加剂

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷,包括:γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3,4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3,4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

While all the phenyl groups in tetraphenylphenyl groups or benzophenanthrene groups are not coplanar. At the same time, by density function theory, the electronic energy gap between HOMO and LUMO frontier molecular orbitals of condensed aromatics are calculated and the Eg of acenaphthenyl groups in C_2 gum is the smallest, which explains the reason why C_2 gum has the best radiation protection effects.

利用甲基三氯硅烷和溴苯的格氏反应合成了甲基苯基二氯硅烷,用核磁分析证实了格氏反应中高沸点副产物为甲基二苯基氯硅烷;通过甲基苯基二氯硅烷和二甲基二氯硅烷的共水解,再裂解而制得含Me_2SiO链节的甲基苯基环硅氧烷混合物,进而利用碱胶开环聚合得到甲基苯基硅橡胶生胶;也可通过甲基苯基二氯硅烷水解所得甲基苯基环硅氧烷D_3~(3Ph、D_4~(4Ph_)与D_4开环聚合制得甲基苯基硅橡胶生胶。

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况:三氯氢硅:又名三氯硅烷、硅氯仿,主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成,是有机硅烷偶联剂中最基本的单体,也是生产半导体硅、单晶硅的原料;四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用,在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统,下步可制取多晶硅。

Organosilicon high-boiling components was by-product from direct synthesis of methylchlorosilanes,The routes for production of monosilane,silicone oil,organosilicon water-proof agent,defoaming reagent,ceramics,organosilicon resin from the high-boiling components and their technical features were outlined,and some suggestions on development direction of catalysis cracking were put forward.

有机硅高沸物是合成甲基氯硅烷单体的副产物,作者简述了利用有机硅高沸物制备单硅烷、硅油、有机硅防水剂、消泡剂、陶瓷和有机硅树脂等产品的生产方法及技术特点,并对高沸物催化裂解产业化的发展方向提出了建议。

The synthesis of hyperbranched poly based upon 1,2-bis diallyl (methyl silyl ethane (B4) as a core molecule and diallyl silane (AB2) monomer via hydrosilylation addition have been investigated: And the hyperbranched poly were prepared using onestep without core, one-step with core and pseudo-one-step methods.

以四烯丙基硅烷(B4)为核、甲基氢二烯丙基硅烷(AB2)为单体,通过硅氢加成反应,采用无核一步法、核一步法、核多步法合成了超支化聚有机硅破烷。

Organosilicon resin microparticles with phenyl and aminopropyl groups were prepared via the hydrolytic co-condensation of phenyltriethoxysilane,γ-aminopropyltriethoxysilane and diphenyldimethoxysilane under the catalysis of tetramethylammonium hydroxide.

在四甲基氢氧化铵水溶液的催化作用下,将苯基三乙氧基硅烷、γ-氨丙基三乙氧基硅烷和二苯基二甲氧基硅烷进行水解共缩聚制备氨丙基苯基有机硅树脂微粉。

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