硅化的

The preventive measures for the harmful defects of alkali metals are as follows: 1, reducing the alkali metals content in the raw materials; 2, increasing the MgO content of the sinter , decreasing the basicity of slag , decreasing the Si content of the pig iron, increasing relative slag volume; 3 , introducing prereduced ore pellets or partly reducted sinter; 4increasing the ability of coke resisting alkali metals; 5, using refractories that have the ability of resisting corrasion of alkali metals; 6 , cleaning the blast furnace periodically. The above recommendations are necessary for decreasing the circulation and accumulation of alkali metals effectively in blast furnace, reducing the harmful influence of alkali metals on blast furnace, increasing the smelting intensity, decreasing the coke rate, improving the gas permeability.

基于碱金属对高炉冶炼的上述危害，本文结合湘钢高炉的实际生产情况，通过理论分析、计算以及其他钢厂防治碱害的经验，提出防治高炉碱害的措施：1、减少入炉原、燃料的碱金属含量；2、提高烧结矿中的MgO含量、降低炉渣碱度、降低生铁含硅量、适当增加渣量；3、采用预还原的金属化球团或部分还原的烧结矿；4、提高焦炭的抗碱能力；5采用抗碱侵蚀的耐火材料；6、周期性性洗炉，以有效地减少碱金属在高炉内的循环富集，降低碱金属对高炉的危害，提高高炉的冶炼强度，降低焦比，改善高炉透气性。

Abstract］ Objective To Treating the nano-SiO2 particle by silicon coupling reagent, functionalize the SiO2 by making double bond on its surface. Polymerizing on the surface of nano-SiO2 surface by the method called emulsion polymerization, the nano-SiO2 is covered by polymer to get the PMMA-KH-570-nano-SiO2 complex material. Test the surface structure of the surface of nano-SiO2 by FTIR, and test sort of its mechanical performances.Comparing the treated nano-SiO2 which is directly dispended in the PMMA emulsion with the SiO2 without any treatment, we are trying to find an effective method which can not only increase the dispersion of SiO2, but also improve the mechanical performance of the artificial teeth.

目的 通过硅烷偶联剂KH-570处理SiO2纳米粒子，向其表面引入双键使其功能化，采用乳液聚合的方法在SiO2纳米粒子表面进行接枝聚合，实现高分子对SiO2纳米粒子的表面包覆处理，制得PMMA－KH-570－SiO2纳米复合材料，采用FTIR对SiO2纳米粒子表面结构进行了表征研究，并且测定了它的多种机械性能，与表面处理过的SiO2纳米粒子直接分散至PMMA乳液中制得的复合材料、未添加任何增强物质的空白组进行比较，探索一种能够提高SiO2在基体中的分散性，为义齿复合材料的研究和开发提供理论依据和参考。

Based on the deterioration mechanism of corrosive medium, a lot of polymer such as ternary-polymer, adding-felt addition, hydrophobe and polypropylene fiber were added to enhance the performance of anti-corrosion, anti-penetration, conglutination and anti-cracking of original cementious material. The microstrure of cementious material was changed from the simplex hydration product of cement to the superposition structure of the hydrolysate of polymer and the hydration product of cement. A lot of the corrosive ions were prevented from the interior of concrete by this stable structure. The results of tryout indicated that the mending material has the good effect at the corrosion form of corrosive medium.

根据介质腐蚀形式的劣化机理，该文以提高修补材料耐腐蚀性能、抗渗透性能、粘结性能和抗裂性能为出发点，采用添加有机硅改性三元共聚物、增粘剂、孔隙憎水剂等多种聚合物和聚丙烯纤维对原水泥基材料进行改性，使得修补材料的内部微观结构从单纯的水泥水化产物转变成聚合物和水泥水化产物叠合的空间网状结构，这种稳定的结构能有效抵抗各种介质离子的侵蚀，在实际工程上的试用也显示出新修补材料良好的使用效果。

Based on above studies, some main conclusions were obtained as follows : 1 the diatoms forming mats in low latitude west pacific is"shade flora"diatom Ethmodiscus rex Hendey; 2 the sites found diatom mats are zone distributed, the direction is NW-SE and most distribute in the deep water area with flat seafloor, between 17°N～20°N and the water depth 4837-6150 m below Carbonate Compensation Depth (CCD 3) AMS 14C dates show that the sediments rich in diatom mats occurred during 16.0 ~ 28.6 ka B.P., which means the bloom mainly occurred in last glacial maximum, while there are not diatom mats deposits in other layers; 4 A total of 101 diatom taxa belonging to 40 genera had been identified from the 155 samples in the two cores WPD 03 and WPD 12, and the relative percentage of Thalassionema frauenfeldii are the highest, Thalassionema nitzschioides、Azpeitia nodulifera、Hemidiscus cuneiformis、Nitzschia marina take the second place.

14C年期间，即&勃发&发生于末次冰期最盛期；4在WPD 03和WPD 12两个岩芯共155个样品中共鉴定硅藻40属101种，且Thalassionema frauenfeldii的相对百分含量最高，Thalassionema nitzschioides、Azpeitia nodulifera、Nitzschia marina、Hemidiscus cuneiformis等次之，这五种硅藻占整个硅藻物种相对百分含量的85%左右，说明在该海域表层水体硅藻席沉积过程中，这五种硅藻最容易与成席硅藻在同时期的环境中生存，形成勃发；5MIS3期的晚期，该区域表层海水盐度降低，这有助于该区水体的成层化，从而使&树荫种&硅藻开始勃发，导致&秋季倾泻&；6末次冰期由于南极中层水北扩，南大洋中层水将富含硅酸盐的海水带入了研究区，即南大洋的&硅溢漏&作用，使该区域硅藻得以勃发，同时，铁输入的增多，可能也是造成硅藻勃发的主要原因之一。

A computer-aided local transient flow property measuring system was developed using a high speed CCD camera coupled with optical fibers in order to study the Gas-liquid-solid three-phase jet loop reactors. SnO2 crystal films were orientally deposited on the alkoxysilane molecule-coated hydroxyl glass substrates so as to prepare surface-marked particles as the tracers. An image analysis system was established to identify different phases. Stroboscopic photography was utilized to extend the measure range. The developed measuring and analysis system was capable of determining accurately the local transient flow property in a G-L-S jet loop reactor. Based on the above system, local transient flow properties of gas, liquid, and solid phase were measured and studied the influences of fluid property, operation and configuration parameters on the reactor.

中文摘要：以气液固三相喷射环流反应器为研究对象，将高速CCD和光纤束耦合制成局部瞬态流动特性微机数据采集及图象处理系统，利用MPS硅烷分子在带有羟基的玻璃基底上的自组装引导SnO2晶态膜层在功能化表面上进行沉积，以获得表面标记的示踪粒子，解决图象处理技术与相的识别的问题，利用频闪技术拓展了测量上限，得到可以准确测定气液固三相喷射环流反应器中局部瞬态流动特性的测试系统；采用上述测试技术进行喷射环流反应器中局部气相、液相与固相瞬态流动特性的实验研究，并考察物性参数、操作参数与结构参数的影响规律。

Two times hydrolyzation of Fe~(3+) and Cr~(3+) was firstly pointed out in the process of pillar preparation with hydrothermal method. In order to improve the thermal stability, Fe/Cr-Si-pillaring agent solution was synthesized by hydrolyzing Fe~(3+) and Cr~(3+) solution on the surface of silica sol, and Fe/Cr-Si-pillared montmorillonite (Fe/Cr-Si-PILM) was prepared with conventional method and hydrothermal method. Because the technical innovation of preparation is the best way to improve the PILM properties, two novel methods (Microwave method and Ultrasonication method) have been studied to synthesize Fe/Cr-PILM.In order to expand PILMs new application in the field of coal conversion, catalytic activity of Fe/Cr-Si-PILM catalyst in LongKou lignite and ShenHua coal residue liquefaction was discussed and characterized in the last part of this paper.

研究证明：蒙脱石的预处理是可行的，我们以预处理后的Ca-M为原料，研究并优化了PILM的水热法制备工艺，提出了金属离子的二次水解法；为了提高PILM的热稳定性，我们自制了硅溶胶，合成了Fe／Cr-Si三元复合柱化剂，并制备了Fe／Cr-Si-PILM；在PILM合成中，制备技术的革新是改进PILM性能的重要方法，为此我们探索了微波合成法和超声波合成法在制备Fe／Cr-PILM中的应用；最后，我们选择龙口褐煤和神华煤液化残渣为研究对象，探索了Fe／Cr-Si-PILM催化剂在煤炭液化中的应用，希望能开拓PILM应用的新领域。

The experimental results denoted that the finer pearlite along the austenite boundaries in the as-cast Cr30Ni20NRE steel disappeared first under long-term and high-temperature service condition, and that an umber of Cr- richened carbides were formed due to unila-teral carburizing at long-term and high- temperature, consequently causing Ni to concentrate, bulging and calalyzing decomposition of the carburizing gas.

试验结果表明，长期在高温条件下服役，铸态Cr30Ni20NRE耐热钢中沿奥氏体晶界的珠光首先融入奥氏体，长期高温单边渗碳形成大量富铬碳化物，促使镍富集并起泡形成瘤状物，催化含碳气体的分解；表层瘤状物使辐射管表层疏松，表面积扩张，加快了碳向基体的渗入，提供了碳化物持续长大的条件，并引起沿碳化物周边开裂和奥氏体基体严重萎缩；合金元素的重新分布造成主合金元素铬和镍产生两极分化，镍和硅的富集促使石墨化，与侵入的氧形成内部氧化空洞和膨胀疏松，最终导致构件穿孔失效。

For the sake of solving the problem of great rotary inertia and forged steel rockerarms bad wear-resisting property in the engine of Xia Li cars with modelTJ370Q TJ376Q, we utilize the assembly theory of creative engineeringmethodology to respectively make the aluminum alloy materials and siliconnitride engineering ceramics as base stock of rocker arm and cabochon glut. Inthis way, the goodness of these two kinds of materials are fully strengthened. Forthe new rocker arms, their comprehensive property are enhanced and the cost ofmanufacture is lower than before.

为了解决夏利轿车发动机TJ370Q和TJ376Q中所装配的锻钢镀硬铬气门摇臂所存在的转动惯量大、圆弧面耐磨性差的问题，项目研制中运用创造性方法学中的&组合&原理，有针对性地选用铝合金和氮化硅陶瓷这两种具有不同性能特点的材料分别作为摇臂基体和工作圆弧面镶块，充分发挥两种材料各自不同的性能优势，从而达到提高产品综合性能，降低制造成本的目的。

Ceramic bearings can produce oxidation-ho, silicon carbide, silicon nitride and so on, diameter from 3mm-50mm, precision Machinable P0, P6, P5 level; its performance characteristics are: high temperature, oil-free self-lubricating, acid, alkali and salt corrosion , wear resistance, low noise, insulating diamagnetic, since high-speed operation; metal nano-ceramic bearing its production process for a new generation of high content of nano-particles in the heat and pressure infiltration of metal surface is activated to fill the cracks and pits the metal so that 3-5 micron metal surface is more smooth solid surface, greatly reduce the friction, improve Chennai base metals, and greatly increased the life span of bearings, and its characteristics are: long life (as an ordinary stainless steel bearings 2 -- 10-fold), low noise (as an ordinary stainless steel bearings, 70%), wear-resisting, acid, alkali, salt corrosion, high temperature, load large; ceramic bearing and metal nano-ceramic bearing design and development to meet the needs of the market for high-speed, low - noise, high load, the demand for corrosion-resistant; Machinery Production Department to produce aircraft rod end joint bearing, linear guide bearings, the fuel tank of earrings, plastic bearing, non-standard side bearing components, glass door hardware, such as high-precision control products; and provide CNC machining.

陶瓷轴承可生产氧化镐、碳化硅、氮化硅等，内径从3mm-50mm，精度可加工P0、P6、P5级；其性能特点为：耐高温、无油自润滑、耐酸、碱、盐腐蚀、耐磨、低噪音、绝缘抗磁、起高速运转；金属纳米陶瓷轴承其生产工艺为新一代的高含量纳米级微粒在热和压力的作用下被激活渗入金属表面，填补金属缝隙和凹坑，使金属表面3-5微米表面更光滑坚固，大大降低其摩擦力，提高金属的奈酸碱性，并大大提高了轴承的寿命，其特性为：长寿命（为普通不锈钢轴承的2-10倍）、低噪音（为普通不锈钢轴承的70%）、耐磨、耐酸、碱、盐腐蚀、耐高温、负载大；陶瓷轴承与金属纳米陶瓷轴承的设计开发以满足市场对高转速、低噪音、高负载、耐腐蚀的需求；机械生产部以生产机杆端关节轴承、直线导轨轴承、油缸耳环、塑料轴承、非标端轴承零部件、玻璃门控五金等高精度产品；并对外提供数控加工。

The relevant experiments illustrates A.C. power is more suitable for deicing or snow-melting than D.C. Silica fume can improve the dispersion of carbon fibers and then reduce the electrical resistivity of carbon fiber cementious composites. At a certain volume content, when the ratio of cement, sand and stone is l:l:2, the properties of the CFRC is the best on the whole.

大量实验研究发现：采用交流电是碳纤维导电混凝土用于融雪化冰时的最佳电源选择；采用硅灰能较好地提高碳纤维在基体中的分散性，有效降低碳纤维水泥基复合材料的电阻率；并在现有的级配比实验中发现了具有最好综合性能的配比，即在相同的纤维体积含量的情况下，导电混凝土的具有最好综合性能的配比是水泥、砂子、石子的重量比为1：1：2。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。